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FISHER SCIENTIFIC CO CHEMICAL DIV. -- SC881 CLEANING SOLUTION (CHROMIC ACID-
SULFU -- 6810-01-245-2127
===================== Product Identification =====================
Product ID:SC881 CLEANING SOLUTION (CHROMIC ACID-SULFU
MSDS Date:11/06/1991
FSC:6810
NIIN:01-245-2127
MSDS Number: BNWVZ
=== Responsible Party ===
Company Name:FISHER SCIENTIFIC CO CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100 OR 201-796-7523
CAGE:1B464
=== Contractor Identification ===
Company Name:FISHER SCIENTIFIC CO
Address:2000 PARK LN
Box:City:PITTSBURGH
State:PA
ZIP:15275
Country:US
Phone:412-490-8586
CAGE:22527
Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
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Fraction by Wt: >97%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:CHROMIC ACID
CAS:1333-82-0
RTECS #:GB6650000
Fraction by Wt: 0.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 MICRO GRAMS/M3
ACGIH TLV:50 MICRO GRAMS/M3
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 2140 MG/KG (H2SO4)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CAUSES SEVERE BURNS ON CONTACT WITH
SKIN AND EYES. VAPORS CAUSE SEVERE IRRITATION OF RESPIRATORY TRACT
IF INHALED. WILL CAUSE SEVERE IRRITATION OF GI TRACT AND BURNS TO
MOUTH, THROAT, AND STOMACH IF S WALLOWED. PROLONGED OR REPEATED
INHALTION OR CONTACT MAY CAUSE CANCER OR LESIONS IN MUCOUS
MEMBRANESOR SKIN.
Explanation of Carcinogenicity:CHROMIUM IS LISTED AS A KNOWN CARCINOGEN
BY IARC AND NTP.
Effects of Overexposure:INHALED: SEVERE CHEST PAIN, SHORTNESS OF
BREATH, COUGHING, SNEEZING, WHEEZING, BLOODY NOSE. EYES: PAIN,
REDNESS, BURNS, TEARING, BLURRED VISION. SKIN: REDNESS, BURNS,
PAIN, ITCHING. INGESTED: SORE THR OAT, BROWN STAINS AROUND MOUTH,
SEVERE PAIN IN STOMACH, NAUSEA, VOMITING.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN AND
RESPIRATORY DISORDERS MAY BE AT INCREASED RISK WHEN USING THIS
MATERIAL.
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======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST, GET
MEDICAL CARE. EYES: FLUSH WITH FLOODING AMOUNTS OF WATER WHILE
HOLING EYELIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN: REMOVE
CONTAMINATED CLOTHING. FLUSH WITH LOTS OF WATER FORSEVERAL
MINUTES. GET MEDICAL ATTENTION FOR BURNS. INGESTED: GET IMMEDIATE
MEDICAL ATTENTION. DOCTORS: REMOVE BY GASTRIC LAVAGE OR EMESIS IF
PERSON IS CONSCIOUS.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL OR CARBON DIOXIDE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. DO NOT GET SOILD STREAM OF WATER ON MATERIAL.
MOVE CONTAINER IF CAN BE DONE AT NO RISK.
Unusual Fire/Explosion Hazard:MAY PRODUCE TOXIC FUMES OR VAPOR ON
EXPOSURE TO HIGH TEMPERATURES OR OPEN FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP COMBUSTIBLES AWAY. DO NOT TOUCH SPILLED
MATERIAL. STOP LEAK IF CAN BE DONE AT NO RISK. CONTAIN SPILL.
ISOLATE AREA AND DENY ENTRY. VENTILATE AREA. NEUTRALIZE AND PLACE
IN AN ACID-PROOF CONTAINER FOR LATER DISPOSAL.
Neutralizing Agent:20% SODIUM BICARBONATE SOLUTION, SLAKED LIME,
CRUSHED LIMESTONE.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLES. USE
ONLY WHERE PROPER VENTILATION IS PROVIDED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF ENGINEERING CONTROLS
FAIL, USE NIOSH/MSHA APPROVED RESPIRATOR FOR ACID MISTS OR AIR
SUPPLIED RESPIRATOR. IF RESPIRATORY PROTECTION IS USED, APROGRAM IN
ACCORDANCE WITH 29 CF R 1910.134 MUST BE IMPLEMENTED.
Ventilation:USE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MAINTAIN EXPOSURES BELOW TLV.
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Protective Gloves:PVC OR NEOPRENE
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:APRON, LAB COAT OR SIMILAR CLOTHING TO
PREVENT REPEATED OR PROLONGED CONTACT. EYE WASH STATION & SAFETY
SHOWER.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
AVOID CONTACT WITH MATERIAL. AVOID BREATHING VAPORS.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:554F,290C
Melt/Freeze Pt:M.P/F.P Text:23.0F,-5.0C
Vapor Pres:.001 MM HG
Spec Gravity:1.9
Solubility in Water:COMPLETE
Appearance and Odor:DARK BROWN VISCOUS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
FINELY DIVIDED COMBUSTIBLES, ORGANICS, WATER, STRONG ALKALIS, METALS,
NITRIC ACID MIXTURES, PHOSPHOROUS COMPOUNDS.
Stability Condition to Avoid:CONTACT WITH WATER, ORGANIC MATERIALS, AND
FINELY DIVIDED COMBUSTIBLES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC AND HAZARDOUS FUMES OF CHROMIUM AND SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. CONTAINS CHROMIUM- REGULATORY LEVEL IS 5.0
MG/L. IF AT OR ABOVE THIS LEVEL, MUST BE DISPOSED OF IAW 40 CFR
262, EPA HAZARDOUS WASTE NUMBER D007.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
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assume responsibility for the suitability of this information to their
particular situation.
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