6/5/2009
Krud Kutter?br>
The Must for Rust
MATERIAL SAFETY DATA SHEET
1 PRODUCT AND COMPANY IDENTIFICATION
Product Name: THE MUST FOR RUST - KRUD KUTTER?Brand
Synonyms: Not applicable
Molecular Formula: Not applicable
Molecular Weight: Not applicable
Supplier: Emergency Telephone:
Supreme Chemicals of Georgia, Inc. (CHEMTREC) 800-424-9300
1535 Oak Industrial Lane, Suite B (Non-emergency Telephone) 800- 466-7126
Cumming, GA 30041
USA
Intended Use: Dissolves rust/oxidation.
2 HAZARDS IDENTIFICATION
Emergency Overview
Physical State: Liquid
Color: Light green
Odor: Odorless
WARNING!
Causes severe eye irritation.
Potential Health Effects
Inhalation: Expected to be a low inhalation hazard. Inhalation of mist or vapors may cause irritation to
the mucous membranes and upper respiratory tract.
Eye Contact: Causes severe eye irritation. Exposure may cause eye tearing, redness, and discomfort.
Skin Contact: May cause mild skin irritation in sensitive individuals. Exposure may cause redness,
itching, and inflammation of skin.
Ingestion: Not expected to be an ingestion hazard. Exposure may cause gastrointestinal irritation, nausea,
vomiting, diarrhea and other systemic effects.
Chronic Health Effects: None known
Target Organ(s): Eye
OSHA Regulatory Status: Hazardous; Consumer Product Use: Exempt
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3 COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS-No. Weight %
Phosphoric Acid 7664-38-2 < 20 %
Components not listed are not hazardous or are below reportable limits
4 FIRST AID MEASURES
Inhalation: If symptomatic, move to fresh air. Get medical attention if symptoms persist.
Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove
contact lenses. Get medical attention immediately.
Skin Contact: Wash with soap and water. Get medical attention if symptoms occur.
Ingestion: If swallowed, DO NOT induce vomiting, unless directed by medical personnel. Get medical
attention.
5 FIRE-FIGHTING MEASURES
Extinguishing Media: Water spray, carbon dioxide, dry chemical or material appropriate for surrounding
fire.
Unsuitable Extinguishing Media: Not applicable
Special Fire Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Unusual Fire & Explosion Hazards: None known
Hazardous Combustion Products: Carbon oxides, phosphorous oxides
6 ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropriate personal protective equipment. See Section 8.
Spill Cleanup Methods: Small Liquid Spills: Wipe up or use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Large Spillages: Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other
non-combustible material and transfer to containers. Use water spray to reduce vapors or divert vapor
cloud drift. Isolate and stay upwind. Ventilate enclosed areas. Keep unauthorized personnel away. Prevent
entry into waterways, sewer, basements or confined areas.
7 HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Use only with
adequate ventilation.
Prevention of Fire and Explosion: None
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Storage: Keep container closed. Store in original container. Keep out of reach of children.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Industrial Exposures:
Exposure Limits:
Chemical Name Source Type Exposure Limits Notes
Phosphoric Acid NIOSH REL 1 mg/m? --
Phosphoric Acid NIOSH STEL 3 mg/m? --
Phosphoric Acid NIOSH IDLH 1000 mg/m? --
Phosphoric Acid ACGIH TWA 1 mg/m? Upper
respiratory tract
eye & skin
irritant
Phosphoric Acid ACGIH STEL 3 mg/m? Upper
respiratory tract
eye & skin
irritant
Phosphoric Acid OSHA Z-1 PEL 1 mg/m? --
Phosphoric Acid California TWA 1 mg/m? --
Phosphoric Acid California STEL 3 mg/m? --
Phosphoric Acid Alberta, Canada TWA 1 mg/m? Irritation
Phosphoric Acid Alberta, Canada STEL 3 mg/m? Irritation
Phosphoric Acid British Columbia, TWA 1 mg/m? --
Canada
Phosphoric Acid British Columbia, STEL 3 mg/m? --
Canada
Phosphoric Acid Ontario, Canada TWAEV 1 mg/m? --
Phosphoric Acid Ontario, Canada STEL 3 mg/m? --
Phosphoric Acid Mexico TWA 1 mg/m? --
Phosphoric Acid Mexico STEL 3 mg/m? --
Engineering Controls: Not generally required when handling product. Good general ventilation
(typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain
airborne levels below recommended exposure limits.
Respiratory Protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure
limits have not been established), an approved respirator must be worn. In the United States of America,
if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR
1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government
approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety
professional or manufacturer for specific information.
Eye Protection: Wear splash goggles and a face shield or safety glasses with side shields.
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Hand Protection: Wear chemical resistant gloves.
Skin Protection: Wear protective clothing appropriate for the risk of exposure.
Hygiene Measures: Eye wash, washing facilities
9 PHYSICAL AND CHEMICAL PROPERTIES
Color: Light green
Odor: Odorless
Physical State: Liquid
pH: No data available
Boiling Point: 216?C (420.8?F)
Melting Point: < -1.1?C (30?F)
Flash Point: None
Evaporation Rate: < 1 (Water = 1)
Flammability: None
Flammability Limit ?Upper (%): Not applicable
Flammability Limit ?Lower (%): Not applicable
Vapor Pressure: 17 mm Hg (@ 20 篊) (68?F)
Vapor Density (Air=1): 3.2
Specific Gravity: 1.13
Solubility in Water: Complete
Partition Coefficient (n-Octanol/water): No data available
Autoignition Temperature: Not applicable
Decomposition Temperature: No data available
Volatile Organic Compounds (VOC): 1%
Viscosity: No data available
Percent Volatile: 1 %
10 STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: None known
Incompatible Materials: Strong oxidizing agents
Hazardous Decomposition Products: Carbon oxides, phosphorous oxides
Possibility of Hazardous Reactions: Will not occur.
11 TOXICOLOGICAL INFORMATION
Information available upon request.
Listed Carcinogens: None
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12 ECOLOGICAL INFORMATION
The Must for Rust is biodegradable.
13 DISPOSAL CONSIDERATIONS
General Information: Dispose in accordance with applicable federal, state, and local regulations.
Disposal Methods: No specific disposal method required.
Container: Since emptied containers retain product residue, follow label warnings even after container is
emptied.
14 TRANSPORT INFORMATION
DOT: ORM-D
Proper Shipping Name: Consumer Commodity
Packaging Requirements: Inner packagings not over 5.0 Liters (1.3 Gallons) net capacity each for
liquids, and packed in strong outer packagings. The gross mass of the package must not exceed 30
kilograms (66 pounds).
For over 30 kilograms (66 pounds):
UN-Number: 1805
Proper Shipping Name: Phosphoric Acid Solution
Class: 8
Packaging Group: III
Emergency Response Guide Number: 154
TDG:
Limited Quantity
Inner packaging must not exceed 5.0 Liters (1.3 Gallons). The gross mass of the package must not exceed
30 kilograms (66 pounds).
For over 30 kilograms (66 pounds):
UN-Number: 1805
Proper Shipping Name: Phosphoric Acid Solution
Class: 8
Packaging Group: III
Emergency Response Guide Number: 154
IATA:
For Limited Quantities of liquids of Class 8 Packing Group III:
Passenger & Cargo Aircraft Packing Instructions: Y819
Passenger & Cargo Aircraft Limited Quantity Maximum Quantity Package: 1 Liter
Single packagings are not permitted. The inner packagings must be packed in one of the following outer
packagings with sufficient cushioning/absorbent material so as to prevent movement/leakage. The
maximum quantity must not exceeded. Inner packagings: glass earthenware, plastic, metal (not
aluminum), or glass ampoule.
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Outer Packaging: Steel packagings must be corrosion-resistant or with protection against corrosion. Glass
or earthenware inner packagings and glass ampoules must be packaged with absorbent material in tightly
closed metal or rigid plastic receptacles in outer packagings. Glass or earthenware inner packagings and
glass ampoules are permitted if this item is free from hydrofluoric acid.
Outer Packaging: Drums: Steel, aluminum, plywood, fiber, plastic. Jerricans: Steel, Aluminum,
Plastic; Boxes: UN Certified Box, Steel, aluminum, wood, plywood, reconstituted wood, fiber board and
plastic
For over 30 kilograms (66 pounds):
UN-Number: 1805
Proper Shipping Name: Phosphoric Acid Solution
Class: 8
Packaging Group: III
Label: Corrosive
Emergency Response Guide Number: 154
IMDG:
Limited Quantities Exception: Dangerous Goods in limited quantities of Class 8.
Limited quantities must be packed in combination packaging. The inner packaging must be within the
quantity limit specified in the Dangerous Goods List (DGL) for the substance being prepared for
shipment and be packaged in suitable outer packaging. The gross mass of the package must not exceed 30
kilograms (66 pounds).
For over 30 kilograms (66 pounds):
UN-Number: 1805
Proper Shipping Name: Phosphoric Acid Solution
Class: 8
Packaging Group: III
EMS No: F-A, S-B
Special Provision: 223
Packing Instructions: P001, LP01
IBC 03
Portable tanks and bulk containers:
IMO Tank Instructions: T3
UN Tank Instructions: T4
Provisions: TP1
Stowage and Segregation: Category A
15 REGULATORY INFORMATION
Canadian Controlled Products Regulations: This product has been classified according to the hazard
criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required
information.
WHMIS Classification: D2B
Mexico ?Phosphoric Acid: 3-0-0-3; PPE: F
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Inventory Status
This product or all components are listed on the following inventory: TSCA
DSL Inventory: No information available
US Regulations
CERCLA Hazardous Substance List (40 CFR 302.4):
Component Reportable
Quantity
Phosphoric Acid 5,000 lbs
SARA Title III
Section 302Extremely Hazardous Substance (40 CFR 355, Appendix A): None
Section 311/312 (40 CFR 370): None
Section 313 Toxic Release Inventory (40 CFR 372): None
Clean Air Act (CCA) Section 112, 1990 Amendments, Statutory Hazardous Air Pollutants: None
Clean Air Act (CAA) Section 112(i) High-Risk Hazardous Air Pollutants (40 CFR 63.74): None
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): None
Clean Water Act Section 307 Toxic Pollutants (40 CFR 401.15): None
Clean Water Act Section 311 Hazardous Chemical (40 CFR 116.4): None
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3):
Component Reportable
Quantity
Phosphoric Acid 5,000 lbs
Drug Enforcement Act: None
TSCA: None
.
State Regulations
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): None
Massachusetts Right-To-Know List: Phosphoric Acid
Minnesota Hazardous Substances List: Phosphoric Acid
New Jersey Right-To-Know List: Phosphoric Acid
Pennsylvania Right-To-Know Substances: Phosphoric Acid
16 OTHER INFORMATION
Hazard Ratings
Health Hazard Fire Hazard Reactivity Hazard Special Hazard
2 0 0 N/A
NFPA
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Health Hazard Fire Hazard Reactivity Hazard
2 0 0
HMIS
0 ?Minimal; 1 ?Slight; 2 ?Moderate; 3 ?Serious; 4 ?Severe; *- Chronic health effect
Revision Information: Transportation updated
Prepared by: Supreme Chemicals of Georgia, Inc.
Issue Date: 6/5/2009
Supersedes Date: 5/31/2007
Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither
the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
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