Title: Date: Rev: Page: File Name:
Material Safety Data Sheet for
1 of 4 MSDS battery
12/08/08 L
All Optima Batteries
MSDS No.
L 8A
Date Issued
Feb. 20, 1990
Date Revised
December 8,
2008
Chemical/Trade Name (identity used on label) Chemical Family/Classification HMIS Rating for Sealed,
Sealed Lead Acid Battery/ OPTIMA BATTERY TM Electric Storage Battery Lead Acid Battery 0 0 0;
For sulfuric acid 3 0 2
Synonyms/Common Name DOT, IATA and IMO Description
Sealed Lead Acid Battery Non-Spillable Battery , Exempt from UN2800 Classification
Address
Company Name
17500 E. 22nd Avenue
OPTIMA Batteries, Inc.
Division or Department Aurora, CO 80011
Wholly- owned subsidiary of Johnson Controls
Inc.
CONTACT TELEPHONE NUMBER
Questions Concerning MSDS Day:
OPTIMA Batteries, Environmental, Health & (800) 292-4359, Ext. 462
Safety Department
Transportation Emergencies 24 Hours: (800) 424-9300
CHEMTREC International: (703) 527-3887 (Collect)
NOTE: The OPTIMA sealed lead acid battery is considered an article as defined by 29 CFR 1910.1200 ?OSHA Hazard
Communication Standard. The information on this MSDS is supplied at customer's request for information only.
II. Hazardous Ingredients
Material % by Wt. CAS Number Eight Hour Exposure Limits
NIOSH
OSHA ACGIH
REL
PEL TLV
50 g/m 150 g/m 100 g/m
3 3 3
Specific Chemical Identity 63-81 7439-92-1
Lead & lead compounds
3
3 3
Specific Chemical Identity 17 - 25 7664-93-9 1mg/m 0.2 mg/m 1 mg/m
(respirable
Sulfuric Acid (35%)
thoracic fraction)
Common Name
Battery Electrolyte (Acid)
Common Name 2-6 9003-07-0 -- -- --
Case Material Polypropylene
Common Name 1-4 65997-17-3 -- -- --
Separator/Paster Paper Fibrous Glass
NOTE: The contents of this product are toxic chemicals that are subject to the reporting requirements
of section 302 and 313 of the Emergency Planning and Community Right-To-Know Act of 1986
(40CFR 355 and 372).
III. Physical Data
Material is (at normal temperatures) Appearance and Odor
Solid Liquid Battery Electrolyte (acid) is a clear to cloudy liquid
with slight acidic odor. Acid saturated lead oxide
Boiling Point (at 760 mm Hg) Melting Point
Lead 1755oC Batt. Electrolyte Lead 327.4oC is a dark reddish-brown to gray solid with slight
o
(Acid) 110-112 C acidic odor.
Specific Gravity (H2O =1) o
Vapor Pressure (mm Hg at 20 C) Z(PSIG)
Battery Electrolyte (Acid) 1.210 - 1.300 Battery Electrolyte (Acid) 11.7
Vapor Density (Air =1) Solubility is H2O
Battery Electrolyte (Acid) 3.4 Lead and Lead Dioxide are not soluble.
Battery Electrolyte (acid) is 100% soluble in water.
% Volatile By Weight Evaporation rate (Butyl Acetate = 1)
Not Determined Not Determined
Title: Date: Rev: Page: File Name:
Material Safety Data Sheet for
2 of 4 MSDS battery
12/08/08 L
All Optima Batteries
IV. Health Hazard Information
NOTE: Under normal conditions of use, this product does not present a health hazard. The following information is
provided for battery electrolyte (acid) and lead for exposure that may occur during battery production or container
breakage or under extreme heat conditions such as fire
ROUTES AND METHODS OF ENTRY
Inhalation
Acid mist may be generated during battery overcharging and may cause respiratory irritation. Seepage of acid from
broken batteries may present inhalation exposure in a confined area.
Skin Contact
Battery electrolyte (acid) can cause severe irritation, burns and ulceration.
Skin Absorption
Skin absorption is not a significant route of entry.
Eye Contact
Battery electrolyte (acid) can cause severe irritation, burns, and cornea damage upon contact.
Ingestion
Hands contaminated by contact with internal components of a battery can cause ingestion of lead/lead compounds.
Hands should be washed prior to eating, drinking, or smoking.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Acute Effects
Acute effects of overexposure to lead compounds are GI (gastrointestinal) upset, loss of appetite, diarrhea,
constipation with cramping, difficulty in sleeping, and fatigue. Exposure and/or contact with battery electrolyte
(acid) may lead to acute irritation of the skin, corneal damage of the eyes, and irritation of the mucous membranes of
the eyes and upper respiratory system, including lungs.
Chronic Effects
Lead and its compounds may cause chronic anemia, damage to the kidneys and nervous system. Lead may also
cause reproductive system damage and can affect developing fetuses in pregnant women. Battery electrolyte (acid)
may lead to scarring of the cornea, chronic bronchitis, as well as erosion of tooth enamel in mouth breathers in
repeated exposures.
POTENTIAL TO CAUSE CANCER
The National Toxicological Program (NTP) and The International Agency for Research on Cancer (IARC) have
classified "strong inorganic acid mist containing sulfuric acid" as a Category 1 carcinogen, a substance that is
carcinogenic to humans. The ACGIH has classified "strong inorganic acid mist containing sulfuric acid" as an A2
carcinogen (suspected human carcinogen). These classifications do not apply to liquid forms of sulfuric acid or
sulfuric acid solutions contained within a battery. Inorganic acid mist (sulfuric acid mist) is not generated under
normal use of this product. Misuse of the product, such as overcharging, may result in the generation of sulfuric
acid mist.
The NTP and the IARC have classified lead as an A3 carcinogen (animal carcinogen). While the agent is carcinogenic
in experimental animals at relatively high doses, the agent is unlikely to cause cancer in humans except under
uncommonly high levels of exposure. For further information, see the ACGIH's pamphlet, 1996 Threshold Limit
Values and Biological Exposure Indices.
EMERGENCY AND FIRST AID PROCEDURES
Inhalation
Not expected for product under normal conditions of use. However, if acid vapor is released due to overcharging or
abuse of the battery, remove exposed person to fresh air. If breathing is difficult, oxygen may be administered. If
breathing has stopped, artificial respiration should be started immediately. Seek medical attention immediately.
Skin
Exposure not expected for product under normal conditions of use. However, if acid contacts skin, flush with water
and mild soap. If irritation develops, seek medical attention immediately.
Eyes
Exposure not expected for product under normal conditions of use. However, if acid from broken battery case enters
eyes, flush with water for at least 15 minutes. Seek medical attention immediately.
Ingestion
Not expected due to physical form of finished product. However, if internal components are ingested:
Lead/Lead compounds: Consult a physician immediately for medical attention.
Battery Electrolyte (Acid): Do not induce vomiting. Refer to a physician immediately for medical attention.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Inorganic lead and its compounds can aggravate chronic forms of kidney, liver, and neurologic diseases. Contact of
battery electrolyte (acid) with the skin may aggravate skin diseases such as eczema and contact dermatitis.
Title: Date: Rev: Page: File Name:
Material Safety Data Sheet for
3 of 4 MSDS battery
12/08/08 L
All Optima Batteries
V. Fire and Explosion Data
Flash Point (test method) Autoignition Temperature Flammable Limits in Air, % by Vol.
Hydrogen - 259oC Hydrogen 580篊 Hydrogen LEL - 4.1 UEL - 74.2
Extinguishing Media
Dry chemical, foam, or CO2
Special Fire Fighting Procedures
Use positive pressure, self-contained breathing apparatus.
Unusual Fire and Explosion Hazard
The sealed lead acid battery is not considered flammable, but it will burn if involved in a fire. A short
circuit can also result in a fire. Acid mists, smoke and decomposition products may be produced.
Remove all ignition sources. Cool battery(s) to prevent rupture.
VI. Reactivity Data
Stability Conditions to Avoid
Unstable Stable Sparks and other sources of ignition may ignite hydrogen gas.
Incompatibility (materials to avoid)
Lead/lead compounds: Potassium, carbides, sulfides, peroxides, phosphorus, sulfur.
Battery electrolyte (acid): Combustible materials, strong reducing agents, most metals, carbides,
organic materials, chlorates, nitrates, picrates, and fulminates.
Hazardous Decomposition Products
Lead/Lead compounds: Oxides of lead and sulfur
Battery electrolyte (acid): Hydrogen, sulfur dioxide, sulfur trioxide
Hazardous Polymerization Conditions to Avoid
High temperature. Battery electrolyte (acid) will react with water to
May Occur Will Not Occur produce heat. Can react with oxidizing or reducing agents.
VII. Control Measures
Engineering Controls
Store sealed lead acid batteries at ambient temperature. Never recharge batteries in an unventilated,
enclosed space. Do not subject product to open flame or fire. Avoid conditions that could cause arcing
between terminals.
Work Practices
Do not carry battery by terminals. Do not drop battery, puncture or attempt to open battery case. Avoid
contact with the internal components of a battery.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection
None required for normal handling of finished product.
Eyes and Face
None required under for finished product under normal conditions of use. If necessary to handle
broken product, chemical splash goggles are recommended.
Hands, Arms, and Body
None required for normal handling of finished product. If necessary to handle broken product, Vinyl-
coated, PVC, gauntlet-type gloves with rough finish are recommended..
Other Special Clothing and Equipment
Safety footwear meeting the requirements of ANSI Z 41.1 ?1991 is recommended when it in necessary
to handle the finished product.
VIII. Safe Handling Precautions
Hygiene Practices
Wash hands thoroughly before eating, drinking, or smoking after handling batteries.
Protective Measures to be Taken During Non-Routine Tasks, Including Equipment Maintenance
Do not carry battery by terminals. Do not drop battery, puncture or attempt to open battery case. Do not
subject product to open flame or fire and avoid situations that could cause arcing between terminals.
SPILL OR LEAK PROCEDURES
Title: Date: Rev: Page: File Name:
Material Safety Data Sheet for
4 of 4 MSDS battery
12/08/08 L
All Optima Batteries
Protective Measures to be Taken if Material is Released or Spilled
Remove combustible materials and all sources of ignition. Avoid contact with acid materials. Use soda
ash, baking soda or lime to neutralize any acid that may be released.
If battery is broken, wear chemical goggles and acid-resistant gloves for handling the parts.
DO NOT RELEASE UNNEUTRALIZED ACID!
Waste Disposal Method
Battery Electrolyte (Acid): Neutralize as above for a spill, collect residue, and place in a drum or
suitable container. Dispose of as a hazardous waste.
DO NOT FLUSH LEAD-CONTAMINATED ACID INTO SEWER.
Send spent or broken batteries to a lead recycling facility or smelter that follows applicable Federal,
State and Local regulations for routine disposition of spent or damaged batteries. The distributor /
user is responsible for assuring that these "spent" or "damaged" batteries are disposed of in an
environmentally sound way in accordance with all regulations. OPTIMA batteries are 100% recyclable
by any licensed reclamation operation..
SUPPLEMENTAL INFORMATION
Proposition 65 Warning: Battery posts, terminals and related accessories contain lead and lead compounds, chemicals
known to the State of California to cause cancer and reproductive harm. Batteries also contain other chemicals known to the
State of California to cause cancer. Wash hands after handling.
TSCA Registry: Ingredients listed in the TSCA Registry are lead, lead compounds, and sulfuric acid.
Transportation: Sealed Lead Acid Battery is not a DOT Hazardous Material.
Other: Per DOT, IATA, ICAO and IMDG rules and regulations, these batteries are exempt from "UN2800"
classification as a result of successful completion of the following tests:
1) Vibration Tests
2) Pressure Differential Tests
3) Case Rupturing Tests (no free liquids)
Model Number CONUS NATIONAL STOCK NUMBERS OCONUS NSN'S
1000M 6140-01-475-9416 6140-01-441-4280
850/6-1050 SLI 6140-01-475-9414
75/35 6140-01-475-9361
800 R 6140-01-475-9357
D900M 6140-01-475-9355
D51R Pending Pending
D51 6140 01 523 6288
D31T 6140-01-457-5469 6140-01-457-5469
D31A 6140 01 502 4973 6140 01 502 4973
D31M 6140 01 502 4405 6140 01 502 4405
D750S 6140-01-457-5392 6140 01 450 0141
800S 6140-01-457-5296 6140-01-378-8232
D750U 6140-01-457-4341 6140-01-441-4272
800U 6140-01-457-4339 6140-01-374-2243
850/6-950 (DC)
Title: Date: Rev: Page: File Name:
Material Safety Data Sheet for
5 of 4 MSDS battery
12/08/08 L
All Optima Batteries
Disclaimer: This information has been compiled from sources considered to be dependable and is, to the best of our
knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty (either
express or implied) or guarantee is made to the accuracy, reliability or completeness of the information contained
herein. This information relates to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process. It is the user's responsibility to satisfy himself as to the
suitability and completeness of this information for his own particular use. We do not accept liability for any loss or
damage that may occur, whether direct, indirect, incidental or consequential, from use of this information.
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