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4759-48-2 8021-39-4 22-34-3

File Name: 4759-48-2_8021-39-4_22-34.asp

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Basic Index (contains single None (or /BI) S 4759-48-2 Full MSDS
words from the full MSDS S 13-CIS-RETINOIC ACID document
document) S SPILL?(L)WATER
S L1 AND FIRST AID

CAS Registry Number /RN S 4759-48-2/RN RN
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Sample Record
DISPLAY ALL

OHSN OHS71221 MSDS-OHS
REVISION DATE: 31 Aug 2009 (Revision Number: 1.0100)

------------------------------------------------------------------------------
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
------------------------------------------------------------------------------

Material Name: WOOD CREOSOTE

ChemADVISOR, Inc.
Stone Quarry Crossing
811 Camp Horne Road, Suite 220
Pittsburgh, PA 15237

Phone: (412) 847-2000
Fax: (412) 847-2010
Email: info@chemadvisor.com


Synonyms
CREASOTE; CREOSOTE, WOOD; RTECS: GO5870000

------------------------------------------------------------------------------
SECTION 2 HAZARDS IDENTIFICATION
------------------------------------------------------------------------------

EMERGENCY OVERVIEW
Color: colorless to brown
Odor: irritating odor
Health Hazards: skin burns, eye burns, respiratory tract irritation
Physical Hazards: Combustible liquid and vapor.
POTENTIAL HEALTH EFFECTS

Inhalation
Short Term: irritation (possibly severe), nausea, headache, dizziness
Long Term: vomiting

Skin Contact
Short Term: burns, rash, itching, low body temperature, nausea, vomiting,
difficulty breathing, headache, dizziness, bluish skin color, convulsions
Long Term: no information on significant adverse effects

Eye Contact
Short Term: burns, pin-point pupils
Long Term: same as effects reported in short term exposure

Ingestion
Short Term: low body temperature, nausea, vomiting, difficulty breathing,
headache, dizziness, bluish skin color, convulsions
Long Term: no information on significant adverse effects

------------------------------------------------------------------------------
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
------------------------------------------------------------------------------
CAS: 8021-39-4
COMPONENT: WOOD CREOSOTE
EC NUMBER: 232-419-1
Percent: 100.0
Symbol(s): Xn C Xi
Risk Phrase(s): R:22-34-37



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------------------------------------------------------------------------------
SECTION 4 FIRST AID MEASURES
------------------------------------------------------------------------------
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial
respiration if not breathing. Get immediate medical attention.

Skin
Wash skin with soap and water for at least 15 minutes while removing
contaminated clothing and shoes. Get immediate medical attention. Thoroughly
clean and dry contaminated clothing before reuse. Destroy contaminated shoes.

Eyes
Immediately flush eyes with plenty of water for at least 15 minutes. Then get
immediate medical attention.

Ingestion
Contact local poison control center or physician immediately. Never make an
unconscious person vomit or drink fluids. When vomiting occurs, keep head lower
than hips to help prevent aspiration. If person is unconscious, turn head to
side. Get medical attention immediately.

Note to Physicians
For ingestion, consider gastric lavage and activated charcoal slurry.

------------------------------------------------------------------------------
SECTION 5 FIRE FIGHTING MEASURES
------------------------------------------------------------------------------
See Section 9 for Flammability Properties

NFPA Ratings:
Health: 3 Fire: 2 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Moderate fire hazard.

Extinguishing Media
regular dry chemical, carbon dioxide, water, regular foam

Large fires: Use regular foam or flood with fine water spray.

Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers
with water spray until well after the fire is out. Stay away from the ends of
tanks. For fires in cargo or storage area: Cool containers with water from
unmanned hose holder or monitor nozzles until well after fire is out. If this
is impossible then take the following precautions: Keep unnecessary people
away, isolate hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or any
discoloration of tanks due to fire. For tank, rail car or tank truck:
Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire
unless flow of material can be stopped first. Flood with fine water spray. Do
not scatter spilled material with high-pressure water streams. Cool containers
with water spray until well after the fire is out. Apply water from a protected
location or from a safe distance. Avoid inhalation of material or combustion
by-products. Stay upwind and keep out
of low areas.

------------------------------------------------------------------------------
SECTION 6 ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------------------------
Water Release
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65). Keep out of water supplies and sewers.

Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible

January 2010
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MSDS-OHS
without personal risk. Reduce vapors with water spray. Small spills: Absorb
with sand or other non-combustible material. Collect spilled material in
appropriate container for disposal. Large spills: Dike for later disposal.
Remove sources of ignition. Keep unnecessary people away, isolate hazard area
and deny entry.

------------------------------------------------------------------------------
SECTION 7 HANDLING AND STORAGE
------------------------------------------------------------------------------
Storage Procedures
Store and handle in accordance with all current regulations and standards.
Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and
bonding required. Keep separated from incompatible substances.

------------------------------------------------------------------------------
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
------------------------------------------------------------------------------
Component Exposure Limits
ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for
any of this product's components.

Exposure Limits for Chemicals which may be generated during processing
This material has no components listed.

Ventilation
Provide local exhaust or process enclosure ventilation system. Ensure
compliance with applicable exposure limits.

Eyes/Face
Wear splash resistant safety goggles with a faceshield. Provide an emergency
eye wash fountain and quick drench shower in the immediate work area.

Protective Clothing
Wear appropriate chemical resistant clothing.

Glove Recommendations
Wear appropriate chemical resistant gloves.

Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may
be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use.
Any chemical cartridge respirator with organic vapor cartridge(s).
Any chemical cartridge respirator with a full facepiece and organic vapor
cartridge(s).
Any air-purifying respirator with a full facepiece and an organic vapor
canister.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with a full facepiece that is operated in a
pressure-demand or other positive-pressure mode in combination with an
auxiliary self-contained breathing apparatus operated in pressure-demand or
other positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is
operated in a pressure-demand or other positive-pressure mode.

------------------------------------------------------------------------------
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
------------------------------------------------------------------------------
Physical State: Liquid
Appearance: Not available
Color: colorless to brown
Physical Form:
Odor: irritating odor
Odor Threshold: Not available
Taste: burning taste
Texture: oily

January 2010
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MSDS-OHS
pH: Not available
Melting Point: Not available
Boiling Point: 195 - 400 .cents.C
Flash Point: 73 .cents.C
Evaporation Rate: Not available
OSHA Flammability Class: IIIA
Vapor Pressure: Not available
Vapor Density (air = 1): Not available
Density: Not available
Specific Gravity (water = 1): >1.076
Water Solubility: slightly soluble
Coeff. Water/Oil Dist: Not available
Auto Ignition: 336 .cents.C
Viscosity: Not available
Volatility: Not available

Solvent Solubility
Soluble: glycerol, acetic acid, fixed alkali hydroxide solutions, alcohol,
chloroform, ether, oils.

------------------------------------------------------------------------------
SECTION 10 STABILITY AND REACTIVITY
------------------------------------------------------------------------------
Chemical Stability
Stable at normal temperatures and pressure.

Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Containers may
rupture or explode if exposed to heat. Keep out of water supplies and sewers.

Materials to Avoid
combustible materials, acids, metal salts, oxidizing materials

WOOD CREOSOTE:
***ACACIA*** : Incompatible.
ALBUMIN: Incompatible.
CHLOROSULFONIC ACID: Increase in temperature and pressure when mixed in closed
container.
CUPRIC SALTS: Incompatible.
FERRIC SALTS: Incompatible.
GOLD SALTS: Incompatible.
OXIDIZERS: Fire and explosion hazard.
SILVER SALTS: Incompatible.

Decomposition Products
oxides of carbon


Thermal decomposition products: oxides of carbon.

Possibility of Hazardous Reactions
Will not polymerize.

------------------------------------------------------------------------------
SECTION 11 TOXICOLOGICAL INFORMATION
------------------------------------------------------------------------------
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and no
selected endpoints have been identified.

RTECS Acute Toxicity (selected)
The components of this material have been reviewed, and RTECS publishes the
following endpoints:

WOOD CREOSOTE (8021-39-4) Oral: 433 mg/kg oral mouse LD50

Acute Toxicity Level

January 2010
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MSDS-OHS
WOOD CREOSOTE (8021-39-4) Toxic: ingestion.

Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA.

RTECS Irritation
The components of this material have been reviewed and RTECS publishes no data
as of the date on this document.

Local Effects
WOOD CREOSOTE (8021-39-4) Irritant: inhalation.
Corrosive: skin, eye.

HEALTH EFFECTSInhalation - Acute Exposure
WOOD CREOSOTE: May cause moderate respiratory tract irritation. In one study of
workers who developed creosote burns, a small percent also complained of
depression, weakness, severe headache, slight confusion, vertigo, salivation,
and nausea. It is unclear whether the route of exposure was skin contact or
inhalation or both.
Inhalation - Chronic Exposure
WOOD CREOSOTE: A study of workers spraying warmed creosote with concentrations
up to 0.01 mg/L reported headaches, giddiness, nausea, vomiting, and
salivation.

Skin Contact - Acute Exposure
WOOD CREOSOTE: The liquid and vapors are strong irritants and may cause
burning, itching, local erythema progessing to a bronze pigmentation, papular
and vesicular eruptions, ulceration, and desquamation. Photosensitization
occurs, especially in fair-skinned persons. Prolonged contact may cause burns.
It is readily absorbed through the skin and may cause systemic illness with
salivation, nausea, vomiting, headache, thready pulse, respiratory distress,
loss of pupillary reflexes, hypothermia, mild convulsions, and cyanosis.
Depression, weakness, slight confusion, nausea, and vertigo were also reported
from one study in which it was not clear whether the route of exposure was
inhalation or skin contact or both.

Skin Contact - Chronic Exposure
WOOD CREOSOTE: Repeated or prolonged exposure may cause darkening of the skin
and dermatitis. If sufficient amounts are absorbed, systemic symptoms as with
acute exposure may occur.

Eye Contact - Acute Exposure
WOOD CREOSOTE: Liquid contact has caused painful protracted
keratoconjunctivitis involving loss of corneal epithelium, clouding of the
cornea, miosis and long-lasting irritability and photophobia. Other symptoms
which have been reported from exposure to creosote-treated particles include
abrasion of the cornea with some permanent scarring, hyperemia, and pronouced
serous secretion.

Eye Contact - Chronic Exposure
WOOD CREOSOTE: Repeated or prolonged exposure may cause conjunctivitis.
Ingestion - Acute Exposure
WOOD CREOSOTE: Has caused intense irritation and congestion of the entire
gastroenteric tract. Salivation, nausea, vomiting, respiratory distress,
thready pulse, vertigo, headache, loss of pupillary reflexes, hypothermia,
cyanosis and mild convulsions may also occur. Death from large doses appears
largely due to cardiovascular collapse.

Ingestion - Chronic Exposure
WOOD CREOSOTE: Repeated ingestion of small doses may result in chronic
intoxication characterized by distubances of vision and digestion including
increased peristalsis and bloody stools. In one case, hypertension and general
cardiovascular collapse were reported. Other symptoms of acute exposure are
also possible. Maternal reproductive effects have been reported in mice
following repeated exposures prior to mating. Paternal reproductive effects
have been reported in mice and rats following repeated exposures prior to
mating.

January 2010
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MSDS-OHS


------------------------------------------------------------------------------
SECTION 12 ECOLOGICAL INFORMATION
------------------------------------------------------------------------------
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components.


------------------------------------------------------------------------------
SECTION 13 DISPOSAL CONSIDERATIONS
------------------------------------------------------------------------------
Disposal Methods
Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste
Number(s): U051. Dispose in accordance with all applicable regulations.

Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.

------------------------------------------------------------------------------
SECTION 14 TRANSPORT INFORMATION
------------------------------------------------------------------------------
US DOT Information
Shipping Name: Corrosive liquids, n.o.s. (Contains: WOOD CREOSOTE)
Hazard Class: 8
UN/NA #: UN1760
Packing Group: II
Required Label(s): 8


TDG Information: No Classification assigned.
ADR Information
Shipping Name: Corrosive liquid, n.o.s. (Contains: )
Hazard Class: 8
UN #: UN1760
Packing Group: II
Required Label(s): 8

RID Information
Shipping Name: Corrosive liquid, n.o.s. (Contains: )
Hazard Class: 8
UN #: UN1760
Packing Group: II
Required Label(s): 8


IATA Information
Shipping Name: Corrosive liquid, n.o.s. (Contains: )
Hazard Class: 8
UN #: UN1760
Packing Group: II
Required Label(s): 8


ICAO Information
Shipping Name: Corrosive liquid, n.o.s. (Contains: )
Hazard Class: 8
UN #: UN1760
Packing Group: II
Required Label(s): 8


IMDG Information
Shipping Name: Corrosive liquid, n.o.s. (Contains: )
Hazard Class: 8
UN #: UN1760
Packing Group: II

January 2010
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MSDS-OHS

------------------------------------------------------------------------------
SECTION 15 REGULATORY INFORMATION
------------------------------------------------------------------------------
U.S. Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR
372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety
plan.

SARA Section 311/312 (40 CFR 370 Subparts B and C)
Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactive: No

U.S. State Regulations
The following components appear on one or more of the following state hazardous
substances lists:

Component: WOOD CREOSOTE
CAS: 8021-39-4
CA: No
MA: Yes
MN: No
NJ: No
PA: No
RI: No

Not regulated under California Proposition 65
EU Marking and Labelling
Symbols
Xn Harmful
C Corrosive
Xi Irritant
Risk Phrases
R22 Harmful if swallowed.
R34 Causes burns.

R37 Irritating to respiratory system.
Safety Phrases
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feedingstuffs.
S20 When using do not eat or drink.
S24 Avoid contact with skin.
S25 Avoid contact with eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36 Wear suitable protective clothing.
S39 Wear eye/face protection.
S46 If swallowed, seek medical advice immediately and show this container or
label.

Component Analysis - Inventory
Component: WOOD CREOSOTE
CAS: 8021-39-4
US: Yes
CA: DSL
EU: EIN
AU: Yes
PH: No
JP: No
KR: Yes
CN: Yes
NZ: Yes

Globally Harmonized System of Classification and Labelling (GHS)
The listed component(s) of this material have been checked for country-specific
published classifications according to the Globally Harmonized System of
Classification and Labelling (GHS). The results of the queries are displayed

January 2010
13
MSDS-OHS
below. Please see the individual country listings, as additional
interpretations or reference information may be available. For a reference
list of H- or P-statements, please visit ChemADVISOR’s website at
www.chemadvisor.com\sdsoncommand\ghs_H&Pphrases.html.


Australia GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

EU GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

Indonesia GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

Japan GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

Korea GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

New Zealand GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

South Africa GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

Taiwan GHS Classifications
No published information available. This material may be hazardous according
to published criteria for classification.

------------------------------------------------------------------------------
SECTION 16 OTHER INFORMATION
------------------------------------------------------------------------------
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR -
European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C -
Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive
Environmental Response, Compensation, and Liability Act; CN - China; CPR -
Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT -
Department of Transportation; DSL - Domestic Substances List; EEC - European
Economic Communicty; EINECS - European Inventory of Existing Commercial
Chemical Substances; EPA - Environmental Protection Agency; EU - European
Union; F - Farenheit; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; ICAO - International Civil Aviation
Organization; IDL - Ingredient Disclosure List; IMDG - International Maritime
Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR -
Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's
Regulatory Database; M

K - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure
Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for
Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP -
National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and
Health Administration; PH - Philippines; RCRA - Resource Conservation and
Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects
of Chemical Substances®; SARA - Superfund Amendments and Reauthorization
Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods;
TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper
Explosive Limit; US - United States

January 2010
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MSDS-OHS

Full text of R phrases in Section 3
R22 Harmful if swallowed.
R34 Causes burns.
R37 Irritating to respiratory system.

Other Information
Reasonable care has been taken in the preparation of this information, but the
manufacturer makes no warranty of merchantability or any other warranty,
expressed or implied, with respect to this information. The manufacturer makes
no representations and assumes no liability for any direct, incidental or
consequential damages resulting from its use. Disclaimer: Supplier gives no
warranty of merchantability or of fitness for a particular purpose. Any product
purchased is sold on the assumption the purchaser will make his own tests to
determine the quality and suitability of the product. Supplier expressly
disclaims any and all liability for incidental and/or consequential property
damage arising out of the use of this product. No information provided shall be
deemed to be a recommendation to use any product in conflict with any existing
patent rights. THIS MSDS IS TO BE UTILIZED SOLEY AS A REFERENCE DOCUMENT AND IT
IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD
COMMUNICATION STA
DARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Material
Safety Data Sheet before handling product.

Copyright
Copyright 1984-2009 ChemADVISOR, Inc. All rights reserved.




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