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Procter & Gamble
Fabric and Home Care Division
Ivorydale Technical Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: FH/F/2004/MBMS-5ZCGW9 Issue Date: 6/22/04
FH/F/2004/MBMS-5ZXNZ9
Supersedes: FH/F/2003/JEJR-5QDMUY Issue Date: 8/25/03
SECTION I - CHEMICAL PRODUCT
Identity: Fabric Refresher
Brands: FEBREZE (All variations)
Hazard Rating: Health: 1 4=EXTREME
Flammability: 2 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
Emergency Telephone Number: P&G Operator: 1-800-308-EASY (1-800-308-3279) or call Local Poison Control
Center
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients include: Contains water, alcohol, odor eliminator derived from corn, fragrance
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common CAS Recommended Limits Concentration LC50/LD50
Chemical
Name No.
Name
Ethanol 64-17-5 OSHA Z-1 PEL: 1000 ppm 1-5% LD50=13 mL/kg
Ethyl alcohol
(1900mg/m3) (oral, rats)
ACGIH TWA: 1000 ppm LC50=N/A
(1880 mg/m3)
NIOSH REL: 1000 ppm
(1900 mg/m3)
SECTION III - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Ingestion: None
Eye Contact: Mild eye irritant.
Inhalation: None
Signs and Symptoms of Exposure:
Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea.
Eye Contact: Do not spray directly toward face. If eye contact occurs, rinse well with water.
Skin: Prolonged skin contact or instillation into the eye may result in transient, superficial effects similar to
those produced by mild toilet soap.
Inhalation: Inhalation of high concentrations of ethanol vapor may cause irritation of the eyes and respiratory
tract, drowsiness, and fatigue.
FEBREZE FABRIC REFRESHER MSDS (Continued) Page 2 of 4
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Inhalation: Remove to fresh air.
Ingestion: Dilute with fluids and treat symptomatically.
Eye Contact: Rinse well with water for at least 15 minutes.
Skin: Rinse with water.
Other: Consumer product packages have a caution statement: USE ONLY AS INTENDED. KEEP OUT OF
THE REACH OF CHILDREN. Do not spray directly toward face. If eye contact occurs, rinse well with
water.
SECTION V - FIRE FIGHTING INFORMATION
LEL: N/A UEL: N/A
Flash Point (Method Used): >> 141?F (cc) Explosive Limits:
Extinguishing Media: Use CO2, water, or dry chemical.
Special Fire Fighting Procedures:. N/A
Unusual Fire Hazards: N/A
Conditions to Avoid: None
Unstable:
Stability
Stable: X
Incompatibility (Materials to Avoid): None known
Hazardous Decomposition/By Products: None known
Conditions to Avoid: None
May Occur:
Hazardous Polymerization:
Will Not Occur: X
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: Use chemical goggles and protective gloves (rubber, neoprene) during spill clean-up.
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE OR PROVINCIAL AND LOCAL REGULATIONS. Slowly flush down sewer with excess water or
dispose as liquid scrap. Discard empty container in trash. Do not landfill liquids.
Steps To Be Taken in Case Material is Released or Spilled: Use water spray to dilute and/or wash away spills to
avoid exposure and to protect persons working to stop/repair leak. Any spills are to be prevented from entering
waterways. Sorbents may be used.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Store at room temperature.
Other Precautions: None
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FEBREZE FABRIC REFRESHER MSDS (Continued) Page 3 of 4
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): No special requirements with casual exposure.
Local Exhaust: Not necessary. Special: None
Ventilation
.
Mechanical (General): Acceptable Other: None
Eye Protection: None required with normal consumer use.
Industrial Setting: If a splash of solution is likely, chemical goggles may be needed.
Protective Gloves: None required with normal consumer use.
Industrial Setting: Minimize skin contact with protective gloves (rubber, neoprene).
Other Protective Equipment: None required with normal consumer use.
Industrial Setting: Use ventilation to minimize exposure to vapor or mist (ethanol).
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Specific Gravity (H2O=1): ca. 1
Boiling Point F: ~212篎
Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): ca. 95
Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/K
Freezing Point: N/A
Odor Threshold: N/A
Coefficient of Water/Oil Distribution: N/A pH (1% solution): 2.5-7.5
Density: ca 0.1 g/mL Solubility in Water: Soluble
Appearance and Odor: Clear liquid. Product is Reserve Alkalinity: N/A
perfumed.
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None known
Materials to Avoid: None
Hazardous Decomposition Products: None known
Other Recommendations: None
SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): >5000 mg/kg
SECTION XII - ECOLOGICAL INFORMATION
No concerns at relevant environmental concentrations.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Slowly flush down sewer with excess water or dispose as liquid scrap. Disposal is to be
performed in compliance with all Federal, State or Provinical and local regulations. Discard empty container in
trash. Do not landfill liquids.
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FEBREZE FABRIC REFRESHER MSDS (Continued) Page 4 of 4
SECTION XIV - TRANSPORT INFORMATION
The finished, packaged product is non-hazardous under DOT.
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules
(SNURs) under TSCA ?.
No components of Febreze are subject to California Proposition 65.
Chemical Name CERCLA RQ
Ethanol 100 lbs
Hydrochloric Acid 5000 lbs
EPCRA (SARA Title III) Section 313 Toxic Chemical: Hydrochloric Acid 1.0% De Minimis Concentration
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified
with Hazard Criteria of the Canadian Controlled Products Regulation (CPR) and this MSDS contains all required
information.
SECTION XVI - OTHER INFORMATION
*N/A. - Not Applicable *N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company's knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to
any property resulting from misuse of the controlled product.
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