Safety data sheet
SONOLASTIC NP1 CARB WHITE
Revision date : 2008/08/20 Page: 1/7
Version: 2.1 (30368491/MDS_GEN_US/EN)
1. Substance/preparation and company identification
Company 24 Hour Emergency Response Information
BASF Construction Chemicals CHEMTREC: 1-800-424-9300
100 Campus Drive BASF HOTLINE: 1-800-832-HELP
Florham Park, NJ 07932
2. Composition/information on ingredients
CAS Number Content (W/W) Chemical name
1317-65-3 10.0 - 30.0 % Limestone
13463-67-7 3.0 - 7.0 % titanium dioxide
112-62-9 3.0 - 7.0 % methyl oleate
8052-41-3 1.0 - 5.0 % Stoddard solvent
14807-96-6 1.0 - 5.0 % talc
3290-92-4 1.0 - 5.0 % 2-Propenoic acid, 2-methyl-,
2-ethyl-2-[[(2-methyl-1-oxo-2-propenyl)oxy]methyl]-1,3-propanedi
yl ester
1305-78-8 1.0 - 5.0 % calcium oxide
584-84-9 0.1 - 1.0 % toluene-2,4-diisocyanate
14808-60-7 0.1 - 1.0 % crystalline silica
3. Hazard identification
Emergency overview
WARNING: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
MAY BE HARMFUL IF INHALED.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
This product contains isocyanates.
Prolonged or repeated skin contact may cause sensitization or allergic reactions.
Avoid contact with the skin, eyes and clothing.
Wash thoroughly after handling.
Keep container tightly closed.
No exposure to respirable Crystalline (quartz) Silica anticipated with recommended use of product.
No exposure to respirable titanium dioxide anticipated with recommended use of product.
Potential health effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for
gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.
Acute toxicity:
Safety data sheet
SONOLASTIC NP1 CARB WHITE
Revision date : 2008/08/20 Page: 2/7
Version: 2.1 (30368491/MDS_GEN_US/EN)
Overexposure may cause CNS depression including headache, dizziness, nausea and loss of consciousness.
Based on the properties of the isocyanate components and considering toxicological data on similar product,
this product may cause acute irritation and/or sensitization of the respiratory system leading to an asthmatic
condition, wheeziness and tightness of the chest. Sensitized persons may subsequently show asthmatic
symptoms when exposed to atmospheric concentrations well below the occupational exposure limit. Repeated
inhalation may lead to a permanent respiratory disability.
Information on: toluene-2,4-diisocyanate
Very toxic by inhalation.
Virtually nontoxic after a single ingestion.
Virtually nontoxic after a single skin contact.
Irritation:
Irritating to eyes, respiratory system and skin. Prolonged or repeated contact may result in dermatitis.
Sensitization:
May cause sensitization by inhalation and skin contact.
Information on: toluene-2,4-diisocyanate
May cause sensitization by inhalation and skin contact.
Repeated dose toxicity:
Overexposure may cause CNS depression including headache, dizziness, nausea and loss of consciousness.
Information on: crystalline silica
This product may contain greater than 0.1% crystalline silica.
Repeated exposure to high concentrations results in silicosis, a lung disease characterized by
coughing, difficult breathing, wheezing, scarring of the lungs, and repeated, non-specific chest
illnesses.
Information on: Stoddard solvent
Overexposure may cause liver and kidney toxicity.
Repeated exposures may result in pulmonary congestion.
Information on: toluene-2,4-diisocyanate
The substance may cause damage to the lung even after repeated inhalation of low doses, as shown
in animal studies.
4. First-aid measures
If inhaled:
Remove victim to fresh air and away from exposure immediately. If not breathing, give artificial respiration.
Seek medical attention.
If in eyes:
Flush with copious amounts of water for at least 15 minutes. If symptoms persist, seek medical advice.
If swallowed:
Do not induce vomiting unless told to by a poison control center or doctor. If person is conscious and can
swallow, give two glasses of water.
5. Fire-fighting measures
Flash point: 185 癋
Autoignition: No data available.
Lower explosion limit: No data available.
Upper explosion limit: No data available.
Suitable extinguishing media:
carbon dioxide, dry extinguishing media, foam, water fog
Hazards during fire-fighting:
Burning produces harmful and toxic fumes.
Safety data sheet
SONOLASTIC NP1 CARB WHITE
Revision date : 2008/08/20 Page: 3/7
Version: 2.1 (30368491/MDS_GEN_US/EN)
Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.
Further information:
Sealed containers should be protected against heat as this results in pressure build-up. Keep containers cool
by spraying with water if exposed to fire.
6. Accidental release measures
Personal precautions:
Use personal protective clothing. Avoid contact with the skin, eyes and clothing.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Cleanup:
Dike spillage. Vacuum up spilled product. Pick up with inert absorbent material (if possible). Dispose of
absorbed material in accordance with regulations.
7. Handling and storage
Handling
General advice:
Keep away from sources of ignition - No smoking. Ensure thorough ventilation of stores and work areas.
Storage
General advice:
Keep container tightly closed.
8. Exposure controls and personal protection
Components with workplace control parameters
Limestone OSHA PEL 5 mg/m3 Respirable fraction ; PEL 15 mg/m3 Total dust ;
titanium dioxide OSHA PEL 15 mg/m3 Total dust ;
ACGIH TWA value 10 mg/m3 ;
Stoddard solvent OSHA PEL 500 ppm 2,900 mg/m3 ;
ACGIH TWA value 100 ppm ;
talc OSHA TWA value 20 millions of particles per cubic foot of air ; TWA
value 2.4 millions of particles per cubic foot of air Respirable ;
TWA value 0.1 mg/m3 Respirable ; TWA value 0.3 mg/m3
Total dust ;
ACGIH TWA value 2 mg/m3 Respirable fraction ;
calcium oxide OSHA PEL 5 mg/m3 ;
ACGIH TWA value 2 mg/m3 ;
toluene-2,4-diisocyanate OSHA CLV 0.02 ppm 0.14 mg/m3 ;
ACGIH TWA value 0.005 ppm ; STEL value 0.02 ppm ;
crystalline silica OSHA TWA value 2.4 millions of particles per cubic foot of air
Respirable ; TWA value 0.1 mg/m3 Respirable ; TWA value
0.3 mg/m3 Total dust ;
ACGIH TWA value 0.025 mg/m3 Respirable fraction ;
Advice on system design:
Provide local exhaust ventilation to maintain recommended P.E.L.
Safety data sheet
SONOLASTIC NP1 CARB WHITE
Revision date : 2008/08/20 Page: 4/7
Version: 2.1 (30368491/MDS_GEN_US/EN)
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) respirator as
necessary.
Hand protection:
Wear chemical resistant protective gloves.
Eye protection:
Safety glasses with side-shields. Wear face shield if splashing hazard exists.
Body protection:
Impermeable protective clothing
General safety and hygiene measures:
Precautions must be taken so that persons handling isocyanates do not breathe the vapors or have it contact
the eyes or skin. Food, beverages, and tobacco products shall not be carried, stored, or consumed where this
material is in use. Hands and/or face should be washed before breaks and at the end of the shift. Handle in
accordance with good industrial hygiene and safety practice.
9. Physical and chemical properties
Form: paste
Odour: slight odour
Colour: pigmented
pH value: Not applicable
Freezing point: No data available.
Boiling point: No data available.
Vapour pressure: No data available.
Relative density: 1.21
Vapour density: No data available.
Partitioning coefficient No data available.
n-octanol/water (log Pow):
Solubility in other solvents: insoluble
10. Stability and reactivity
Conditions to avoid:
Avoid prolonged exposure to extreme heat. Avoid moisture.
Substances to avoid:
strong oxidizing agents
Hazardous reactions:
The product is chemically stable.
No hazardous reactions when stored and handled according to instructions.
Decomposition products:
Possible thermal decomposition products: carbon oxides, nitrogen oxides, aromatic isocyanates,
gases/vapours
11. Toxicological information
Acute toxicity
Safety data sheet
SONOLASTIC NP1 CARB WHITE
Revision date : 2008/08/20 Page: 5/7
Version: 2.1 (30368491/MDS_GEN_US/EN)
Oral:
No data available.
Information on: calcium oxide
LD50/rat: 500 - 2,000 mg/kg
----------------------------------
Inhalation:
No data available.
Dermal:
No data available.
Sensitization:
Can sensitize the skin and/or respiratory tract of allergic persons.
Chronic toxicity
Carcinogenicity:
IARC has determined that there is sufficient evidence of carcinogenicity in both humans and experimental
animals for inhaled crystalline silica in the form of quartz or cristobalite.
Information on: crystalline silica
The International Agency for Research on Cancer (IARC) has classified this substance as a Group 1 (known)
human carcinogen.
Information on: titanium dioxide
IARC (International Agency for Research on Cancer) has classified this substance as group 2B (The agent is
possibly carcinogenic to humans).
In long-term studies in rats in which the substance was given by inhalation, a carcinogenic effect was
observed.
Tumors were only observed in rats after chronic inhalative exposure to high concentrations which caused
sustained lung inflammation.
In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not
observed.
Dermal exposure is not expected to be carcinogenic.
----------------------------------
12. Ecological information
Environmental toxicity
Other ecotoxicological advice:
Ecological data are not available.
13. Disposal considerations
Waste disposal of substance:
Do not discharge into drains/surface waters/groundwater.
Dispose of in accordance with local authority regulations.
14. Transport information
Safety data sheet
SONOLASTIC NP1 CARB WHITE
Revision date : 2008/08/20 Page: 6/7
Version: 2.1 (30368491/MDS_GEN_US/EN)
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
15. Regulatory information
Federal Regulations
Registration status:
TSCA, US released / listed
OSHA hazard category: IARC 1, 2A or 2B carcinogen, NTP listed carcinogen, Chronic target organ
effects reported, OSHA PEL established, ACGIH TLV established
SARA hazard categories (EPCRA 311/312): Acute, Chronic
SARA 313:
CAS Number Chemical name
584-84-9 toluene-2,4-diisocyanate
State regulations
State RTK
CAS Number Chemical name State RTK
1317-65-3 Limestone MA, PA
13463-67-7 titanium dioxide MA, NJ, PA
112-62-9 methyl oleate MA
14807-96-6 talc MA, NJ, PA
1305-78-8 calcium oxide MA, NJ, PA
584-84-9 toluene-2,4-diisocyanate MA, NJ, PA
14808-60-7 crystalline silica MA, NJ, PA
CA Prop. 65:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
16. Other information
HMIS III rating
Health: 2? Flammability: 1 Physical hazard: 0
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the substance
possesses essentially no hazard; a rating of four indicates high hazard.
Safety data sheet
SONOLASTIC NP1 CARB WHITE
Revision date : 2008/08/20 Page: 7/7
Version: 2.1 (30368491/MDS_GEN_US/EN)
Local contact information
END OF DATA SHEET
|