CITCOOL?22 Concentrate
Material Safety Data Sheet
CITGO Petroleum Corporation
639322001
MSDS No.
P.O. Box 4689 Hazard Rankings
Houston, TX 77210 Revision Date 10/26/2004
HMIS NFPA
IMPORTANT: Read this MSDS before handling or disposing of this product and pass this 2 2
Health Hazard *
information on to employees, customers and users of this product.
Fire Hazard 0 0
Emergency Overview 0
Reactivity 0
Physical State Liquid.
* = Chronic Health Hazard
Clear, Orange to Sweetish.
Color Odor
Amber. (undiluted)
Clear, Yellow. (with
5% water dilution)
CAUTION: Protective Equipment
Can cause eye, skin or respiratory tract irritation.
Minimum Recommended
See Section 8 for Details
SECTION 1. PRODUCT IDENTIFICATION
CITCOOL?22 Concentrate (800) 248-4684
Trade Name Technical Contact
Product Number Medical Emergency
639322001 (832) 486-4700
Mixture. (800) 424-9300
CAS Number CHEMTREC Emergency
(United States Only)
Metalworking fluid
Product Family
Metalworking fluid;
Synonyms
CITGO?Material Code No.: 639322001
SECTION 2. COMPOSITION
Concentration (%)
Component Name(s) CAS Registry No.
Proprietary Ingredients Proprietary Mixture 5 - 25
1, 2, 3 benzotriazole 95-14-7 1 - 4.9
2,2',2''-(Hexahydro-1,3,5-triazine-1,3,5-triyl) triethanol 4719-04-4 0.1 - 0.9
SECTION 3. HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.
Major Route(s) of Entry Skin contact. Eye contact. Inhalation.
Signs and Symptoms of Acute Exposure
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CITCOOL?22 Concentrate
Product mist can irritate the mucous membranes of the nose, the throat, bronchi, and lungs.
Inhalation
Eye Contact This product can cause transient mild eye irritation with short-term contact with liquid sprays
or mists. Symptoms include stinging, watering, redness, and swelling.
Skin Irritant. This material can cause moderate skin irritation with short-term contact based
Skin Contact
upon data from components or similar materials.
Ingestion If swallowed, large volumes of material can cause generalized depression, headache,
drowsiness, nausea, vomiting and diarrhea. Smaller doses can cause a laxative effect. If
aspirated into the lungs, liquid can cause lung damage.
Chronic Health Effects Prolonged or repeated skin contact can cause irritation and inflammation characterized by
Summary drying, or cracking skin (dermatitis). In addition, incidents of allergic contact dermatitis have
been reported from exposure to some used metal working fluids. Repeated exposure to
metalworking fluid mists at concentrations above applicable workplace exposure levels have
been associated with respiratory irritation or other pulmonary effects. Exposure to microbial
contaminants found in certain used metalworking fluids have been associated with asthma
and a lung inflammation condition known as hypersensitivity pneumonitis. Symptoms are
similar to pneumonia including headache, cough and chest pain. Repeated occurrences of
acute hypersensitivity pneumonitis can result in irreversible lung damage.
Disorders of the following organs or organ systems that may be aggravated by significant
Conditions Aggravated
exposure to this material or its components include: Skin, Respiratory System
by Exposure
Target Organs May cause damage to the following organs: upper respiratory tract, skin, eye, lens or cornea.
Carcinogenic Potential This product is not known to contain any components at concentrations above 0.1% which
are considered carcinogenic by OSHA, IARC or NTP.
OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present,
the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard (29 CFR
1910.1200).
OSHA Physical Hazard Classification
OSHA Health Hazard Classification
Combustible Explosive Pyrophoric
Irritant Sensitizer
X
Highly Toxic Water-reactive
Toxic Oxidizer
Flammable
Corrosive Carcinogenic Compressed Gas Organic Peroxide Unstable
SECTION 4. FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid.
For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If
Inhalation
breathing is difficult, 100 percent humidified oxygen should be administered by a qualified
individual. Seek medical attention immediately. Keep the affected individual warm and at
rest.
Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while
Eye Contact
occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness,
or pain persists.
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CITCOOL?22 Concentrate
If burned by hot material, cool skin by quenching with large amounts of cool water. For
Skin Contact
contact with product at ambient temperatures, remove contaminated shoes and clothing.
Wipe off excess material. Wash exposed skin with mild soap and water. Seek medical
attention if tissue appears damaged or if pain or irritation persists. Thoroughly clean
contaminated clothing before reuse. Discard contaminated leather goods. If material is
injected under the skin, seek medical attention immediately.
Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless
Ingestion
directed to by a physician. Never give anything by mouth to a person who is not fully
conscious. If significant amounts are swallowed or irritation or discomfort occurs, seek
medical attention immediately.
INGESTION: The viscosity range of the product(s) represented by this MSDS is greater than
Notes to Physician
100 SUS at 100癋. There is a low risk of aspiration upon ingestion Careful gastric lavage or
emesis may be considered to evacuate large quantities of material.
SECTION 5. FIRE FIGHTING MEASURES
Not applicable.
NFPA Flammability
Classification
Not applicable.
Flash Point
Upper Flammable Limit
Lower Flammable Limit No data. No data.
Autoignition Not available.
Temperature
Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides
Products of sulfur and/or nitrogen.
Special Properties This is an aqueous solution. After the water component evaporates, the remaining material
will burn.
Extinguishing Media Use dry chemical, "alcohol" foam or Carbon Dioxide. Water may be ineffective as an
extinguishing medium, but may be used to cool fire-exposed containers.
Firefighters must use full bunker gear including NIOSH-approved positive pressure
Protection of Fire
self-contained breathing apparatus to protect against potential hazardous combustion or
Fighters
decomposition products and oxygen deficiencies.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For
more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal
Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS.
Do not touch damaged containers or spilled material unless wearing appropriate protective
equipment. Slipping hazard; do not walk through spilled material. Stop leak if you can do so
without risk. For small spills, absorb or cover with dry earth, sand, or other inert
non-combustible absorbent material and place into waste containers for later disposal.
Contain large spills to maximize product recovery or disposal. Prevent entry into waterways or
sewers. In urban area, cleanup spill as soon as possible. In natural environments, seek
cleanup advice from specialists to minimize physical habitat damage. This material will float
on water. Absorbent pads and similar materials can be used. Comply with all laws and
regulations.
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CITCOOL?22 Concentrate
SECTION 7. HANDLING AND STORAGE
Dilute with water in accordance with prescribed recommendations prior to use. Avoid
Handling
breathing vapors or spray mists. Avoid contact with eyes, skin or clothing. Avoid
contamination and extreme temperatures to minimize product degradation. Empty containers
may contain product residues that can ignite with explosive force. Do not pressurize, cut,
weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential
ignition sources. Consult appropriate federal, state and local authorities before reusing,
reconditioning, reclaiming, recycling or disposing of empty containers and/or waste residues
of this product. Traces of formaldehyde and other thermal decomposition products may form
at temperatures above 150?C (302篎). FOR INDUSTRIAL USE ONLY
Keep container closed. Do not store with strong oxidizing agents. Do not store at elevated
Storage
temperatures. Avoid storing product in direct sunlight for extended periods of time. Consult
appropriate federal, state and local authorities before reusing, reconditioning, reclaiming,
recycling or disposing of empty containers or waste residues of this product.
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations
of mists and/or vapors below the recommended exposure limits (see below). An eye wash
station and safety shower should be located near the work-station.
Personal Protective Personal protective equipment should be selected based upon the conditions under which
Equipment this material is used. A hazard assessment of the work area for PPE requirements should
be conducted by a qualified professional pursuant to OSHA regulations. The following
pictograms represent the minimum requirements for personal protective equipment. For
certain operations, additional PPE may be required.
Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in
industrial settings. Wear goggles and/or face shield if splashing or spraying is anticipated.
Wear goggles and face shield if material is heated above 125癋 (51癈). Have suitable eye
wash water available.
Hand Protection Avoid skin contact. Use gloves constructed of chemical resistant materials such as
neoprene or heavy nitrile rubber or appropriate barrier creams with prolonged or repeated
contact. If the product is processed or handled at elevated temperature, protect against
thermal burns by using heat-resistant (insulated) gloves. Do not wear gloves or loose fitting
clothing around rotating or moving equipment. Use good personal hygiene practices.
Use clean protective clothing (e.g., neoprene or Tyvek? if splashing or spraying conditions
Body Protection
are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat.
If significant contact occurs, remove oil-contaminated clothing as soon as possible and
promptly shower. Launder contaminated clothing before reuse or discard. Wear heat
protective boots and protective clothing when handling material at elevated temperatures.
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CITCOOL?22 Concentrate
Airborne concentration will determine the level of respiratiory protection required.
Respiratory Protection
Respiratory protection is normally not required unless the product is heated or misted. For
known or anticipated vapor or mist concentrations above the occupational exposure
guidelines (see below), use a NIOSH-approved organic vapor respirator equipped with a
dust/mist prefilter if adequate protection is provided. For unknown vapor concentrations or
concentrations exceeding respirator protection factors, use a positive-pressure,
pressure-demand, self-contained breathing apparatus (SCBA). Respirators should be used
in accordance with OSHA requirements (29 CFR 1910.134).
Use good personal hygiene practices. Wash hands and other exposed skin areas with
General Comments
plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities, or
leaving work. DO NOT use gasoline, kerosene, solvents, or harsh abrasive skin cleaners.
Occupational Exposure Guidelines
Substance Applicable Workplace Exposure Levels
Metalworking fluid NIOSH (United States).
TWA: 0.4 mg/m 3 8 hour(s). Form: *Thoracic particulate mass
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL)
Sweetish.
Odor
Color
Liquid. Clear, Orange to
Physical State
Amber. (undiluted)
Clear, Yellow. (with
5% water dilution)
>1 (Air = 1)
Vapor
1.04 (Water = 1) 8.8
Specific Gravity pH
Density
Boiling Range 100癈 (212癋) -25癈 (-13癋)
Melting/Freezing
Point
Volatility <625 g/l VOC (w/v)
Not available.
Vapor Pressure
Viscosity
Easily soluble in cold water. not available
Solubility in
(cSt @ 40癈)
Water
Not applicable.
Flash Point
No additional information.
Additional
Properties
SECTION 10. STABILITY AND REACTIVITY
Hazardous Polymerization Not expected to occur.
Stable under
Chemical Stability
recommended storage
and handling conditions
(see section 7).
Keep away from water reactive materials.
Conditions to Avoid
This material is incompatible with materials that are reactive with hydroxyl compounds, strong
Materials
oxidizers and acids.
Incompatibility
No additional hazardous decomposition products were identified other than the combustion
Hazardous
products identified in Section 5 of this MSDS.
Decomposition
Products
MSDS No. Revision Date
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CITCOOL?22 Concentrate
SECTION 11. TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification
in Section 3 of this MSDS.
Toxicity Data
Metalworking Fluid, Soluble:
Acute and chronic respiratory responses have been reported in occupational exposures to
metal working fluids (MWF). In addition, exposure to MWF mists can aggravate existing
respiratory conditions. Chronic effects of overexposure to MWF mists can include sinusitis,
persistent cough, asthma, increased respiratory tract secretions and airway constriction.
Certain studies have suggested that bacterial endotoxin in MWF can result in increased
respiratory tract irritation among the exposed population. Endotoxins can stimulate alveolar
macrophage release of cytokine mediators that are involved in broncho-constriction and
inflammation.
Hypersensitivity pneumonitis (also known as allergic alveolitis) has been reported among
automobile workers exposed to MWF. Hypersensitivity pneumonitis is a diffuse interstitial
granulomatous lung disease believed to be associated with an immunologic reaction of the
lung to repeated inhalation of foreign antigens. In the acute phase, signs and symptoms
include alveolar inflammation and influenze-like symptoms. In the chronic phase and
following repeated exposures, it is characterized by pulmonary fibrosis. Reoccurring
episodes of acute hypersensitivity pneumonitis can lead to progressive, irreversible lung
impairment.
SECTION 12. ECOLOGICAL INFORMATION
Ecological effects testing has not been conducted on this product. A biocide has been added
Ecotoxicity
for protection against microbial growth. Product released to the environment can be
hazardous to plants, animals or aquatic life.
Environmental Fate This product is miscible in water and is expected to readily disperse in marine environments.
SECTION 13. DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is
the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal
methodologies for spent materials and residues at the time of disposition.
Conditions of use may cause this material to become a "hazardous waste", as defined by
federal or state regulations. It is the responsibility of the user to determine if the material is a
"hazardous waste" at the time of disposal. Transportation, treatment, storage, and disposal
of waste material must be conducted in accordance with RCRA regulations (see 40 CFR 260
through 40 CFR 271). State and/or local regulations may be more restrictive. Contact the
RCRA/Superfund Hotline at (800) 424-9346 or your regional US EPA office for guidance
concerning case specific disposal issues. Empty drums and pails retain residue. DO NOT
pressurize, cut, weld, braze, solder, drill, grind, or expose this product's empty container to
heat, flame, or other ignition sources. DO NOT attempt to clean it. Empty drums and pails
should be drained completely, properly bunged or sealed, and promptly sent to a
reconditioner.
MSDS No. Revision Date
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CITCOOL?22 Concentrate
SECTION 14. TRANSPORT INFORMATION
The shipping description below may not represent requirements for all modes of transportation, shipping
methods or locations outside of the United States.
Not regulated by the U.S. Department of Transportation as a hazardous material.
US DOT Status
Not regulated.
Proper Shipping Name
Not regulated. Not applicable.
Hazard Class Packing Group(s)
Not regulated.
UN/NA Number
Reportable Quantity A Reportable Quantity (RQ) has not been established for this material.
Placard(s) Not applicable.
Emergency Response
Guide No.
Not available.
HAZMAT STCC No.
Not a DOT "Marine
MARPOL III Status
Pollutant" per 49 CFR
171.8.
SECTION 15. REGULATORY INFORMATION
TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA)
inventory.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 302/304
facilities subject to Subparts 302 and 304 to submit emergency planning and notification
Emergency Planning
information based on Threshold Planning Quantities (TPQs) and Reportable Quantities
and Notification
(RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No
components were identified.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 311/312 Hazard
facilities subject to this subpart to submit aggregate information on chemicals by "Hazard
Identification
Category" as defined in 40 CFR 370.2. This material would be classified under the following
hazard categories:
Acute (Immediate) Health Hazard, Chronic (Delayed) Health Hazard
This product contains the following components in concentrations above de minimis levels
SARA 313 Toxic
that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section
Chemical Notification
313 of SARA: No components were identified.
and Release Reporting
The Comprehensive Environmental Response, Compensation, and Liability Act of 1980
CERCLA
(CERCLA) requires notification of the National Response Center concerning release of
quantities of "hazardous substances" equal to or greater than the reportable quantities (RQ's)
listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not
include petroleum, including crude oil or any fraction thereof which is not otherwise
specifically designated in 40 CFR 302.4. This product or refinery stream is not known to
contain chemical substances subject to this statute. However, it is recommended that you
contact state and local authorities to determine if there are any other reporting requirements
in the event of a spill.
Clean Water Act Discharges or spills of this material onto or in waters of the United States, adjoining shorelines,
(CWA) or into conduits leading to surface waters of the US without proper Federal or State permits
should be reported to the National Response Center at (800) 424-8802.
MSDS No. Revision Date
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CITCOOL?22 Concentrate
California This material may contain the following components which are known to the State of California
Proposition 65 to cause cancer, birth defects or other reproductive harm, and may be subject to the
requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5):
Formaldehyde.: 0.015%
New Jersey New Jersey RTK: 639322001
Right-to-Know Label
No additional regulatory remarks.
Additional Regulatory
Remarks
SECTION 16. OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.
REVISION INFORMATION
2.0
Version Number
10/26/2004
Revision Date
Printed on 10/26/2004.
Print Date
ABBREVIATIONS
AP: Approximately EQ: Equal >: Greater Than <: Less Than NA: Not Applicable ND: No Data NE: Not Established
ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association
IARC: International Agency for Research on Cancer NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
NIOSH: National Institute of Occupational Safety and Health
NPCA: National Paint and Coating Manufacturers Association HMIS: Hazardous Materials Information System
NFPA: National Fire Protection Association EPA: US Environmental Protection Agency
DISCLAIMER OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED
REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE
FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN
INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR
PARTICULAR PURPOSE.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE
BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO
NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE
ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE
PRODUCT.
***** END OF MSDS *****
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