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MSDS Material Safety Data Sheet
CAS

7732-18-5 4719-04-4 7664-41-7

File Name: 7732-18-5_4719-04-4_7664-41-7.asp

                                     Material Safety Data Sheet
Material Name: Gerdau Bond 83-309002

* * * Section 1 - Chemical Product and Company Identification * * *
Manufacturer Information
Gerdau Ameristeel Phone: (800) 876-3626
4221 West Boy Scout Blvd.
Suite 600 Emergency # 800-424-9300 CHEMTREC
Tampa, FL 33607

* * * Section 2 - Hazards Identification * * *
Emergency Overview
May cause eye and skin irritation. Prolonged contact may cause sensitization.
Potential Health Effects: Eyes
May cause irritation.
Potential Health Effects: Skin
May cause irritation.
Potential Health Effects: Ingestion
Not considered a likely route of exposure under normal product use. May cause gastrointestinal irritation if
swallowed.
Potential Health Effects: Inhalation
May cause respiratory tract irritation.
HMIS Ratings: Health: 1 Fire: 0 HMIS Reactivity 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
* * * Section 3 - Composition / Information on Ingredients * * *

CAS # Component Percent
7732-18-5 Water >98
4719-04-4 Hexahydro-1,3,5-tris(2-hydroxyethyl)-S-triazine <1
7664-41-7 Ammonia <1

* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
First Aid: Skin
For skin contact, wash immediately with soap and water. If irritation persists, get medical attention.
First Aid: Ingestion
If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting.
First Aid: Inhalation
Move person to non-contaminated air. Call a physician if symptoms develop or persist. If the affected person is
not breathing, apply artificial respiration.
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.
None
Hazardous Combustion Products
Not Determined
Extinguishing Media
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Fire Fighting Equipment/Instructions
Because fire may produce thermal decomposition products, wear a self-contained breathing apparatus (SCBA)
with a full face piece operated in pressure-demand or positive-pressure mode.


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Page 1 of 4 Issue Date: 12/04/08 Revision: 1.0000 Print Date: 12/31/2008
Material Safety Data Sheet
Material Name: Gerdau Bond 83-309002

NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
No special containment necessary.
Clean-Up Procedures
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate
ventilation.
Evacuation Procedures
Isolate area. Keep unnecessary personnel away.
Special Procedures
None necessary.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Wear appropriate personal protective clothing to prevent eye and skin contact. Avoid breathing vapors or mists of
this product. Use with adequate ventilation. Do not take internally.
Storage Procedures
Keep container tightly closed.
* * * Section 8 - Exposure Controls / Personal Protection * * *
A: Component Exposure Limits
Ammonia (7664-41-7)
ACGIH: 25 ppm TWA
35 ppm STEL
OSHA: 35 ppm STEL; 27 mg/m3 STEL
NIOSH: 25 ppm TWA; 18 mg/m3 TWA
35 ppm STEL; 27 mg/m3 STEL

Engineering Controls
Use general ventilation and use local exhaust, where possible, in confined or enclosed spaces.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear appropriate eye protection to prevent eye contact.
Personal Protective Equipment: Skin
Use impervious gloves.
Personal Protective Equipment: Respiratory
If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection.
Personal Protective Equipment: General
Eye wash fountain is recommended.
* * * Section 9 - Physical & Chemical Properties * * *
Appearance: Odor:
Colorless None
Physical State: pH:
Liquid ND
Vapor Pressure: Vapor Density:
23 hPa (17 mm Hg) ND
Boiling Point: Melting Point:
>93癈 (>199癋) 0癈 (32癋)
Solubility (H2O): Specific Gravity:
Fully miscible 1 g/cm3
Evaporation Rate: VOC:
ND < 50 g/L
Octanol/H2O Coeff.: Flash Point:
ND ND
Flash Point Method: Upper Flammability Limit
ND ND
(UFL):
Lower Flammability Limit Burning Rate:
ND ND
(LFL):
Auto Ignition: ND



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Page 2 of 4 Issue Date: 12/04/08 Revision: 1.0000 Print Date: 12/31/2008
Material Safety Data Sheet
Material Name: Gerdau Bond 83-309002

* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
None
Incompatibility
None
Hazardous Decomposition
No dangerous decomposition products known.
Possibility of Hazardous Reactions
Will not occur.
* * * Section 11 - Toxicological Information * * *
Acute Dose Effects
A: General Product Information
No information available for the product.
B: Component Analysis - LD50/LC50
Water (7732-18-5)
Oral LD50 Rat: >90 mL/kg

Ammonia (7664-41-7)
Inhalation LC50 Rat: 5.1 mg/L/1H; Inhalation LC50 Rat:2000 ppm/4H; Oral LD50 Rat:350 mg/kg

Hexahydro-1,3,5-tris(2-hydroxyethyl)-S-triazine (4719-04-4)
Oral LD50 Rat: 763 mg/kg; Dermal LD50 Rat:>2 g/kg

Carcinogenicity
A: General Product Information
No information available for the product.
B: Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
No information available for the product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Ammonia (7664-41-7)
Test & Species Conditions
96 Hr LC50 Cyprinus carpio 1.1 mg/L
96 Hr LC50 Lepomis macrochirus 0.26-4.6 mg/L
96 Hr LC50 Pimephales promelas 0.73-2.35 mg/L
96 Hr LC50 Poecilia reticulata >1.5 mg/L
48 Hr EC50 Daphnia magna 25.4 mg/L


* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions

Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.


____________________________________________________________
Page 3 of 4 Issue Date: 12/04/08 Revision: 1.0000 Print Date: 12/31/2008
Material Safety Data Sheet
Material Name: Gerdau Bond 83-309002

* * * Section 14 - Transportation Information * * *
US DOT Information
Shipping Name: Not Regulated

* * * Section 15 - Regulatory Information * * *
US Federal Regulations

Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Ammonia (7664-41-7)
SARA 302: 500 lb TPQ
CERCLA: 100 lb final RQ; 45.4 kg final RQ

State Regulations

Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA RI
Ammonia 7664-41-7 Yes Yes Yes Yes Yes Yes

Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Additional Regulatory Information

Component Analysis - Inventory
Component CAS # TSCA CAN EEC
Water 7732-18-5 Yes DSL EINECS
Ammonia 7664-41-7 Yes DSL EINECS
Hexahydro-1,3,5-tris(2-hydroxyethyl)-S-triazine 4719-04-4 Yes DSL EINECS

* * * Section 16 - Other Information * * *
Other Information
The information herein is presented in good faith and believed to be accurate as of the effective date given.
However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities
comply with Federal, State or provincial, and local laws.
Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference
of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National
Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety
and Health Administration., NJTSR = New Jersey Trade Secret Registry.


End of Sheet




____________________________________________________________
Page 4 of 4 Issue Date: 12/04/08 Revision: 1.0000 Print Date: 12/31/2008

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