Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.01.2007 Version 1 Reviewed on 15.01.2007
1 Identification of substance:
?Product details:
?Trade name: Adefo Grundreiniger
?Application of the substance / the preparation Cleaning material/ Detergent
?Manufacturer/Supplier:
ADEFO-CHEMIE GmbH
Justus-von-Liebig-Str. 24-26
D-63128 Dietzenbach
Tel.: +49 6074 84239-0
Fax: +49 6074 84239-63
E-Mail: service@adefo-chemie.de
http://www.adefo-reinigungsmittel.de
?Informing department:
Tel.: +49 6074 84239-0
Fax: +49 6074 84239-63
E-Mail: service@adefo-chemie.de
?Emergency information: Tel.: +49 (0)6132-84463
2 Composition/Data on components:
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
sekund鋜es Alkansulfonat, Natriumsalz Xi; R 37-41 5.0-10%
CAS: 112-34-5 2-(2-butoxyethoxy)ethanol Xi; R 36 2.0-5.0%
EINECS: 203-961-6
CAS: 111-76-2 2-butoxyethanol Xn, Xi; R 20/21/22-36/38 2.0-5.0%
EINECS: 203-905-0
CAS: 68439-50-9 Fettalkoholpolyglykolether Xn, Xi, N; R 22-41-50 0.5-2.0%
CAS: 4719-04-4 Tri-N-(2-hydroxyethyl)-hexahydrotriazin Xn, Xi; R 22-43 < 0.5%
EINECS: 225-208-0
Main component: water 70-90%
?Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
?Hazard designation: void
?Information pertaining to particular dangers for man and environment
The product does not have to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from
technical literature and by information furnished by supplier companies.
4 First aid measures
?General information No special measures required.
?After inhalation Supply fresh air.
(Contd. on page 2)
GB
DR
Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.01.2007 Version 1 Reviewed on 15.01.2007
Trade name: Adefo Grundreiniger
(Contd. of page 1)
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
The product is not skin irritating.
?After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; instantly call for medical help.
5 Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
?For safety reasons unsuitable extinguishing agents Water with a full water jet.
?Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear self-contained breathing apparatus.
6 Accidental release measures
?Person-related safety precautions:
Wear protective clothing.
Particular danger of slipping on leaked/spilled product.
?Measures for environmental protection:
Do not allow to enter drainage system, surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
?Additional information:
No dangerous materials are released.
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
?Handling
?Information for safe handling: No special precautions necessary if used correctly.
?Information about protection against explosions and fires: No special measures required.
?Storage
?Requirements to be met by storerooms and containers: Store only in the original container.
?Information about storage in one common storage facility: Store away from foodstuffs.
?Further information about storage conditions: Store in a cool place.
?Recommended storage temperature: 5-30癈
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
(Contd. on page 3)
GB
DR
Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.01.2007 Version 1 Reviewed on 15.01.2007
Trade name: Adefo Grundreiniger
(Contd. of page 2)
?Components with limit values that require monitoring at the workplace:
111-76-2 2-butoxyethanol
WEL Short-term value: 50 ppm
Long-term value: 25 ppm
Sk
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Do not eat, drink or smoke while working.
?Breathing equipment: Not required.
?Protection of hands:
Protective gloves.
The protective gloves to be used must comply with the specifications of the EC directive 89/686/
EEC and the resultant standard EN 374.
This recommendation applies only to the product stated in the Safety Data Sheet and supplied by
us as well as to the purpose specified by us.
Only use chemical-protective gloves with CE-labelling of category III.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
Nitrile rubber, NBR
Butyl rubber, BR
Recommended thickness of the material: 0.5 mm
?Penetration time of glove material
Value for permeation: Level 6 (480 min)
The determined penetration times according to EN 374 part III are not performed under practical
conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,
is recommended.
?As protection from splashes gloves made of the following materials are suitable:
Synthetic gloves
Value for permeation: Level:
3 (60 min)
?Not suitable are gloves made of the following materials: Natural rubber, NR
?Eye protection: Safety glasses
9 Physical and chemical properties:
?General Information
Fluid
Form:
Brown
Colour:
Product specific
Odour:
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: 110癈
?Flash point: > 70癈
(Contd. on page 4)
GB
DR
Page 4/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.01.2007 Version 1 Reviewed on 15.01.2007
Trade name: Adefo Grundreiniger
(Contd. of page 3)
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive.
?Density at 20癈 1.05 g/cm?br>
?Solubility in / Miscibility with
Fully miscible
Water:
?pH-value at 20癈: 13
?Viscosity:
Not determined
dynamic:
Not determined
kinematic:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known
?Dangerous products of decomposition: No dangerous decomposition products known
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritant effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
The product is not subject to classification according to the calculation method of the General EC
Classification Guidelines for Preparations as issued in the latest version:
When used and handled according to specifications, the product does not have any harmful effects
according to our experience and the information provided to us.
12 Ecological information:
?Information about elimination (persistence and degradability):
The contained surfactants are biodegradable
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-
values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is
considerably reduced, so that after the use of the product the aqueous waste, emptied into drains,
is only low water-dangerous.
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No.648/2004 on detergents.
GB
(Contd. on page 5)
DR
Page 5/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.01.2007 Version 1 Reviewed on 15.01.2007
Trade name: Adefo Grundreiniger
(Contd. of page 4)
13 Disposal considerations
?Product:
?Recommendation
Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts
in accordance with Local Authority requirements.
?European waste catalogue
07 06 99 wastes not otherwise specified
?Uncleaned packagings:
?Recommendation:
Non contaminated packagings can be used for recycling.
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper
cleaning.
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
EAK-No. 15 01 10
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: -
?Maritime transport IMDG:
?IMDG Class: -
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: -
?Transport/Additional information: Not dangerous according to the above specifications.
15 Regulatory information
?Designation according to EC guidelines:
The product is not subject to classification according to the calculation methods of the "General
Classification Guideline for Preparations of the EC" as issued in the last version.
?Hazard-determining components of labelling:
Tri-N-(2-hydroxyethyl)-hexahydrotriazin
?Special designation of certain preparations:
Contains Tri-N-(2-hydroxyethyl)-hexahydrotriazin. May produce an allergic reaction.
?National regulations
?Technical instructions (air):
Class Share in %
NK 6.0
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
22 Harmful if swallowed.
36 Irritating to eyes.
(Contd. on page 6)
GB
DR
Page 6/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 15.01.2007 Version 1 Reviewed on 15.01.2007
Trade name: Adefo Grundreiniger
(Contd. of page 5)
36/38 Irritating to eyes and skin.
37 Irritating to respiratory system.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
50 Very toxic to aquatic organisms.
?Sources
Internal physical tests, MSDS of the ingredients
applicable EEC directives:
- 1999/45//EC last change 2006/8/EC
- 67/548/EC last change 2004/73/EC (29. ATP)
- 91/155/EC last change 2001/58/EC
GB
DR
|