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MATERIAL SAFETY DATA SHEET
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SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
LUBRIPLATE?Lubricants Co. Emergency Telephone Number:
129 Lockwood St. 1-800-255-3924-CHEM-TEL (24 hour)
Newark, NJ 07105 Telephone Number for information:
1-973-589-9150
SUBSTANCE: FISKE'S HP-76
TRADE NAMES/SYNONYMS:
PRODUCT USE: Petroleum lubricating oil
CREATION DATE: 04/03/2008
REVISION DATE: 03/05/2009
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SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT: Water
CAS NUMBER: 7732-18-5
EC NUMBER (EINECS): 231-791-2
PERCENTAGE: 70-75
COMPONENT: Triethanolamine
CAS NUMBER: 102-71-6
EC NUMBER (EINECS): 203-049-8
PERCENTAGE: 10-15
COMPONENT: Ricinoleic acid
CAS NUMBER: 61789-44-4
EC NUMBER (EINECS): 205-470-2
PERCENTAGE: 2-5
COMPONENT: Phosphate ester
CAS NUMBER: 68815-11-2
EC NUMBER (EINECS): not assigned
PERCENTAGE: 2-5
COMPONENT: Diethanolamine
CAS NUMBER: 111-42-2
EC NUMBER (EINECS): 203-868-0
PERCENTAGE: 0-2
COMPONENT: EDTA
CAS NUMBER: 105-38-9
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EC NUMBER (EINECS): not assigned
PERCENTAGE: 0-2
COMPONENT: Hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triaznine
CAS NUMBER: 4719-04-4
EC NUMBER (EINECS): 225-208-0
PERCENTAGE: 0-2
COMPONENT: Polyoxyalkylene
CAS NUMBER: NA
EC NUMBER (EINECS): NA
PERCENTAGE: 0-1
NOTE: The IP 346 value of the mineral oil is less than 3%
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SECTION 3 HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: Irritation
LONG TERM EXPOSURE: Lung damage
SKIN CONTACT:
SHORT TERM EXPOSURE: Irritation
LONG TERM EXPOSURE: Irritation, skin disorders
EYE CONTACT:
SHORT TERM EXPOSURE: Irritation
LONG TERM EXPOSURE: No information available
INGESTION:
SHORT TERM EXPOSURE: Diarrhea, difficulty breathing
LONG TERM EXPOSURE: no information on significant adverse effects
Significant Laboratory Data with Possible Relevance to Humans Health Hazard Evaluation: There are
reports that ingestion of diethanolamine (DEA) produced nervous system injury in dogs and rats. Heart and
salivary gland lesions have also been observed in mice treated with DEA cutaneously and in drinking water.
Rats given high doses of DEA developed anemia and testicular lesions. An increased incidence of some
skeletal variations suggestive of a slight developmental delay was seen only in the fetuses of rats given 1,500
mg/kg/day cutaneously which also caused significant maternal toxicity. However, no fetal malformations were
observed in either rats or rabbits similarly tested.
The National Toxicology Program has concluded that there is clear evidence of liver tumor and some evidence
of kidney tumor in mice dermally exposed for their lifetime to DEA. The significance of these findings and
their relevance to humans are not clear as DEA was not genotoxic (neither mutagenic nor clastogenic), and did
not induce tumors in rats or in transgenic mice similarly treated. Additional research to better understand the
significance of these observations to humans, if any, is underway.
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Recent analyses of diethanolamine and triethanolamine for N-nitrosodiethanolamine have not revealed its
presence at the detection limit of the test (20 ppb). However, amines may react with nitrites or other nitrosating
agents to form nitrosamines. Some nitrosamines have been shown to carcinogenic in laboratory animals.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS):
Health ?1
Flammability ?0
Reactivity ?0
Not a Controlled Product under (WHMIS) ?Canada Special Protection: See Section 8
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SECTION 4 FIRST AID MEASURES
INHALATION: None required
SKIN CONTACT: Remove any contaminated clothing and wash with soap and warm water.
EYE CONTACT: Flush with clear water for 15 minutes or until irritations subsides. If irritation persists,
consult a physician.
INGESTION: If ingested, call a physician immediately.
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SECTION 5 FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARDS: Intense heat may cause drums to rupture.
EXTINGUISHING MEDIA: Foam, Dry Chemical, Carbon Dioxide or Water Spray (Fog)
SPECIAL FIRE FIGHTING PROCEDURES: After water evaporates and fire starts, treat as an oil fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
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SECTION 6 ACCIDENTAL RELEASE MEASURES
OCCUPATIONAL RELEASE: Handle as an oil spill. Avoid breathing vapors or mist. Use adequate
ventilation.
WASTE DISPOSAL METHOD: Chemical waste disposal is governed by the Resource Conservation and
Recovery Act, as well as by other local, state, and federal laws and regulations.
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SECTION 7 HANDLING AND STORAGE
STORAGE: Keep containers closed when not in use. Do not handle of store near heat, sparks, flame, or
strong oxidants.
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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMITS:
OIL MIST IN AIR (Not Encountered in Normal Usage):
5 mg/m3 UK OES TWA
10mg/m3 UK OES STEL
VENTILATION: Provide local exhaust ventilation system. Ensure compliance with applicable exposure
limits.
EYE PROTECTION: Wear splash resistant safety goggles. Provide an emergency eye wash fountain and
quick drench shower in the immediate work area.
CLOTHING: Wear appropriate chemical resistant clothing.
GLOVES: Wear appropriate chemical resistant (nitrile) gloves.
RESPIRATOR: Consider the need for appropriate protective equipment, such as self-contained breathing
apparatus, adequate masks and filters. If concentrated vapors are present and adequate ventilation is
unavailable, use proper respirator for organic vapors.
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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: liquid
APPEARANCE: transparent
COLOUR: amber
PHYSICAL FORM: oil
ODOR: mild odor
BOILING POINT: >102 C
FREEZING POINT: Not available
FLASH POINT: Water solution ?does not apply
LOWER FLAMMABLE LIMIT: None
UPPER FLAMMABLE LIMIT: None
AUTO IGNITION: Not available
VAPOUR PRESSURE: <13 mm Hg at 25 C
VAPOR DENSITY (air=1): Not determined
SPECIFIC GRAVITY (water=1): 1.03
DENSITY: not available
WATER SOLUBILITY: Soluble
pH: not available
VOLATILITY: not available
ODOR THRESHOLD: not available
EVAPORATION RATE (butyl acetate=1): <0.01
VISCOSITY: not available
COEFFICIENT OF WATER/OIL DISTRIBUTION: not available
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SECTION 10 STABILITY AND REACTIVITY
REACTIVITY: Stable at normal temperatures and pressures
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition. Avoid contact with
incompatible materials.
INCOMPATIBLES: Strong oxidants like liquid oxygen, concentrated oxygen
HAZARDOUS DECOMPOSITION:
Thermal decomposition products or combustion: oxides of carbon
POLYMERISATION: Will not polymerise.
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SECTION 11 TOXICOLOGICAL INFORMATION
Water:
TOXICITY DATA:
No data available
Triethanolamine:
TOXICITY DATA:
4,920 ul/kg oral-rat LD50
Ricinoleic acid:
TOXICITY DATA:
Greater than 5,000 mg/kg oral-rat LD50
Phosphate ester:
TOXICITY DATA:
No data available
Diethanolamine:
TOXICITY DATA:
No data available
EDTA:
TOXICITY DATA:
Greater than 2,000 mg/kg oral-rat LD50
Hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triaznine:
TOXICITY DATA:
No data available
Polyoxyalkylene:
TOXICITY DATA:
No data available
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SECTION 12 ECOLOGICAL INFORMATION
Not available
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SECTION 13 DISPOSAL CONSIDERATIONS
Dispose in accordance with all applicable regulations
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SECTION 14 TRANSPORT INFORMATION
LAND TRANSPORT ADR: No classification assigned.
LAND TRANSPORT RID: No classification assigned.
AIR TRANSPORT IATA: No classification assigned.
AIR TRANSPORT ICAO: No classification assigned.
MARITIME TRANSPORT IMDG: No classification assigned.
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SECTION 15 REGULATORY INFORMATION
EUROPEAN REGULATIONS:
EC CLASSIFICATION (CALCULATED): Not classified as dangerous.
Risk Phrases: R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
SARA/TITLE III, Section 313 Status ?Diethanolamine <2%
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SECTION 16 OTHER INFORMATION
The above information is furnished without warranty, expressed or implied, except that it is accurate to
the best knowledge of LUBRIPLATE Lubricants Company. The data on these sheets relates only to the
specific material designated herein. LUBRIPLATE Lubricants Company assumes no legal responsibility
for use or reliance upon this data.
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