Product Code 18N03AS
Revision Date 05/04/2010
Supersedes 10/13/2009
Material Safety Data Sheet Date Printed 05/11/2010
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
Identification of the Substance:
Trade Name: GLIDOX(TM) 500
Chemical Name: HYDROPEROXIDE, 2,6,6-TRIMETHYLBICYCLO[3.1.1]HEPTYL-
Use of the Substance:Polymerization initiator
Company Identification:
_______________________________________________________________________
European Headquarters
LyondellBasell Flavors & Fragrances, LLC LyondellBasell Flavors & Fragrances, LLC
P.O. Box 389 C/O SCM EUROPE
Jacksonville, FL 32201, USA Place de l'ALBERTINE 2
Telephone: 904-768-5800 B-1000 Brussels - Belgium
Fax:904-768-2200 Telephone: +32.2.289.05.10 Fax:+32.2.289.05.90
_______________________________________________________________________
Emergency Telephone: CHEMTREC: (USA, Canada): 1-800-424-9300 ;(All Others): 703-527-3887
2. COMPOSITION/INFORMATION ON INGREDIENTS
Typical
CAS Number EINECS Number Ingredient Weight %
6876-13-7 229-978-9 PINANE, CIS- 35.20
28324-52-9 248-969-0 PINANE HYDROPEROXIDE 54.50
4948-28-1 225-591-4 PINANOL, CIS-2- 3.10
20536-40-7 000-000-0 ISOCAMPHANE, ENDO- 1.90
473-55-2 207-467-1 PINANE, TRANS- 5.30
EU Classifications (refer to Section 16 for descriptions):
Symbol(s) Risk Phrase Code(s) Safety Phrase Code(s)
C,O R(10)-5-35 S15-37/39
3. HAZARDS IDENTIFICATION
This substance is classified as dangerous according to EU Directive 1999/45/EC.
Potential Health Effects
Acute Health Effects:
Contact with the undiluted material can cause eye and skin damage.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 1 of 7
Product Code 18N03AS
Revision Date 05/04/2010
Supersedes 10/13/2009
Material Safety Data Sheet Date Printed 05/11/2010
Chronic Health Effects:
Not Determined.
4. FIRST AID MEASURES
Inhalation:
Seek fresh air immediately. If breathing is difficult, seek medical advice.
Eye Contact:
Flush with water for at least 15 minutes. If irritation develops, get
medical attention.
Skin Contact:
Remove contaminated clothing. Wash affected areas with plenty of soap and
water. If irritation develops, seek medical advice.
Ingestion:
Drink lots of water to dilute substance. Get medical attention immediately
or contact a poison control center for advice.
5. FIRE FIGHTING MEASURES
Suitable Fire Extinguishing Media:
Carbon dioxide, dry chemical, foam.
Unsuitable Fire Extinguishing Media:
If water must be used, use as a spray only.
Special Exposure Hazards:
Avoid heat, sparks and open flames. There is a danger of EXPLOSIVE
THERMAL DECOMPOSITION. Keep temperatures below 176癋 (80癈). If fire
occurs near the product, use water to cool the containers. Fire
fighting should e done from a safe distance or a protected location.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, acrid fumes.
Special Protective Equipment for Fire Fighters:
Standard turnout gear for combustible and corrosive liquids.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Standard turnout gear for combustible and corrosive liquids.
Environmental Precautions:
Do not allow the substance or solutions of the substance to be discharged
into lakes, streams, ponds or public waters.
Cleanup Procedures:
Small spills should be absorbed by dirt, sand, or other absorbent. Large
spills may be pumped into containers for recovery/disposal.
7. HANDLING AND STORAGE
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 2 of 7
Product Code 18N03AS
Revision Date 05/04/2010
Supersedes 10/13/2009
Material Safety Data Sheet Date Printed 05/11/2010
Handling:
Wear safety glasses or goggles and rubber gloves or apron when
handling. Depending on local conditions, prolonged storage in sealed
drums will result in a gradual increase in internal pressure. A
periodic release of this pressure is necessary to prevent rupture of
the container.
Storage:
Store in a cool place in the original tightly closed contaiiner. Do
not store in close proximity to heat, sparks, open flames, strong
acids, strong bases. To minimize product degradation, avoid prolonged
exposure of the material to air. Keep container tightly closed when not
in use.
Ventilation:
Local mechanical exhaust may be needed in confined and warm areas.
Safety Stations:
An eyewash station and a safety shower should be readily available and
clearly marked.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits:
None found.
Exposure Controls:
Respiratory Protection:
A respirator is not normally required. If vapor concentration is suspected
to be high, use a NIOSH approved organic vapor respirator
Eye Protection:
Wear safety glasses or goggles.
Hand Protection:
Wear standard industrial type rubber gloves.
Skin Protection:
A rubber apron is recommended when handling the material for extended
periods of time.
Personal Hygiene:
Wash hands and other exposed areas of skin with soap and water after
handling the material.
Environmental Controls:
No environmental exposure controls required under Community environmental
protection laws.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 3 of 7
Product Code 18N03AS
Revision Date 05/04/2010
Supersedes 10/13/2009
Material Safety Data Sheet Date Printed 05/11/2010
9. PHYSICAL AND CHEMICAL PROPERTIES
General Information:
Property Result
Appearance: Pale yellow liquid.
Odor: Pine-type.
Important Health, Safety and Environmental Information:
Property Result
pH: Not determined.
Boiling Point: 298.4F (148.0C) (Thermal Analyzer)
Flash Point: 114F (46C) (Tag Closed Cup)
Melting Point: Not determined
Flammability: Not determined.
Explosive Properties: Do not heat above 176 F (80 C). Explosive thermal
decompostion may occur.
Oxidizing Properties: Organic Peroxide, Type F, Liquid, 54%
Vapor Pressure: Not Determined.
Solubility in Water (Weight%): Not determined
Solubility in Alcohol(Weight%): Not Determined.
Fat Solubility: Not Determined.
Partition Coefficient (n-Octanol/Water): Not determined
Viscosity: Not determined.
Vapor Density (air=1): NOT DETERMINED
Evaporation Rate (Butyl Acetate=1): Not determined.
Autoignition Temperature: Not Determined.
Specific Gravity: 0.959 @ 25 C
10. STABILITY AND REACTIVITY
Stability:
Substance is unstable and reactive at temperatures above 176 degrees F(80
C). Explosive thermal decomposition may occur.
Conditions to Avoid:
Do not heat above 176 degrees F (80 C) as explosive thermal decomposition
may occur.
Materials to Avoid:
Avoid contact with reducing agents, Friedel-Crafts catalysts, metals.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, acrid fumes.
11. TOXICOLOGICAL INFORMATION
Primary Target Organs: Eyes, skin.
Primary Entry Route(s): Eyes, Skin.
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 4 of 7
Product Code 18N03AS
Revision Date 05/04/2010
Supersedes 10/13/2009
Material Safety Data Sheet Date Printed 05/11/2010
Medical Conditions Aggravated by Overexposure No known conditions.
Acute Toxicity:
Parameter Result
Acute Oral Toxicity: Not determined.
Acute Inhalation Toxicity: Not Determined.
Acute Dermal Toxicity: Not determined
Eye Irritancy: Contact with the undiluted material may cause eye damage.
Dermal Irritancy: Contact with the undiluted material may cause skin damage.
Skin Sensitization: Not determined.
Mutagenicity: Not determined
Teratogenicity: Not determined.
12. ECOLOGICAL INFORMATION
Ecotoxicity: Not determined.
Mobility: Not determined.
Persistence and Degradability: Not determined.
Bioaccumulation Potential: Not determined.
Ozone Depleting Substances: None.
13. DISPOSAL CONSIDERATIONS
Disposal Methods: This material, if discarded, is considered a hazardous waste by EPA
regulations 40 CFR 261.
Safe Handling of Wastes: Refer to Section 8 for information pertaining to personal protective
equipment and exposure controls when handling this material for
disposal.
Community Provisions: Dispose of this material at a local, state or federally approved landfill,
incinerator or recovery facility.
14. TRANSPORT INFORMATION
Label Codes: ORGANIC PEROXIDE
DOT Proper Shipping Name (Bulk): UN3109, Organic Peroxide Type F, Liquid (Pinanyl
Hydroperoxide), 5.2, PGII
DOT Proper Shipping Name (Non-Bulk): UN3109, Organic Peroxide Type F, Liquid (Pinanyl
Hydroperoxide), 5.2, PGII
ERG: 145
Marine Pollutant: No
15. REGULATORY INFORMATION
Chemical Inventories Status:
USA (TSCA): Compliant
European Community (EINECS): Compliant
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 5 of 7
Product Code 18N03AS
Revision Date 05/04/2010
Supersedes 10/13/2009
Material Safety Data Sheet Date Printed 05/11/2010
Canada (DSL): Not Compliant
Australia (AICS): Compliant
Japan (IEC): Compliant
Korea (KECI/ECL): Not Compliant
Philippines (PICCS): Compliant
China (SEPA/CICS): Compliant
USA: Federal:
SARA Title III Section 302/304: None.
SARA Title III Section 311/312: Yes
SARA Title III Section 313: None.
Hazardous Air Pollutants: Methylisobutyl ketone; CAS No. 108-10-1; 0.1%
USA: States:
New Jersey RTK: Pinane Hydroperoxide; CAS No. 28324-52-9; 50.0 to 55.0%
International:
16. OTHER INFORMATION
EU Classifications:
Symbol Code(s): Symbol Phrase(s):
C,O CORROSIVE/OXIDIZING
Risk Phrase Codes: Risk Phrases:
R(10)-5-35 Flammable. Causes severe burns. Heating may cause an explosion.
Safety Phrase Codes: Safety Phrases:
S15-37/39 Keep away from heat. Wear suitable gloves.
U.S. NPCA/HMIS Hazardous Materials Information System
Health Flammability Reactivity Personal Protection*
2 3 2 C
0 - Minimal Hazard: No significant risk to health.
1 - Slight Hazard: Irritation or minor reversible injury possible.
2 - Moderate Hazard: Temporary or minor injury may occur.
3 - Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given.
4 - Severe Hazard: Life-threatening, major or permanent damage mayresult from single or repeated exposures.
* This rating will generally suffice for normal operating conditions.Please note however, that the type of personal
protection utilized may change based on specific use conditions (refer to Section 8).
Reason(s) for (Re)issue:
Legal entity change
Technical Contact(s):
Environmental and Regulatory Affairs Dept.
References:
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 6 of 7
Product Code 18N03AS
Revision Date 05/04/2010
Supersedes 10/13/2009
Material Safety Data Sheet Date Printed 05/11/2010
Acronyms: NTP(National Toxicology Program); IARC (International Agency for
Research on Cancer); OSHA (Occupational Health and Safety
Administration); DOT (U.S. Dept. of Transportation); NIOSH (National
Institute of Occupational Safety and Health)
The information contained in this MSDS relates to this specific product. The information may not be valid if the product is used in combination with
any other materials or in any process. It is the user's responsibility to satisfy himself as to the suitability and completeness of this information for
his own particular use.
Page 7 of 7
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