This safety data sheet is prepared in accordance with EU
directive 91/155/EC amended by Directive 2001/58/EC
SAFETY DATA SHEET
Natural stone colour intensifier for granite, blue stone and other natural stone
types
Identification of the substance/preparation and of the
1.
company/undertaking
Identification of the substance or preparation
: Natural stone colour intensifier for granite, blue stone and other natural stone types
Product name
: Is a professional product that deepens the coloiur of natural stone and completly revitalises
Product use
it.
Company/undertaking identification
: HG International b.v. : +31 (0)36 54 94 700
Manufacturer Telephone No.:
: Damsluisweg 70 : +31 (0)36 54 94 744
Address Fax
1332 EJ Almere : www.hginternational.com
Internet:
: Netherlands
Country
: HG UK
Importer
: Unit 11 Grange Way Business Park Whitehall Road Industrial Estate
Address
Uk Colchester Essex CO2 8HF
: +44.1206.795.200
Telephone No.:
: +44.1206.795.201
Fax
: United Kingdom (UK)
Country
Composition/information on ingredients
2.
: Preparation
Substance/preparation
EC Number
Ingredient name CAS number % Classification
United Kingdom (UK)
alkanes, c9-12-iso- 90622-57-4 292-459-0 30 - 100 Xn; R65
R66
R53
bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, 125-12-2 204-727-6 1 - 5 Xi; R38
exo-
See section 16 for the full text of the R Phrases declared
above
* Occupational Exposure Limit(s), if available, are listed in Section 8
Hazards identification
3.
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
: Xn; 65
Classification
66, 67
53
: Harmful: may cause lung damage if swallowed.
Human health hazards
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
: May cause long-term adverse effects in the aquatic environment.
Environmental hazards
See section 11 for more detailed information on health effects and symptoms.
Date of issue
5.05
Version Page: 1/6
15-11-2005. Version 5.05
This safety data sheet is prepared in accordance with EU
directive 91/155/EC amended by Directive 2001/58/EC
SAFETY DATA SHEET
Natural stone colour intensifier for granite, blue stone and other natural stone
types
First aid measures
4.
First aid measures
: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give
Inhalation
artificial respiration. Obtain medical attention.
: If swallowed, do NOT induce vomiting. Never give anything by mouth to an unconscious
Ingestion
person. Aspiration hazard if swallowed- can enter lungs and cause damage. Obtain medical
attention.
: Wash with soap and water. Get medical attention if irritation develops.
Skin Contact
: In case of contact, immediately flush eyes with a copious amount of water for at least 15
Eye contact
minutes. Get medical attention if irritation occurs.
: Not available.
Notes to physician
: Not available.
Specific treatments
See section 11 for more detailed information on health effects and symptoms.
Fire-fighting measures
5.
: In case of fire, use water spray (fog), foam, dry chemical or CO2 extinguisher or spray.
Extinguishing media
: Combustible liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in
Special exposure hazards
low or confined areas, travel a considerable distance to a source of ignition and flash
back. Runoff to sewer may create fire or explosion hazard.
Not available.
: These products are carbon oxides (CO, CO2).
Hazardous thermal
decomposition products
: Fire fighters should wear appropriate protective equipment and self-contained breathing
Special protective equipment for
fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental release measures
6.
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable
Personal Precautions
protective equipment (Section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
Environmental precautions
sewers.
: If emergency personnel are unavailable, contain spilled material. For small spills add
Methods for cleaning up
absorbent (soil may be used in the absence of other suitable materials) scoop up material and
place in a sealed, liquid-proof container for disposal. For large spills dike spilled material or
otherwise contain material to ensure runoff does not reach a waterway. Place spilled material
in an appropriate container for disposal.
Note: see section 8 for personal protective equipment and section 13 for waste disposal.
Handling and storage
7.
Aspiration hazard if swallowed- can enter lungs and cause damage. Do not ingest. If ingested do not induce vomiting.
Handling :
Avoid contact of spilled material and runoff with soil and surface waterways. Wash thoroughly after handling.
: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Packaging materials
: Use original container.
Recommended
: Not available.
Specific uses
Date of issue
5.05
Version Page: 2/6
15-11-2005. Version 5.05
This safety data sheet is prepared in accordance with EU
directive 91/155/EC amended by Directive 2001/58/EC
SAFETY DATA SHEET
Natural stone colour intensifier for granite, blue stone and other natural stone
types
Exposure controls/personal protection
8.
Exposure limit values :
Ingredient name Occupational exposure limits
United Kingdom (UK)
Exposure controls
: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
Occupational exposure
vapours below their respective occupational exposure limits. Ensure that eyewash stations
controls
and safety showers are close to the workstation location.
: Ventilation is normally required when handling or using this product. Wear appropriate
Respiratory protection
respirator when ventilation is inadequate.
: Chemical-resistant, impervious gloves or gauntlets complying with an approved standard
Hand protection
should be worn at all times when handling chemical products if a risk assessment indicates this
is necessary.
>8 hour(s) (breakthrough time): polyvinyl alcohol (PVA)
: splash goggles
Eye protection
: Work uniform or laboratory coat.
Skin protection
Physical and chemical properties
9.
General information
Appearance
: Liquid.
Physical state
: Clear Yellow or brown. (Light.)
Colour
: Characteristic. (Slight.)
Odour
Important health, safety and environmental information
: Not applicable.
pH
: May start to solidify at <-50癈 (-58癋) based on data for: alkanes, c9-12-iso-.
Melting point
: The lowest known value is 173 to 193癈 (343.4 to 379.4癋) (alkanes, c9-12-iso-).
Boiling point
: Closed cup: 62癈 (143.6癋). (Pensky-Martens.)
Flash point
Not available.
Explosive properties :
Not applicable
Explosion Limits :
Not applicable
Oxidising properties :
0.823 g/cm3 (20癈 / 68癋)
Relative density :
Insoluble in cold water, hot water.
Solubility :
Dynamic: 1000 cP
Viscosity :
Kinematic: 6 cSt
Other information
: The lowest known value is >200癈 (392癋) (alkanes, c9-12-iso-).
Auto-ignition temperature
Date of issue
5.05
Version Page: 3/6
15-11-2005. Version 5.05
This safety data sheet is prepared in accordance with EU
directive 91/155/EC amended by Directive 2001/58/EC
SAFETY DATA SHEET
Natural stone colour intensifier for granite, blue stone and other natural stone
types
10. Stability and reactivity
: The product is stable.
Stability
: Stable under recommended storage and handling conditions (see section 7). Keep away from
Conditions to Avoid
heat, sparks and flame.
Materials to avoid : Reactive with oxidising agents.
Hazardous Decomposition : These products are carbon oxides (CO, CO2).
Products
11. Toxicological information
Potential acute health effects
No known significant effects or critical hazards.
Inhalation :
Aspiration hazard if swallowed- can enter lungs and cause damage.
Ingestion :
Slightly irritating to the skin.
Skin Contact :
No known significant effects or critical hazards.
Eye contact :
Acute toxicity
Ingredient name Test Result Route Species
alkanes, c9-12-iso- LD50 >10000 mg/kg Oral Rat
LD50 >3200 mg/kg Dermal Rabbit
LD50 >3000 mg/kg Dermal Rabbit
bicyclo[2.2.1]heptan-2-ol, 1,7,7- LD50 9050 mg/kg Oral Rat
trimethyl-, acetate, exo- LD50 3100 mg/kg Oral Mouse
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Inhalation No known significant effects or critical hazards.
:
No known significant effects or critical hazards.
Ingestion :
No known significant effects or critical hazards.
Skin :
Not available.
Other adverse effects :
12. Ecological information
Ecotoxicity data
Ingredient name Species Period Result
alkanes, c9-12-iso- Fish (LC50) 96 hour(s) >100 mg/l
May cause long-term adverse effects in the aquatic environment.
Other adverse effects
Date of issue
5.05
Version Page: 4/6
15-11-2005. Version 5.05
This safety data sheet is prepared in accordance with EU
directive 91/155/EC amended by Directive 2001/58/EC
SAFETY DATA SHEET
Natural stone colour intensifier for granite, blue stone and other natural stone
types
13. Disposal considerations
: The generation of waste should be avoided or minimised wherever possible. Avoid dispersal
Methods of disposal
of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of
this product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
: Not applicable.
Waste classification
: The classification of the product may meet the criteria for a hazardous waste
Hazardous waste
14. Transport information
International transport regulations
Regulatory UN number Proper shipping name Class Packing group Label Additional
information Information
Hazard
3295 UN, "dangerous goods in 3 III
ADR/RID Class
identification
limited quantities of class
number
3, III, ADR Mixture 3
30
Limited quantity
LQ7
-
3295 UN, "dangerous goods in 3 III
ADN Class
limited quantities of class
3, III, ANDR mixture 3
Emergency
3295 "dangerous goods in 3 III
IMDG Class
schedules
limited quantities of class
(EmS)
3" UN 3295, PG III, 3
F-E, S-D
mixture. Marine pollutant
(alkanes, c9-12-iso-) Marine pollutant
Marine pollutant
(P)
-
IATA-DGR Class 3295 "dangerous goods in 3 -
limited quantities of class
3" UN 3295, PG III, 3
mixture
15. Regulatory information
EU Regulations
Hazard symbol(s) :
Harmful
: R65- Harmful: may cause lung damage if swallowed.
Risk Phrases
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R53- May cause long-term adverse effects in the aquatic environment.
Date of issue
5.05
Version Page: 5/6
15-11-2005. Version 5.05
This safety data sheet is prepared in accordance with EU
directive 91/155/EC amended by Directive 2001/58/EC
SAFETY DATA SHEET
Natural stone colour intensifier for granite, blue stone and other natural stone
types
: S2- Keep out of the reach of children.
Safety Phrases
S24- Avoid contact with skin.
S29/56- Do not empty into drains, dispose of this material and its container to hazardous or
special waste collection point.
S37- Wear suitable gloves.
S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this
container or label.
: Not available.
Other EU regulations
: Classification and labelling have been performed according to EU directives 67/548/EEC,
Product use
1999/45/EC, including amendments and the intended use.
- Consumer applications.
Other EU regulations
: Yes, applicable.
Child protection
: Yes, applicable.
Tactile warning of danger
: 32089091
EC Statistical classification
(Tariff Code)
: 30% and more: aliphatic hydrocarbons;perfumes
Ingredients identification
information
16. Other information
Full text of R phrases referred to : R65- Harmful: may cause lung damage if swallowed.
R38- Irritating to skin.
in sections 2 and 3 - United
R66- Repeated exposure may cause skin dryness or cracking.
Kingdom (UK)
R67- Vapours may cause drowsiness and dizziness.
R53- May cause long-term adverse effects in the aquatic environment.
: Xn - Harmful
Full text of classifications
Xi - Irritant
referred to in sections 2 and 3 -
United Kingdom (UK)
History
Date of printing : 15-11-2005.
: 15-11-2005.
Date of issue
Version : 5.05
Verified by T. Rutgers.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
5.05
Version Page: 6/6
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