3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 09-2236-9 Issue date : 06/03/2005
Version : 9.00 Supersedes date : 12/21/2004
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Environmental Health and Safety Services Department, 3M
Canada Company
Telephone: (519) 452-2161, Fax: (519) 452-6015, Web Site: www.3M.ca
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1 Product Identification
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Tradename:
3M FIREDAM 150+ CAULK
Product ID:
98-0400-5316-1 98-0400-5375-7 XE-1014-8317-2 CT-0608-7029-3
98-0400-5315-3 98-0400-5343-5 98-0400-5419-3
Intended Use of Product:
Passive Fire Barrier Product
Division:
CONSUMER SAFETY AND LIGHT MANAGEMENT
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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CALCIUM CARBONATE 1317-65-3 45 - 50
POLYVINYL ACETATE EMULSION 107175-81-5 15 - 20
ACRYLIC EMULSION 70677-00-8 5 - 10
MEDIUM PETROLEUM NAPHTHA 64742-88-7 5 - 10
WATER 7732-18-5 5 - 10
DIBENZOATE PROPANOL 27138-31-4 2-4
ETHYLENE GLYCOL 107-21-1 1-3
TITANIUM DIOXIDE 13463-67-7 1-3
ALKANOL AMINE 124-68-5 0.1 - 1.0
3M FIREDAM 150+ CAULK Page 2 of 8
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ALKYPHENOLETHOXYLATE 9016-45-9 0.1 - 1.0
NOTE:
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
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3 Hazards Identification
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Critical Hazards:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
May be absorbed following inhalation and cause target organ effects.
May be absorbed following ingestion and cause target organ effects.
An ingredient in this product (Ethylene Glycol) has been shown to
cause embryotoxic and teratogenic effects in laboratory animals.
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
Instructions for Skin Contact:
Wash affected area with soap and water. If signs/symptoms develop,
get medical attention.
Instructions for Inhalation:
Remove person to fresh air. If signs/symptoms develop, get medical
attention.
Instructions for Ingestion:
Do not induce vomiting. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get immediate
medical attention.
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5 Fire Fighting Measures
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Flash point: Not applicable
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Autoignition temperature: Not applicable
Suitable Extinguishing Media:
No data available.
Exposure Hazards during Fire:
Non-flammable: ordinary combustible material. Material will not
burn.
Combustion Products from Fire:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Fire Fighting Procedures:
3M FIREDAM 150+ CAULK Page 3 of 8
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Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
NFPA: Health 2
NFPA: Fire 0
NFPA: Reactivity 0
NFPA: Unusual Reaction Hazard none
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6 Accidental Release Measures
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Personal Precautions:
Observe precautions from other sections. Call 3M- HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Spill Response:
Ventilate the area with fresh air. Collect as much of the spilled
material as possible. Clean up residue with detergent and water.
Collect the resulting residue containing solution. Place in a
closed container approved for transportation by appropriate
authorities.
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7 Handling and Storage
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Storage Requirements:
No data available.
Incompatible Materials:
Store away from oxidizing agents.
Ventilation:
No data available.
Use Instructions:
For industrial or professional use only. Avoid contact with
oxidizing agents.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact. The following should be worn alone or in
combination, as appropriate, to prevent eye contact: Indirect
vented goggles;
Hand Protection:
Select and use gloves and/or protective clothing to prevent skin
contact based on the results of an exposure assessment. Consult
with your glove and/or protective clothing manufacturer for
selection of appropriate compatible materials.
Skin Protection:
3M FIREDAM 150+ CAULK Page 4 of 8
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Avoid prolonged or repeated skin contact of grinding dust.
Respiratory Protection:
Under normal use conditions, airborne exposures are not expected to
be significant enough to require respiratory protection. Avoid
breathing of vapours.
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
Recommended Ventilation:
Use with appropriate local exhaust ventilation. Use general
dilution ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits. If
ventilation is not adequate, use respiratory protection equipment.
Ingredient Exposure Data
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CALCIUM CARBONATE (1317-65-3)
LD50 (rat, oral) 6450 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 10 mg/m3 (Particulates not otherwise classified)
POLYVINYL ACETATE EMULSION (107175-81-5)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
ACRYLIC EMULSION (70677-00-8)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
MEDIUM PETROLEUM NAPHTHA (64742-88-7)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
CMRG: TWA 100 ppm
WATER (7732-18-5)
LD50 (rat, oral) >90 ml/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
DIBENZOATE PROPANOL (27138-31-4)
Specific Ingredient Data
No data available. No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
3M FIREDAM 150+ CAULK Page 5 of 8
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No data available.
ETHYLENE GLYCOL (107-21-1)
LD50 (rat, oral) 4700 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: CEIL 100 mg/m3 as aerosol; (Table A4)
ACGIH: CEIL 39.4 ppm as aerosol; (Table A4)
CMRG: CEIL 100 mg/m3 as vapour and aerosol;
TITANIUM DIOXIDE (13463-67-7)
LD50 (rat, oral) >24000 mg/kg
LC50 (rat, inhalation/4 hours) >6820 mg/m3
Exposure Limits
ACGIH: TWA 10 mg/m3
CMRG: TWA 5 mg/m3
ALKANOL AMINE (124-68-5)
Specific Ingredient Data
No data available.
LD50 (rat, oral) 2900 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
ALKYPHENOLETHOXYLATE (9016-45-9)
LD50 (rat, oral) 1310 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Solid; blue; paste; low odour;
Odour Threshold: No data available.
pH: 8.0 -9.0
Boiling point/boiling range: 100.0 C
Melting point/melting range: Not available
Vapour pressure: Not available
Water Solubility: Miscible in wet stage;
Specific gravity: 1.5 Water=1
Vapour density: Lighter than air;
Volatile organic compounds: Not available
Evaporation rate: 1.0 BuOAc=1
Viscosity: No data available.
Percent Volatile: 28 %
3M FIREDAM 150+ CAULK Page 6 of 8
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10 Stability and Reactivity
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Conditions to Avoid:
None known.
Materials to Avoid:
Strong oxidizing agents;
Hazardous Decomposition:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Effects from Skin Contact:
Mild Skin Irritation: Signs/symptoms can include localized redness,
swelling, and itching.
Effects from Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include
cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Prolonged or repeated exposure may cause: Pulmonary Edema:
Signs/symptoms may include chest discomfort, shortness of breath,
significant cough with frothy sputum production, bluish colored
skin (cyanosis), increased heart rate and possible respiratory
failure, and may be fatal.
May be absorbed following inhalation and cause target organ
effects.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, nausea, diarrhea and vomiting.
May be absorbed following ingestion and cause target organ effects.
Sensitization Information:
No data available.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
An ingredient in this product (Ethylene Glycol) has been shown to
cause embryotoxic and teratogenic effects in laboratory animals.
Component Based Information:
No data available.
Product Based Information:
No data available.
3M FIREDAM 150+ CAULK Page 7 of 8
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Other Effects & Information:
Central Nervous System (CNS) Depression: Signs/symptoms may include
headache, dizziness, drowsiness, incoordination, nausea, slowed
reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause: Kidney Effects:
Signs/symptoms may include reduced or absent urine production,
increased serum creatinine, lower back pain, increased protein in
urine, and increased blood urea nitrogen (BUN).
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12 Ecological Information
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Environmental Data:
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
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13 Disposal Considerations
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Product as Sold:
Dispose of completely cured (or polymerized) wastes in a sanitary
landfill. As a disposal alternative, incinerate uncured product in
an industrial or commercial incinerator in the presence of a
combustible material.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transportation Information
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Transportation of Dangerous Goods
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TDG Classification: Non-Regulated Material
Special Information:
Contact 3M for more information.
International Dangerous Goods Classification
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3M FIREDAM 150+ CAULK Page 8 of 8
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15 Regulatory Information
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WHMIS Classification: D2A, D2B
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
TSCA - Toxic Substances Control Act (USA)
DSL - Domestic Substances List (Canada)
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16 Other Information
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Reason for Reissue:
The following Sections and topics have been updated or revised:
Added product id(s) to the MSDS;
Section 2 - Composition/Information on Ingredients;
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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