3M MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 05/19/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M Brand Fire Barrier CP-25WB+
MANUFACTURER: 3M
DIVISION: Consumer Safety and Light Management
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/19/2005
Supercedes Date: 07/01/2004
Document Group: 09-5451-1
Product Use:
Specific Use: Used as a firestop in buildings.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
Water 7732-18-5 20 - 30
Zinc Borate Hydrate 138265-88-0 20 - 30
Synthetic Polymer Latex Trade Secret 15 - 25
Sodium Silicate 1344-09-8 10 - 20
Ethylhexyldiphenyl Phosphate 1241-94-7 5 - 10
Zinc Borate 1332-07-6 1- 5
Iron Oxide 1309-37-1 1- 5
Polyethylene Glycol 25322-68-3 1- 5
Chopped Fiberglass 65997-17-3 1- 5
Quartz Silica 14808-60-7 < 0.2
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Brown caulk thixotropic paste with negligible odor.
General Physical Form: Solid
Immediate health, physical, and environmental hazards: Contains a chemical or chemicals which can cause cancer.
3.2 POTENTIAL HEALTH EFFECTS
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3M MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 05/19/2005
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description Regulation
Quartz Silica 14808-60-7 Group 1 International Agency for Research on Cancer
Quartz Silica 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Not Applicable
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Material will not burn.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
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3M MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 05/19/2005
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Ventilate the area with fresh air. Contain spill. Cover or dilute with water. Clean up
residue with detergent and water. Collect the resulting residue containing solution. Place in a closed container approved for
transportation by appropriate authorities. Dispose of collected material as soon as possible. Discharge the resulting residue containing
solution to a municipal or industrial wastewater treatment facility.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors,
mists or spray. For industrial or professional use only. Use general dilution ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGE
Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. No hazards
anticipated. However, provide ventilation adequate to control odors.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
8.2.2 Skin Protection
Gloves are not required.
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid
breathing of vapors, mists or spray.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
Iron Oxide ACGIH TWA, as Fe 5 mg/m3 Table A4
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3M MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 05/19/2005
Iron Oxide OSHA TWA, as fume 10 mg/m3 Table Z-1A
Chopped Fiberglass 3M TWA, as dust 10 mg/m3
Polyethylene Glycols AIHA TWA, as aerosol 10 mg/m3
Quartz Silica ACGIH TWA, respirable 0.05 mg/m3 Table A2
Quartz Silica OSHA TWA, respirable 0.1 mg/m3 Table Z-1A
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Brown caulk thixotropic paste with negligible odor.
Odor, Color, Grade:
Solid
General Physical Form:
Not Applicable
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
No Data Available
Vapor Density
17.5 mmHg [@ 20 篊]
Vapor Pressure
1.35 [Ref Std: WATER=1]
Specific Gravity
No Data Available
Melting point
Complete
Solubility in Water
0 g/l
Volatile Organic Compounds
30 %
Percent volatile
Approximately 12000 centipoise [Test Method: Brookfield]
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
None known. Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
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3M MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 05/19/2005
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of waste product in a sanitary landfill. As a disposal alternative, incinerate in an industrial or
commercial facility.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
42-0016-4710-8, 42-0016-4715-7, 42-0016-4716-5, 98-0400-5380-7, 98-0400-5381-5, 98-0400-5382-3, 98-0400-5383-1, 98-
0400-5406-0, 98-0400-5456-5
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
Zinc Borate (ZINC COMPOUNDS) 1332-07-6 1- 5
Zinc Borate Hydrate (ZINC COMPOUNDS) 138265-88-0 20 - 30
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
SILICA, CRYSTALLINE (AIRBORNE NONE **Carcinogen
PARTICLES OF RESPIRABLE SIZE)
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIES
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3M MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 05/19/2005
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 0 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS? hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS?ratings are to be used with a fully implemented HMIS?program. HMIS?is a registered mark of the National Paint and Coatings
Association (NPCA).
Revision Changes:
Section 1: Product name was modified.
Section 1: Product use information was modified.
Section 16: NFPA hazard classification for health was modified.
Section 16: HMIS hazard classification for health was modified.
Copyright was modified.
Section 3: Potential effects from eye contact was modified.
Section 3: Potential effects from skin contact information was modified.
Section 3: Potential effects from inhalation information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 7: Handling information was modified.
Section 8: Skin protection phrase was modified.
Section 4: First aid for skin contact - decontamination - was modified.
Section 4: First aid for skin contact - medical assistance - was modified.
Section 4: First aid for ingestion (swallowing) - decontamination - was modified.
Section 4: First aid for ingestion (swallowing) - medical assistance - was modified.
Section 2: Ingredient table was modified.
Section 14: ID Number(s) was modified.
Page Heading: Product name was modified.
Section 15: Inventories information was modified.
Section 15: EPCRA 313 information was modified.
Section 3: Carcinogenicity table was modified.
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3M MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 05/19/2005
Section 8: Exposure guidelines ingredient information was modified.
Section 9: Vapor pressure value was modified.
Section 3 and Section 9: General physical form information was modified.
Sections 3 and 9: Odor, color, grade information was modified.
Section 9: Property description for optional properties was modified.
Section 9: Specific gravity information was modified.
Section 4: First aid for skin contact - termination of exposure - was added.
Section 4: First aid for skin contact - handling - was added.
Section 15: California proposition 65 ingredient information was added.
Section 15: California proposition 65 heading was added.
Section 15: California proposition 65 cancer warning was added.
Section 5: OSHA flammability heading was deleted.
Section 5: OSHA flammability data was deleted.
Section 9: Density information was deleted.
Section 9: Boiling point information was deleted.
Sections 3 and 9: Specific physical form information was deleted.
Sections 3 and 9: Specific physical form heading was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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