MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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Product Name Iron Out Automatic Toilet Bowl Cleaner
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Mixture
CAS #
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Toilet bowl cleaner
Product use
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Iron Out dba Summit Brands
Manufacturer
7201 Engle Road
Fort Wayne, IN 46804-5875 US
Phone: 260-483-2519
Emergency Phone: 1-800-424-9300 (CHEMTREC)
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LEGEND Health * 2
1
HMIS/NFPA
Flammability 1
Severe 4
2 1
Serious 3
Physical Hazard 1
Moderate 2
Slight 1 Personal Protection
B
Minimal 0
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2. Hazards Identification
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CAUTION: EYE AND SKIN IRRITANT.
Emergency overview
May cause sensitization by inhalation and skin contact.
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Potential short term health effects
Eye, Skin contact, Inhalation, Ingestion.
Routes of exposure
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May cause irritation.
Eyes
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Contact with skin can cause irritation and allergic reaction (sensitization) in some
Skin
individuals.
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Dusts of this product may cause irritation of the nose, throat, and respiratory tract.
Inhalation
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May cause stomach distress, nausea or vomiting.
Ingestion
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Eyes. Respiratory system. Skin.
Target organs
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May cause respiratory and/or skin sensitization in sensitive individuals.
Chronic effects
Prolonged or repeated exposure can cause drying, defatting and dermatitis.
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Symptoms may include redness, edema, drying, defatting and cracking of the skin.
Signs and symptoms
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
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3. Composition / Information on Ingredients
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Ingredient(s) CAS # Percent
Sodium lauryl sulfate 151-21-3 7 - 13
Amides, coco (hydroxyethyl) 68140-00-1 10 - 30
Sodium hydrosulfite 7775-14-6 10 - 30
Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, exo- 125-12-2 1-5
Pine oil 8002-09-3 1-5
Sodium metabisulfite 7681-57-4 0.1 - 1
Sodium sulfite 7757-83-7 0.1 - 1
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4. First Aid Measures
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First aid procedures
Flush with cool water. Remove contact lenses, if applicable, and continue flushing.
Eye contact
Obtain medical attention if irritation persists.
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Brush away excess of dry material. Flush with water. Obtain medical attention if
Skin contact
irritation persists.
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If symptoms develop move victim to fresh air. If symptoms persist, obtain medical
Inhalation
attention.
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Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is
Ingestion
convulsing. Obtain medical attention.
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Symptoms may be delayed.
Notes to physician
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If you feel unwell, seek medical advice (show the label where possible). Ensure that
General advice
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with
eyes and skin. Keep out of reach of children.
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5. Fire Fighting Measures
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Not flammable by WHMIS/OSHA criteria.
Flammable properties
Risk of spontaneous iginition at high temperatures.
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Extinguishing media
Dry chemical. Carbon dioxide. Foam. Water spray.
Suitable extinguishing media
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Unsuitable extinguishing media Not available
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Protection of firefighters
Not available
Specific hazards arising from
the chemical
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Firefighters should wear full protective clothing including self contained breathing
Protective equipment for
apparatus.
firefighters
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May include and are not limited to: Oxides of carbon. Oxides of sulphur. Hydrogen
Hazardous combustion products
sulphide.
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Explosion data
Not available
Sensitivity to mechanical
impact
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Not available
Sensitivity to static discharge
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6. Accidental Release Measures
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Keep unnecessary personnel away. Do not touch or walk through spilled material. Do
Personal precautions
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.
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Prevent entry into waterways, sewers, basements or confined areas.
Methods for containment
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Before attempting clean up, refer to hazard data given above. Use broom or dry
Methods for cleaning up
vacuum to collect material for proper disposal without raising dust. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary
system.
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7. Handling and Storage
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Use good industrial hygiene practices in handling this material.
Handling
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Keep out of reach of children. Store in a closed container away from incompatible
Storage
materials. Avoid storage at elevated temperatures.
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8. Exposure Controls / Personal Protection
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Exposure limits
Ingredient(s) Exposure Limits
Amides, coco (hydroxyethyl) ACGIH-TLV
Not established
OSHA-PEL
Not established
Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, exo- ACGIH-TLV
Not established
OSHA-PEL
Not established
Pine oil ACGIH-TLV
Mist: 5 mg/m3
OSHA-PEL
Not established
Sodium hydrosulfite ACGIH-TLV
Not established
OSHA-PEL
Not established
Sodium lauryl sulfate ACGIH-TLV
Not established
OSHA-PEL
Not established
Sodium metabisulfite ACGIH-TLV
TWA: 5 mg/m3
OSHA-PEL
Not established
Sodium sulfite ACGIH-TLV
Not established
OSHA-PEL
Not established
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General ventilation normally adequate.
Engineering controls
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Personal protective equipment
Wear safety glasses with side shields.
Eye / face protection
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Rubber gloves. Confirm with a reputable supplier first.
Hand protection
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As required by employer code.
Skin and body protection
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Not normally required if good ventilation is maintained and exposure guidelines are not
Respiratory protection
exceeded. Where exposure guideline levels may be exceeded, use an approved NIOSH
respirator.
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General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do
not eat or drink. Wash hands before breaks and immediately after handling the product.
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9. Physical and Chemical Properties
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Opaque.
Appearance
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Light blue
Color
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Tablet.
Form
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Pine
Odor
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Not available
Odor threshold
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Solid
Physical state
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3 - 3.5 1% solution
pH
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Not available
Melting point
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Not available
Freezing point
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Not available
Boiling point
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> 60.00 癈 (> 140 癋)
Flash point
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Not available
Evaporation rate
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Not applicable
Flammability limits in air, lower, %
by volume
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Not applicable
Flammability limits in air, upper, %
by volume
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Not available
Vapor pressure
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Not available
Vapor density
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Not available
Specific gravity
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Not available
Octanol/water coefficient
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Not available
Auto-ignition temperature
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Not available
Percent volatile
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10. Stability and Reactivity
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Stable under recommended storage conditions.
Chemical stability
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Do not mix with other chemicals. Avoid high temperatures.
Conditions to avoid
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Acids. Oxidizing agents. Organic materials. Combustible materials.
Incompatible materials
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Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of sulphur. Hydrogen
sulphide.
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Hazardous polymerization does not occur.
Possibility of hazardous reactions
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11. Toxicological Information
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Component analysis - LC50
Ingredient(s) LC50
Amides, coco (hydroxyethyl) Not available
Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, exo- Not available
Pine oil Not available
Sodium hydrosulfite Not available
Sodium lauryl sulfate Not available
Sodium metabisulfite Not available
Sodium sulfite 5.5 mg/l/4h rat
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Component analysis - Oral LD50
Ingredient(s) LD50
Amides, coco (hydroxyethyl) 2700 mg/kg rat
Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, exo- 9000 mg/kg mouse; 10000 mg/kg rat
Pine oil 3200 mg/kg rat
Sodium hydrosulfite 2500 mg/kg rat
Sodium lauryl sulfate 1288 mg/kg rat
Sodium metabisulfite 1131 mg/kg rat
Sodium sulfite 820 mg/kg mouse; 820 mg/kg rat
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Effects of acute exposure
May cause irritation.
Eye
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Contact with skin can cause irritation and allergic reaction (sensitization) in some
Skin
individuals.
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Dusts of this product may cause irritation of the nose, throat, and respiratory tract.
Inhalation
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May cause stomach distress, nausea or vomiting.
Ingestion
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May cause respiratory and skin sensitization. People with asthma or other lung
Sensitization
problems may be more susceptible. May cause severe allergic reaction in some
asthmatics and sulfite sensitive individuals.
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Non-hazardous by WHMIS/OSHA criteria.
Chronic effects
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Non-hazardous by WHMIS/OSHA criteria.
Carcinogenicity
ACGIH - Threshold Limit Values - Carcinogens
Sodium metabisulfite 7681-57-4 A4 - Not Classifiable as a Human Carcinogen
IARC - Group 3 (Not Classifiable)
Sodium metabisulfite 7681-57-4 Monograph 54 [1992] (listed under Sulfur dioxide and some sulfites bisulfites and
metabisulfites)
Sodium sulfite 7757-83-7 Monograph 54 [1992] (listed under Sulfur dioxide and some sulfites bisulfites and
metabisulfites)
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Non-hazardous by WHMIS/OSHA criteria.
Mutagenicity
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Non-hazardous by WHMIS/OSHA criteria.
Reproductive effects
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Non-hazardous by WHMIS/OSHA criteria.
Teratogenicity
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12. Ecological Information
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See below
Ecotoxicity
Ecotoxicity - Freshwater Algae Data
Sodium hydrosulfite 7775-14-6 72 Hr EC50 Scenedesmus subspicatus: 120 mg/L; 96 Hr EC50 Scenedesmus
subspicatus: 87 mg/L
Sodium lauryl sulfate 151-21-3 72 Hr EC50 Scenedesmus subspicatus: 53 mg/L; 96 Hr EC50 Scenedesmus
subspicatus: 30-100 mg/L; 96 Hr EC50 Selenastrum capricornutum: 117 mg/L
Sodium metabisulfite 7681-57-4 72 Hr EC50 Scenedesmus subspicatus: 48 mg/L; 96 Hr EC50 Scenedesmus
subspicatus: 40 mg/L
Ecotoxicity - Freshwater Fish Species Data
Amides, coco (hydroxyethyl) 68140-00-1 96 Hr LC50 Brachydanio rerio: 28.5 mg/L [semi-static]
Bicyclo[2.2.1]heptan-2-ol, 125-12-2 96 Hr LC50 Brachydanio rerio: 10.0-18.0 mg/L [static]
1,7,7-trimethyl-, acetate, exo-
Sodium hydrosulfite 7775-14-6 96 Hr LC50 Leuciscus idus: 46 - 68 mg/L [static]
Sodium lauryl sulfate 151-21-3 96 Hr LC50 Pimephales promelas: 8-12.5 mg/L [static] (fry); 96 Hr LC50 Pimephales
promelas:15-18.9 mg/L [static] (juvenile); 96 Hr LC50 Pimephales promelas:22.1-22.8
mg/L [static] (adult); 96 Hr LC50 Oncorhynchus mykiss:4.3-8.5 mg/L [static]; 96 Hr LC50
Oncorhynchus mykiss:4.62 mg/L [flow-through]; 96 Hr LC50 Oncorhynchus mykiss:4.2
mg/L; 96 Hr LC50 Brachydanio rerio:7.97 mg/L [flow-through]; 96 Hr LC50 Brachydanio
rerio:9.9-20.1 mg/L [semi-static]; 96 Hr LC50 Lepomis macrochirus:4.06-5.
Sodium metabisulfite 7681-57-4 96 Hr LC50 Lepomis macrochirus: 32 mg/L [static]
Sodium sulfite 7757-83-7 96 Hr LC50 Leuciscus idus: 220 - 460 mg/L [static]
Ecotoxicity - Microtox Data
Sodium hydrosulfite 7775-14-6 17 Hr EC50 Pseudomonas putida: 107 mg/L
Sodium lauryl sulfate 151-21-3 5 Min EC50 Photobacterium phosphoreum: 1.19 mg/L; 15 min EC50 Photobacterium
phosphoreum: 0.72 mg/L; 30 min EC50 Photobacterium phosphoreum: 0.46 mg/L
Sodium metabisulfite 7681-57-4 17 Hr EC50 Pseudomonas putida: 56 mg/L
Sodium sulfite 7757-83-7 17 Hr EC50 Pseudomonas putida: 770 mg/L
Ecotoxicity - Water Flea Data
Amides, coco (hydroxyethyl) 68140-00-1 24 Hr EC50 Daphnia magna: 10 mg/L
Pine oil 8002-09-3 48 Hr EC50 water flea: 3.32 mg/L
Sodium hydrosulfite 7775-14-6 48 Hr EC50 Daphnia magna Straus: 98 mg/L
Sodium lauryl sulfate 151-21-3 48 Hr EC50 Daphnia magna: 1.8 mg/L
Sodium metabisulfite 7681-57-4 24 Hr EC50 Daphnia magna Straus: 89 mg/L
Sodium sulfite 7757-83-7 24 Hr LC50 Psammechinus miliaris: 330 mg/L
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Not available
Environmental effects
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Not available
Aquatic toxicity
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Not available
Persistence / degradability
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Not available
Bioaccumulation / accumulation
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Not available
Partition coefficient
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Not available
Mobility in environmental media
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Not available
Chemical fate information
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Not available
Other adverse effects
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13. Disposal Considerations
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Not available
Waste codes
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Review federal, provincial, and local government requirements prior to disposal.
Disposal instructions
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Not available
Waste from residues / unused
products
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Not available
Contaminated packaging
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14. Transport Information
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U.S. Department of Transportation (DOT)
Not regulated as dangerous goods.
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Transportation of Dangerous Goods (TDG - Canada)
Not regulated as dangerous goods.
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15. Regulatory Information
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This product has been classified in accordance with the hazard criteria of the Controlled
Canadian federal regulations
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Canada - WHMIS - Ingredient Disclosure List
Sodium lauryl sulfate 151-21-3 1%
Sodium metabisulfite 7681-57-4 1%
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard
US Federal regulations
Communication Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
CERCLA/SARA Hazardous Substances - Not applicable.
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
None
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Not available
Clean Air Act (CAA)
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Not available
Clean Water Act (CWA)
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Controlled
WHMIS status
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Class D - Division 2A, 2B
WHMIS classification
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WHMIS labeling
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This product does not contain a chemical known to the State of California to cause
State regulations
cancer, birth defects or other reproductive harm.
U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
Sodium metabisulfite 7681-57-4 Present
U.S. - Massachusetts - Right To Know List
Sodium hydrosulfite 7775-14-6 Present
Sodium metabisulfite 7681-57-4 Present
U.S. - Minnesota - Hazardous Substance List
Sodium metabisulfite 7681-57-4 Present
U.S. - New Jersey - Right to Know Hazardous Substance List
Pine oil 8002-09-3 sn 2684
Sodium hydrosulfite 7775-14-6 sn 1697
Sodium metabisulfite 7681-57-4 sn 1708
U.S. - Pennsylvania - RTK (Right to Know) List
Sodium hydrosulfite 7775-14-6 Present
Sodium metabisulfite 7681-57-4 Present
U.S. - Rhode Island - Hazardous Substance List
Sodium hydrosulfite 7775-14-6 Flammable
Sodium metabisulfite 7681-57-4 Toxic
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Inventory name
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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16. Other Information
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Information contained herein was obtained from sources considered technically accurate
Disclaimer
and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
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17-Jun-2009
Issue date
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15-Mar-2009
Effective date
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15-Mar-2012
Expiry date
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Dell Tech Laboratories Ltd. (519) 858-5021
Prepared by
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