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MSDS Material Safety Data Sheet
CAS

28064-14-4 67762-90-7 1241-94-7 100-41-4 108-88-3

File Name: 28064-14-4_67762-90-7_1241-94-7_100-41-4_108-88.asp

                                                                                        CHEMTREC Transportation
Emergency Phone: 800-

Material 424-9300
Pittsburgh Poison Control

Safety Data Center
Health Emergency No.: 412-
681-6669
Sheet NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident
involving chemicals


Section 1 - Chemical Product / Company Information

Revision
CARBOGUARD 992 PART A 05/04/2009
Product Name:
Date:
Identification
PLMSDS 0956A1NL Supercedes : 01/16/2008
Number:
Cross Linked Epoxy, FOR
Product
INDUSTRIAL USE ONLY
Use/Class:
Regulatory, Department
Preparer:
Manufacturer: Carboline Company
2150 Schuetz Road
St. Louis, MO 63146


Section 2 - Composition / Information On Ingredients

Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
EPOXY PHENOL 28064-14-4 95.0 N/E N/E N/E N/E
NOVOLAC RESIN
FUMED SILICA 67762-90-7 5.0 N/E N/E N/E N/E
SILICA 67762-90-7 5.0 10 MG/M3, N/E 6 MG/M3 N/E
AMORPHOUS INHALABLE



Section 3 - Hazards Identification

Emergency Overview: Possible Sensitizer Under normal use conditions, this product is not expected to
cause adverse health effects.

Effects Of Overexposure - Eye Contact: May cause eye irritation.

Effects Of Overexposure - Skin Contact: May cause allergic skin reaction. May cause skin irritation.

Effects Of Overexposure - Inhalation: May cause nose and throat irritation.

Effects Of Overexposure - Ingestion: May be harmful if swallowed.

Effects Of Overexposure - Chronic Hazards: No Information.

Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact

Medical Conditions Prone to Aggravation by Exposure: If sensitized to amines, epoxies, or other
chemicals do not use. See a physician if a medical condition exists.


Section 4 - First Aid Measures

First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult
a physician.

First Aid - Skin Contact: In case of contact, wash skin immediately with soap and water.




Page 1 of 5
First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a
physician if symptoms persist or exposure was severe.

First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.


Section 5 - Fire Fighting Measures
Flash Point, F: 206F (96C) Lower Explosive Limit, %: 0.9
Upper Explosive Limit, %: 7.5
(Setaflash)

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog

Unusual Fire And Explosion Hazards: This product contains less than 1% volatile components. The
amount of vapors that could accumulate are minimal. However, vapors are heavier than air and could
travel long distances, ignite, and flashback. Eliminate all ignition sources. Keep away from sparks, open
flames, and heat sources. All electrical equipment and installations should be made and grounded in
accordance with the National Electrical Code. In areas where explosion hazards exist, workers should be
required to use nonferrous tools and to wear conductive and non-sparking shoes.

Special Firefighting Procedures: Evacuate hazard area of unprotected personnel. Use a NIOSH
approved self-contained breathing unit and complete body protection. Cool surrounding containers with
water in case of fire exposure.


Section 6 - Accidental Release Measures

Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling
equipment must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear
appropriate personal protection clothing and equipment. Follow exposure controls/personal protection
guidelines in Section 8. Contain and soak up residual with an aborbent (clay or sand). Take up absorbant
material and seal tightly for proper disposal. Dispose of in accordance with local, state and federal
regulations. Refer to Section 15 for SARA Title III and CERCLA information.


Section 7 - Handling And Storage

Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or
transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty
containers. Use only in accordance with Carboline application instructions, container label and Product
Data Sheet. Avoid breathing vapors or spray mist.

Storage: Keep away from heat, sparks, open flames and oxidizing agents. Keep containers closed. Store
in a cool, dry place with adequate ventilation.


Section 8 - Exposure Controls / Personal Protection

Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).

Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in
Section 2. User should test and monitor exposure levels to ensure all personnel are below guidelines. If
not sure, or not able to monitor, use MSHA/NIOSH approved supplied air respirator. Follow all current
OSHA requirements for respirator use. For silica containing coatings in a liquid state, and/or if no
exposure limits are established in Section 2 above, supplied air respirators are generally not required.

Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates
to skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.

Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.

Other protective equipment: Eye wash and safety showers should be readily available.




Page 2 of 5
Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or
using toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before
reuse. Leather shoes can absorb and allow hazardous materials to pass through. Check shoes carefully
after soaking before reuse.


Section 9 - Physical And Chemical Properties
N/A - N/A Heavier than Air
Boiling Range: Vapor Density:
Slight Phenolic N/D
Odor: Odor Threshold:
Viscous Liquid Slower Than Ether
Appearance: Evaporation Rate:
N/D
Solubility in H2O:
N/D 1.19
Freeze Point: Specific Gravity:
N/D N/D
Vapor Pressure: PH:
Liquid
Physical State:

(See section 16 for abbreviation legend)



Section 10 - Stability And Reactivity

Conditions To Avoid: Heat, sparks and open flames.

Incompatibility: Avoid contact with strong oxidizing agents.

Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these
operations.

Hazardous Polymerization: Will not occur under normal conditions.

Stability: This product is stable under normal storage conditions.


Section 11 - Toxicological Information

Product LD50: N/D Product LC50: N/D

Chemical Name CAS Number LD50 LC50
EPOXY PHENOL NOVOLAC RESIN 28064-14-4 >5,000 MG/KG. ORAL, RAT >1.7 MG/L (AEROSOL) 4 HR
FUMED SILICA 67762-90-7 > 6350 MG/KG, ORAL, RAT NOT AVAILABLE
SILICA AMORPHOUS 67762-90-7 > 5000 MG/KG, ORAL , RAT NOT AVAILABLE



Section 12 - Ecological Information

Ecological Information: No data


Section 13 - Disposal Information

Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental
regulations. Responsibility for proper waste disposal is with the owner of the waste.


Section 14 - Transportation Information

Not Regulated Packing Group: N/A
DOT Proper Shipping
Name:
N/A N/A
DOT Technical Name: Hazard
Subclass:
None N/A
DOT Hazard Class: Resp. Guide
Page:
None
DOT UN/NA Number:




Page 3 of 5
Additional Notes: None.


Section 15 - Regulatory Information

CERCLA - SARA HAZARD CATEGORY

This product has been reviewed according to the EPA Hazard Categories promulgated under Sections
311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
considered, under applicable definitions, to meet the following categories:

SARA SECTION 313

This product contains the following substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

No Section 313 Substances exist in this product

TOXIC SUBSTANCES CONTROL ACT

All components of this product are listed on the TSCA inventory.

This product contains the following chemical substances subject to the reporting requirements of TSCA
12(B) if exported from the United States:

No TSCA 12(B) Substances exist in this product

U.S. STATE REGULATIONS AS FOLLOWS:

NEW JERSEY RIGHT-TO-KNOW

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS Number
DIPHYNL ESTER 1241-94-7
ADDITIVE TRADE SECRET


PENNSYLVANIA RIGHT-TO-KNOW

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS Number
DIPHYNL ESTER 1241-94-7


CALIFORNIA PROPOSITION 65

Warning: The following ingredients present in the product are known to the state of California to
cause Cancer:

Chemical Name CAS Number
ETHYL BENZENE 100-41-4


Warning: The following ingredients present in the product are known to the state of California to
cause birth defects, or other reproductive hazards:

Chemical Name CAS Number
TOLUENE 108-88-3


INTERNATIONAL REGULATIONS AS FOLLOWS:

CANADIAN WHMIS

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of
the 16 headings.




Page 4 of 5
CANADIAN WHMIS CLASS: Not WHMIS Regulated


Section 16 - Other Information

HMIS Ratings
Health: 0 Flammability: 1 Reactivity: 0 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 6

REASON FOR REVISION: Changes made in Section(s) 1, 5, 15, and 16.

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined


The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations




Page 5 of 5

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