3M-CP25WB+.txt
3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 09-5451-1 Issue date : 2007/06/21
Version : 4.00 Supersedes date : 2004/09/03
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Corporate Regulatory Services, 3M Canada Company
Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca
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1 Product Identification
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Tradename:
3M BRAND FIRE BARRIER CP-25WB+
Product ID:
42-0016-4710-8 42-0016-4715-7 42-0016-4716-5 98-0400-5379-9
98-0400-5380-7 98-0400-5381-5 98-0400-5382-3 98-0400-5383-1
98-0400-5392-2 98-0400-5406-0 98-0400-5407-8 98-0400-5448-2
98-0400-5456-5 98-0400-5463-1
Intended Use of Product:
Passive Fire Barrier Product
Division:
BUILDING & COMMERCIAL SERVICES
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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WATER 7732-18-5 20 - 30
ZINC BORATE 1332-07-6 20 - 30
SYNTHETIC POLYMER LATEX Trade Secret 15 - 25
SODIUM SILICATE 1344-09-8 10 - 20
2-ETHYLHEXYLDIPHENYL PHOSPHATE 1241-94-7 5 - 10
IRON OXIDE 1309-37-1 1-5
POLYETHYLENE GLYCOL 25322-68-3 1-5
CHOPPED FIBERGLASS 65997-17-3 1-5
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QUARTZ SILICA 14808-60-7 0.1 - 0.2
NOTE:
SYNTHETIC POLYMER LATEX is a non-hazardous Trade Secret material
according to WHMIS criteria.
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
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3 Hazards Identification
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Critical Hazards:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Moderate Skin Irritation: Signs/symptoms can include localized
redness, swelling, itching, and dryness.
WARNING: Contains a chemical which can cause cancer. (14808-60-7)
(NTP known human carcinogen, IARC human carcinogen 1, Calif.
Proposition 65)
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
Instructions for Skin Contact:
Remove contaminated clothing and shoes. Immediately flush skin with
large amounts of water. Get medical attention. Wash contaminated
clothing and clean shoes before reuse.
Instructions for Inhalation:
Remove person to fresh air. If signs/symptoms develop, get medical
attention.
Instructions for Ingestion:
Do not induce vomiting unless instructed to do so by medical
personnel. Give victim two glasses of water. Never give anything
by mouth to an unconscious person. Get medical attention.
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5 Fire Fighting Measures
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Flash point: Not applicable
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Autoignition temperature: Not applicable
Suitable Extinguishing Media:
Not applicable
Exposure Hazards during Fire:
Material will not burn.
Combustion Products from Fire:
3M BRAND FIRE BARRIER CP-25WB+ Page 3 of 9
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Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Fire Fighting Procedures:
Wear full protective equipment (Bunker Gear) and a self-contained
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breathing apparatus (SCBA).
NFPA: Health 2
NFPA: Fire 0
NFPA: Reactivity 0
NFPA: Unusual Reaction Hazard none
Special Instructions:
Not applicable.
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6 Accidental Release Measures
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Personal Precautions:
Observe precautions from other sections. Call 3M- HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Spill Response:
Ventilate the area with fresh air. Collect as much of the spilled
material as possible. Clean up residue with detergent and water.
Place in a closed container approved for transportation by
appropriate authorities. Dispose of collected material as soon as
possible.
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7 Handling and Storage
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Storage Requirements:
Store in a cool, dry place.
Incompatible Materials:
Store away from heat;
Ventilation:
No data available.
Use Instructions:
For industrial or professional use only. Do not eat, drink or smoke
when using this product. Wash exposed areas thoroughly with soap
and water.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact.
The following should be worn alone or in combination, as
appropriate, to prevent eye contact:
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Indirect vented goggles;
Hand Protection:
Wear appropriate gloves when handling this material.
The following glove material(s) are recommended:
polyvinyl chloride;
Skin Protection:
Avoid prolonged or repeated skin contact.
Select and use gloves and/or protective clothing to prevent skin
contact based on the results of an exposure assessment. Consult
with your glove and/or protective clothing manufacturer for
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selection of appropriate compatible materials.
Respiratory Protection:
Under normal use conditions, airborne exposures are not expected to
be significant enough to require respiratory protection.
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
Recommended Ventilation:
Use with appropriate local exhaust ventilation.
Ingredient Exposure Data
------------------------
WATER (7732-18-5)
LD50 (rat, oral) > 90 ml/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
ZINC BORATE (1332-07-6)
Specific Ingredient Data
No data available. No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
SYNTHETIC POLYMER LATEX (Trade Secret)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
SODIUM SILICATE (1344-09-8)
Specific Ingredient Data
No data available.
LD50 (rat, oral) 3.3 - 8.4 g/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
2-ETHYLHEXYLDIPHENYL PHOSPHATE (1241-94-7)
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Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
IRON OXIDE (1309-37-1)
LD50 (rat, oral) > 10,000 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 5 mg/m3 (specific form) as Fe; (Respirable) (Table A4)
POLYETHYLENE GLYCOL (25322-68-3)
LD50 (rat, oral) 600 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
AIHA: TWA 10 mg/m3 as aerosol;
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CHOPPED FIBERGLASS (65997-17-3)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
3M: TWA 10 mg/m3 as dust
QUARTZ SILICA (14808-60-7)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 0.025 mg/m3 (Respirable) (Table A2)
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Solid; paste; Thixotropic;
Caulk; brown; negligible
odour;
Odour Threshold: No data available.
pH: No data available.
Boiling point/boiling range: No data available.
Melting point/melting range: Not available
Vapour pressure: No data available.
Water Solubility: Complete
Specific gravity: 1.35 Water=1
Vapour density: No data available.
Volatile organic compounds: 0 gms/liter
Evaporation rate: No data available.
Viscosity: No data available.
Percent Volatile: 30 %
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10 Stability and Reactivity
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Conditions to Avoid:
Store away from heat;
Materials to Avoid:
None known.
Hazardous Decomposition:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Effects from Skin Contact:
Moderate Skin Irritation: Signs/symptoms can include localized
redness, swelling, itching, and dryness.
Effects from Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough,
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sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, stomach upset, nausea, vomiting and diarrhea.
Sensitization Information:
No data available.
Carcinogenicity:
WARNING: Contains a chemical which can cause cancer. (14808-60-7)
(NTP known human carcinogen, IARC human carcinogen 1, Calif.
Proposition 65)
Mutagenicity:
No data available.
Reproductive Effects:
No data available.
Component Based Information:
No data available.
Product Based Information:
No data available.
3M BRAND FIRE BARRIER CP-25WB+ Page 7 of 9
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12 Ecological Information
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Environmental Data:
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
Special statements for 2001/58/EC:
One or more components of this product have significant known or
predicted environmental hazards, but a conservative assessment
indicates a low environmental risk. Intended use and proper
disposal are unlikely to cause the environmentally hazardous
component(s) to enter the environment in quantities or by routes
that could cause the adverse environmental impacts.
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13 Disposal Considerations
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Product as Sold:
Dispose of waste product in a sanitary landfill. As a disposal
alternative, dispose of waste product in a facility permitted to
accept chemical waste.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transportation Information
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Transportation of Dangerous Goods
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TDG Classification: Non-Regulated Material
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Special Information:: Contact 3M for more information.
These transportation classifications are provided as a customer
service. As the shipper YOU remain responsible for complying with
all applicable laws and regulations, including proper
transportation classification and packaging. 3M's transportation
classifications are based on product formulation, packaging, 3M
policies and 3M's understanding of applicable current regulations.
3M does not guarantee the accuracy of this classification
information. This information applies only to transportation
classification and not the packaging, labeling, or marking
requirements. The original 3M package is certified for Canadian
ground shipment only. If you are shipping by air or ocean, the
package may not meet applicable regulatory requirements.
3M BRAND FIRE BARRIER CP-25WB+ Page 8 of 9
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International Dangerous Goods Classification
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15 Regulatory Information
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WHMIS Classification: D2A, D2B
98-0400-5456-5 Exempt
(Consumer Product)
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
DSL - Domestic Substances List (Canada)
AICS - Australian Inventory of Chemical Substances
TSCA - Toxic Substances Control Act (USA)
EINECS - European Inventory of Existing Commercial Chemical
Substances
CICS - Chinese Inventory of Chemical Substances
KECI - Korean Existing Chemicals Inventory
MITI - Ministry of International Trade and Industry (JAPAN)
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16 Other Information
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Reason for Reissue:
The following Sections and topics have been updated or revised:
Division name change.
Update Tradename
Section 2 - Composition/Information on Ingredients;
Section 3 - Hazards Identification - Critical Hazards;
Section 4 - First Aid Measures;
Section 5 - Fire Fighting Measures
Section 6 - Accidental Release Measures;
Section 7 - Handling and Storage;
Section 8 - Exposure Controls/Personal Protection;
Section 9 - Physical and Chemical Properties;
Section 10 - Stability and Reactivity;
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Section 11 - Toxicological Information;
Section 13 - Disposal Considerations;
WHMIS Classification change
Section 15 - Regulatory Information: Product Certifications
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
3M BRAND FIRE BARRIER CP-25WB+ Page 9 of 9
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EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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