3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill
(tm) System)
MANUFACTURER: 3M
DIVISION: Building & Commercial Services Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/08/2007
Supercedes Date: 10/10/2005
Document Group: 16-4731-2
Product Use:
Intended Use: INDUSTRIAL DEGREASER
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
POLYETHOXYLATED ALCOHOL - NJTSN #027586004-8002 Trade Secret 15 - 40
2-AMINOISOBUTANOL 124-68-5 15 - 40
WATER 7732-18-5 10 - 30
ETHYLENE GLYCOL ETHYLHEXYL ETHER 1559-35-9 5 - 10
TRIMETHYL OCTADECYL AMMONIUM CHLORIDE 112-03-8 3- 7
ISOPROPYL ALCOHOL 67-63-0 1- 5
DIETHYLENE GLYCOL MONO(2-ETHYLHEXYL) ETHER 1559-36-0 1- 5
D-LIMONENE 5989-27-5 <1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear, red concentrate with mild clean and fresh fragrance
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Combustible liquid and vapor. May cause chemical eye burns.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
May cause allergic skin reaction. May cause severe skin irritation. May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.
Skin Contact:
Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
A 3M Product Environmental Data Sheet (PED) is available.
A conservative assessment of this product indicates that its use and proper disposal are likely to present a low environmental risk.
Potential use and misuse are unlikely to cause components to enter the environment in quantities or by routes that could cause adverse
environmental impacts.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
147 篎 [Test Method: Closed Cup]
Flash Point
Class IIIA Combustible Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Combustible liquid and vapor.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical
ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains
and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with
bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.
Collect as much of the spilled material as possible. Collect as much of the spilled material as possible using non-sparking tools.
Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected
material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the product label.
Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Do not eat, drink or
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3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container closed when not in use. Keep
away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Grounding
or safety shoes with electrostatic dissipating soles (ESD) are not required with TWIST 'n FILL. Avoid contact with oxidizing agents.
7.2 STORAGE
Keep container tightly closed. Store away from heat. Store out of direct sunlight. Store away from acids. Store away from oxidizing
agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, special ventilation is not required.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, eye contact with the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is
recommended: Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin
contact with the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective
clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl
Rubber
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, respiratory protection is not required.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH
approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or
fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional
information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ISOPROPYL ALCOHOL ACGIH TWA 200 ppm Table A4
ISOPROPYL ALCOHOL ACGIH STEL 400 ppm Table A4
ISOPROPYL ALCOHOL OSHA TWA 400 ppm Table Z-1A
ISOPROPYL ALCOHOL OSHA STEL 500 ppm Table Z-1A
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
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3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear, red concentrate with mild clean and fresh fragrance
Odor, Color, Grade:
Liquid
General Physical Form:
147 篎 [Test Method: Closed Cup]
Flash Point
> 212 篎
Boiling point
Approximately 1 [Ref Std: WATER=1]
Density
Approximately 25 mmHg
Vapor Pressure
Approximately 1 [Ref Std: WATER=1]
Specific Gravity
Approximately 11.2
pH
Complete
Solubility in Water
3 - 7 % [Test Method: calculated per CARB title 2]
Volatile Organic Compounds
15 - 40
Percent volatile
30 - 90 g/l [Test Method: calculated per CARB title 2]
VOC Less H2O & Exempt Solvents
< 100 centipoise [Test Method: ACS METHOD]
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong acids; Strong oxidizing agents; Reducing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
CHEMICAL FATE INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a
facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
70-0709-9194-1 00-48011-29664-7 70-0709-9195-8 00-48011-29665-4
70-0709-9251-9 00-48011-29677-7 70-0709-9252-7 00-48011-29678-4
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
ETHYLENE GLYCOL ETHYLHEXYL 1559-35-9 5 - 10
ETHER (GLYCOL ETHERS)
TRIMETHYL OCTADECYL AMMONIUM 112-03-8 3- 7
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3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
CHLORIDE (AMMONIA COMPOUNDS)
DIETHYLENE GLYCOL MONO(2- 1559-36-0 1- 5
ETHYLHEXYL) ETHER (GLYCOL ETHERS)
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
The components of this product are listed on the Canadian Domestic Substances List.
INTERNATIONAL REGULATIONS
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 3 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 3 Flammability: 2 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS? hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS?ratings are to be used with a fully implemented HMIS?program. HMIS?is a registered mark of the National Paint and Coatings
Association (NPCA).
Reason for Reissue: Changed Physical Properties
Revision Changes:
Section 1: Product use information was modified.
Section 1: Division name was modified.
Copyright was modified.
Section 9: pH information was modified.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) INDUSTRIAL DEGREASER CONCENTRATE (Product No. 26, Twist 'n Fill (tm)
System) 05/08/2007
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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