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24 Hour Emergency Phone Numbers:
Material
Medical/Poison Control:
1-800-327-3874
1-513-558-5111
Safety Transportation/National Response
Center:
1-800-535-5053
Data 1-352-323-3500
Sheet NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signal閠ique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Epoxy Stik 2 Minute Epoxy Revision Date: 09/12/2007
Product UPC Number: 070798013001 Supercedes: 04/21/2006
Product Use/Class: Epoxy MSDS Number: 00079977001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 (non-emergency matters)
Section 2 - Hazards Identification
Emergency Overview: A clear liquid product with a musty odor. WARNING! May cause eye, skin, nose, throat and
respiratory tract irritation. May cause sensitization. Corrosive. Harmful if swallowed or absorbed through the skin. May
cause burns.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Corrosive to the eyes! Direct contact with eyes will cause severe irritation and
may lead to burns and permanent eye damage including blindness. Mists and vapors may cause moderate to severe eye
irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation and/or dermatitis. May cause allergic skin reaction or
sensitization. Harmful if absorbed through the skin. Prolonged and repeated skin contact may cause moderate to severe
skin irritation and possibly burns. May be corrosive on prolonged contact.
Allergic contact dermatitis is a common effect of occupational exposure to formaldehyde, polymer with (chloromethyl)
oxirane and phenol. Exposure to formaldehyde, polymer with (chloromethyl)oxirane and phenol may result in severe
burns to the skin. Eczema, urticaria, photodermatitis, erythema, persistent itching, severe facial swelling, blistering and
erythema multiforme have been reported after dermal exposure to bisphenol A diglycidyl ether. Sclerotic skin changes are
possible.
Topical exposure to phenol results in brown, relatively painless patches on the skin and whitish patches on the mucous
membranes. Phenol is nephrotoxic to humans and animals, especially following chronic exposure. Humans have
experienced nephritis following toxic dermal exposure. Because of the concentration in this product and the limted
exposure potential, nephrotoxicity is not expected to occur.
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Effects Of Overexposure - Inhalation: Harmful if inhaled. Exposure to formaldehyde, polymer with (chloromethyl)
oxirane and phenol vapors may result in coughing, asthmatic attacks and bronchospasm persisting for several days.
Bronchospasm may also occur. Organic acid anhydrides may produce an asthma-rhinitis syndrome, a flu-like syndrome,
pulmonary disease-anemia syndrome, or irritant respiratory effects. Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes). May cause allergic respiratory reaction. Overexposure to fumes or vapors may cause
delayed lung damage and chemical pneumonia.
Effects Of Overexposure - Ingestion: Harmful if swallowed. Ingestion of Formaldehyde, polymer with (chloromethyl)
oxirane and phenol may results in oral and esophageal burns.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage.
Prolonged and repeated skin contact may cause irritation and possibly dermatitis. May aggravate existing skin, eye or
lung conditions. Formaldehyde, polymer with (chloromethyl)oxirane and phenol may cause dermatitis, lung injury or
chemical pneumonia.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: Colds, allergies, eczema, psoriasis, and other skin
conditions, emphysema, asthma and other respiratory disorders.
Carcinogenicity:
None
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
Formaldehyde, polymer with (chloromethyl)oxirane and phenol 9003-36-5 30 -60
Mercaptan-terminated polymer 33007-83 -9 30 -60
2,4,6-Tri(dimethylaminomethyl)phenol 90-72 -2 3-7
Phenol 108-95-2 1-5
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately. Move patient to fresh air. Monitor for
respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or
pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with inhaled beta2 agonist and
oral or parenteral corticosteroids.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Immediately dilute
with 4 to 8 ounces (120 to 240 mL) of water or milk (not to exceed 4 ounces/120 mL in a child).
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
routes of entry.
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Section 5 - Fire Fighting Measures
Extinguishing Media: Alcohol, Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
Formaldehyde, polymer with (chloromethyl)
9003-36-5 N.E. N.E. N.E. N.E. N.E. N.E. No
oxirane and phenol
Mercaptan-terminated polymer 33007-83-9 N.E. N.E. N.E. N.E. N.E. N.E. No
2,4,6-Tri(dimethylaminomethyl)phenol 90-72-2 N.E. N.E. N.E. N.E. N.E. N.E. No
Phenol 108-95-2 5 PPM N.E. N.E. 5 PPM N.E. N.E. Yes
Exposure Notes: None.
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
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Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Not Established
Odor: Musty Odor Threshold: Not Established
Color: Clear Evaporation Rate: Not Applicable
Solubility in H2O: Not Established Specific Gravity: 1.1
Freeze Point: Not Established pH: Not Established
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Liquid Flammability: Non-Flammable
(Seta Closed Cup)
Flash Point, F: Greater than 200 Method:
Lower Explosive Limit, %: Not Established Upper Explosive Limit, %:Not Established
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
90-72-2 2,4,6-Tri(dimethylaminomethyl)phenol 2169 MG/KG ORAL -------------
108-95-2 Phenol 669 mg/Kg (rat) 316 mg/m3 (rat)
Significant Data with Possible Relevance to Humans: One animal study showed that in utero exposure (not neonatal)
of rats to bisphenol A, a compound similar to formaldehyde, polymer with (chloromethyl)oxirane and phenol, promotes
uterine disruption (thinning of the uterine epithelium during estrus) in offspring, probably by influencing expression and
distribution of these receptors.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
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EPA Waste Code if Discarded (40 CFR Section 261): none
Section 14 - Transportation Information
DOT Proper Shipping Consumer Commodity ("Corrosive Packing Group: None (III if not domestic by
Name: liquid, basic, organic, n.o.s., Ltd. ground)
Qty" by vessel)
DOT Technical Name: Mercaptan/amine blend Hazard Subclass: N.A.
DOT Hazard Class: ORM-D (8 by vessel, 9 by air) DOT UN/NA Number: None (UN3267 by vessel,
ID8000 by air)
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Phenol 108-95-2
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
None
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
None
California Proposition 65:
00079977001 English Page 6 of 6
None.
Section 16 - Other Information
HMIS Ratings:
Health: 2 Flammability: 1 Reactivity: 1 Personal Protection: X
Volatile Organic Compounds (VOC), less water less exempts: g/L: 33 lb/gal: 0.27 wt:wt%: 3.0
Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: wt:wt%: 0.0
REASON FOR REVISION: Periodic Update
Legend: N.A. ?Not Applicable ACGIH ?American Conference of Governmental Industrial Hygienists
N.E. ?Not Established SARA ?Superfund Amendments and Reauthorization Act of 1986
N.D. ?Not Determined NJRTK ?New Jersey Right-to-Know Law
VOC ?Volatile Organic Compound OSHA ?Occupational Safety and Health Administration
PEL ?Permissible Exposure Limit HMIS ?Hazardous Materials Identification System
TLV ?Threshold Limit Value NTP ?National Toxicology Program
CEIL ?Ceiling Exposure Limit STEL ?Short Term Exposure Limit
LD50 ?Lethal Dose 50 LC50 ?Lethal Concentration 50
F ?Degree Fahrenheit MSDS ?Material Safety Data Sheet
C ?Degree Celsius CASRN ?The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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