9/23/09 MATERIAL SAFTY DATA SHEET PLENCO 06401 PAGE 1
PLASTICS ENGINEERING COMPANY
3518 Lakeshore Rd.
Sheboygan, WI 53083
EMERGENCY TELEPHONE NUMBER: (920) 458-2127
For effective hazard communication, this MSDS must be made available to those who handle or use the
product and to those who control conditions of handling or use. Please send this MSDS to all appropriate
individuals in your organization, especially those responsible for health and safety.
PRODUCT INFORMATION
PRODUCT NAME: PLENCO 06401
CAS NO.: N/A
CHEMICAL FAMILY: Phenolic molding compound with two stage resin
CHEMICAL NAME: Phenol-formaldehyde polymeric molding compound
REVISION DATE: 03/21/96 REVISION NUMBER: 1
NOTE: Unless specifically indicated otherwise, the following information applies to the compound in the
form sold, not to articles, parts, etc. molded of the compound; in normal molding, the material
substantially completes its progression to a cross-linked insoluble, infusible solid.
SECTION 1 HEALTH HAZARD DATA
AS SOLD
The product is a plastic molding compound: A plastic resin (phenol-formaldehyde polymer) intimately
mixed and reacted with one or more of a variety of organic and/or inorganic filling materials. The plastic
resin is not believed or known to be hazardous. When fully "cured" or reacted, the plastic resin is insoluble,
infusible and binds the well- dispersed, embedded filling materials. However, "As Sold" the plastic resin is
not completely "cured" or reacted and contains some unreacted ingredients dissolved within it. So
dissolved, these chemicals are extremely unlikely to pose a hazard; but because they are hazardous in their
pure forms, OSHA requires that they be reported and described as hazardous ingredients (see below and
section 6). Under normal conditions of storage and handling, no significant amount of hazardous vapors
should evolve from the "As Sold" product. Because phenol is more soluble in the resin than in water, there
is no likely significant health hazard through skin absorption. The great majority of filling materials are
embedded within compound granules that are large enough not to constitute an inhalation hazard.
Nevertheless, some particles of plastic resin and/or filling materials may be present in a size that
constitutes a respirable dust (including, in some products, up to 1% inorganic filling material mixed in after
compounding). This respirable dust may contain one or more of the following materials: carbon black, coal
dust, fibrous glass, graphite, mica, mineral wool fiber, talc, and/or wood flour (soft). Chronic inhalation of
each of the above has been associated with fibrotic lung disease. For most or all, it has also been associated
with increased risk of lung cancer, especially among smokers. Inhalation of dust should be avoidable with
proper material handling procedures and good ventilation, but if not, respirators should be
9/23/09 MATERIAL SAFTY DATA SHEET PLENCO 06401 PAGE 2
worn. The primary acute health risk from exposure to the product "As Sold" is irritation, especially from
the dust. Ingestion, inhalation of dust, and contact with skin and eyes should be avoided.
AS USED:
During polymerization (e.g., curing of the product during normal processing) or decomposition (e.g.,
overheating or burning of the product) small amounts of gaseous ammonia, phenol and formaldehyde (as
well as water vapor, carbon monoxide and carbon dioxide) are evolved. Breathing of the fumes can be
harmful. If the odor of ammonia or formaldehyde is noticeable, then the airborne concentration of these
chemicals should be carefully monitored and ventilation improvements considered; These chemicals begin
to be detectable by odor at concentrations approaching or exceeding the PEL. The odor of phenol begins to
be noticeable at a concentration about one- fifth the PEL. In any case, adequacy of ventilation can best be
determined by use of instruments to monitor airborne concentrations of ammonia, phenol and
formaldehyde. Grinding or machining of cured molded material may create a dust that poses a respiratory
hazard if inhaled (see above) and may release small amounts of gaseous ammonia.
ACUTE OR CHRONIC HEALTH HAZARD INFORMATION
Ordinary use of this product is unlikely to produce significant exposure to hazardous chemicals. PELs for
these chemicals are set at levels designed to avoid any significant health risk and are achievable with
proper material handling procedures, ventilation and housekeeping. Nevertheless, per OSHA requirement,
we list the following possible health hazards if one were exposed to the following chemicals at levels much
higher, or in a different form, than expected from ordinary use of this product:
1. Phenol - Highly toxic.
Poisoning may occur via skin absorption, vapor inhalation, or ingestion.
Inhalation of the vapors may cause severe irritation to the nose, throat, and respiratory tract.
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May cause liver, kidney and heart damage.
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2. Formaldehyde - Irritant to eyes, lungs, and skin.
Has been shown to cause cancer in laboratory animals.
Listed as an IARC carcinogen.
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California law requires the following statement be included: contains a chemical (formaldehyde)
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known to the state of California to cause cancer.
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National Cancer Institute study finds little evidence to connect formaldehyde exposure with cancer
in humans.
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May cause respiratory sensitization.
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3. Ammonia ?Irritant to eyes and respiratory tracts.
POSSIBLE RESPIRABLE DUST COMPONENTS (Up to 8% may go thru 100 mesh):
4. Carbon black - Irritant to eyes and respiratory tracts.
Exposure at high levels is associated with declines in pulmonary function and cardio vascular
stress.
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9/23/09 MATERIAL SAFTY DATA SHEET PLENCO 06401 PAGE 3
5. Coal dust - Irritant to eyes, nose and throat.
Can cause respiratory effects such as pneumoconiosis, bronchitis, emphysema and progressive
massive fibrosis, with long exposure.
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6. Fibrous Glass ?Mechanical irritant to eyes, nose and skin.
Can cause irritation and inflammation of the nasopharyngeal region and upper respiratory tract.
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7. Graphite ?Irritant to eyes.
Can cause pneumoconiosis, although studies suggest that pneumoconiosis is a mixed dust reaction.
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8. Mica ?Irritant to eyes.
OSHA believes that the evidence strongly suggests that it is a pneumoconistic agent..
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9. Mineral Wool Fiber - Irritant to eyes and skin.
Several studies have shown excess risk of non malignant respiratory disease.
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10. Talc - Irritant to eyes, mucous membranes and respiratory tracts.
Medical evidence is complicated by the fact that talcs contain amphiboles and other minerals.
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11. Wood flour (soft) - Irritant to eyes, mucous membranes and upper respiratory tracts.
Various species of wood dust can elicit allergic contact dermatitis in sensitized individuals.
May cause respiratory sensitization.
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SECTION 2 FIRST AID
Eyes: Immediately flush eyes with copious amounts of water for at least 15 minutes.
Get medical attention.
Skin: Wash thoroughly with soap and water.
Inhalation: Use with adequate ventilation.
If breathing is affected, remove to fresh air.
If breathing stops, apply mouth to mouth resuscitation.
Get medical attention.
Ingestion: If conscious, give water immediately and induce vomiting by placing finger down throat.
Never give anything by mouth to an unconscious person.
Get medical attention.
9/23/09 MATERIAL SAFTY DATA SHEET PLENCO 06401 PAGE 4
SECTI0N 3 FIRE AND EXPLOSION DATA
Flash Point: No flash point
Flammable Limits: LEL: Dust .030 oz./per cubic foot UEL: No data
Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Special Fire Fighting Procedures: MSHA/NIOSH approved self-contained breathing apparatus
recommended. Avoid inhalation of gases.
Unusual fire and explosion hazards: Organic dust/air mixtures are highly flammable (explosive); avoid
dust accumulations or dust-laden atmospheres and sources of
ignition.
SECTI0N 4 CONTROL MEASURES
Work/Hygienic Practices: Eye wash and shower facility should be available. Practice good hygiene and
maintain a clean work environment.
Ventilation: Point source exhaust recommended to remove dust and vapors evolved during use (dust
collection system). Use explosion proof motors.
Respiratory Protection: NOISH approved respirators recommended if TLVs are exceeded.
Protective Clothing: Gloves recommended.
Eye Protection: Safety glasses with side shields.
Storage: Store in a cool, dry place. Keep containers closed to avoid contamination. Prevent
accumulations of dust. Avoid excessive heat and sources of ignition. Observe good
housekeeping practices.
SECTI0N 5 PHYSICAL DATA
Boiling Point: (760 mm Hg) N/A Specific Gravity: (H20 = 1) See technical data sheet
Vapor Pressure: (mm Hg 20 Deg C) N/A Percent Volatile: (by weight) N/A
Vapor Density: (Air = 1) N/A Evaporation rate: (Butyl acetate = 1) N/A
Heat of Vaporization: (Delta HV) N/A Solubility in water: (% by weight) Negligible
Appearance and Odor: Granular, nodular, pellet or briquette with slight odor of phenol
9/23/09 MATERIAL SAFTY DATA SHEET PLENCO 06401 PAGE 5
SECTI0N 6 HAZARDOUS INGREDIENTS/SARA TITLE III
Chemicals marked with an asterisk (*) are subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372.
CAS# PERCENT TLV/PEL
*Phenol 108-95-2 <6.3 ** ACGIH-TWA/SKIN 5 ppm
OSHA-TWA/SKIN 5 ppm
Carbon Black 1333-86-4 <12 ACGIH-TWA 3.5 mg/m 3
OSHA-TWA 3.5 mg/m3
Coal Dust <18 ACGIH-TWA 2 mg/m3
OSHA-TWA<5% SiO2 2.4 mg/m3
%SiO2+ 2
OSHA-TWA>5% SiO2 10 mg/m3
%SiO2 + 2
Graphite 7782-42-5 <40 ACGIH-TWA 2 mg/m3
OSHA-TWA 15 mppcf
Mica 12001-26-2 <60 ACGIH-TWA 3 mg/m3
OSHA-TWA 20 mppcf
Talc 14807-96-6 <20 ACGIH-TWA 2 mg/m3
OSHA-TWA 20 mppcf
Particulates not otherwise classified (PNOC) <70 ACGIH-TWA/INHAL 10 mg/m3
ACGIH-TWA/RESPIR 3 mg/m3
OSHA-TWA/TOTAL 15 mg/m3
OSHA-TWA/RESPIR 5 mg/m3
** More precise information on the amount of this chemical in the products you buy is available upon
request from the Plenco Safety Department.
SECTI0N 7 REACTIVITY DATA
Stability: Stable
Avoid contamination, exposure to flame or heat, or storage at temperatures in excess of 100
degrees F.
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Incompatibility: Like most organic materials, this product is sensitive to strong oxidizing agents and
may either decompose or ignite when mixed with same.
Hazardous Decomposition Products: Vapors evolved during polymerization may contain phenol,
formaldehyde or ammonia.
Hazardous polymerization: Should not occur.
9/23/09 MATERIAL SAFTY DATA SHEET PLENCO 06401 PAGE 6
SECTI0N 8 SPILL, LEAK, AND DISPOSAL
Spill or Leak Procedure:
Vacuum or sweep with sweeping compound, sawdust or sand.
Avoid generating dust.
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Vacuums with explosion proof motors are recommended.
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This product contains free phenol which is subject to effluent limits under the Clean Water Act.
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Waste Disposal:
Bury or incinerate in accordance with local, state, and federal regulations.
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SECTI0N 9 TRANSPORTATION INFORMATION
Shipping Classification DOT Hazard Class
Plastic Materials VIZ: Non-Hazardous
Powdered form NMFC item #156200
SECTI0N 10 ADDITIONAL INFORMATION
N/A = Not Applicable
TOTAL = Total Dust
RESPIR. = Respirable Dust
FOR ADDITIONAL INFORMATION CALL: (920) 458-2127
The information set forth herein is furnished free of charge and is based on technical data which PLENCO
believes to be reliable. It is intended for use by persons having technical skills and at their own discretion
and risk. Since conditions of use are outside our control, we make no warranties, expressed or implied, and
assume no liability in connection with your use of this information.
PLASTICS ENGINEERING COMPANY
THIS IS THE LAST PAGE PRINT DATE: 9/23/09 TIME: 14:52
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