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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 02/27/2008 Reviewed on 02/27/2008
1 Identification of substance
?Product details
?Trade name: 39747 Multi-Purpose Panel Adhesive
?Article number: 39747
?Manufacturer/Supplier:
SEM Products Inc.
651 Michael Wylie Dr.
Charlotte, NC 28217
(704)522-1006
?Information department:
labsupport@sem.ws : SEM Products 651 Michael Wylie Dr. Charlotte, NC 28217 : phone 1-704-522-1006, M -
TH 7am - 4pm EDT
?Emergency information: 24 HR EMERGENCY CHEMTREC 1-800-424-9300
2 Composition/Data on components
?Chemical characterization
?Description: Mixture of the substances listed below with nonhazardous additions.
?Dangerous components:
37244-96-5 NEPHELINE SYENITE 10-25%
Warning: 3.3/2A, 3.8/3
28064-14-4 BISPHENOL F EPOXY RESIN 2.5-10%
Warning: 3.2/2, 3.3/2A, 3.4.S/1, 3.8/3
163440-98-0 ELASTOMER MODIFIED DIGLYCIDAL ETHER 2.5-10%
Warning: 3.2/2, 3.3/2A, 3.4.S/1, 3.8/3
65997-17-3 Glass 2.5-10%
Warning: 3.2/2, 3.3/2A, 3.8/3
108-95-2 phenol 2.5-10%
Danger: 3.1.O/2, 3.1.D/2, 3.2/2, 3.3/2A, 3.4.S/1, 3.8/3; 3.4.R/1
14228-73-0 CYCLOHEXANEDIMETHANOL DIGLYCIDAL ETHER 2.5-10%
Warning: 3.8/2; 3.2/2, 3.3/2A, 3.4.S/1
Amine proprietary 2.5-10%
Warning: 3.2/2, 3.3/2A, 3.8/3
67762-90-7 FUMED SILICA 2.5-10%
Warning: 3.3/2A, 3.8/3
9046-10-0 POLYOXYPROPOLENEDIAMINE 1-2.5%
Danger: 3.1.O/3, 3.8/3; 3.2/1B
111-40-0 2,2'-iminodiethylamine 1-2.5%
Danger: 3.1.O/3, 3.1.D/3, 3.4.S/1; 3.2/1B
1%
2530-83-8 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane
Danger: 3.1.O/2, 3.1.D/3, 3.1.I/3, 3.2/2, 3.3/2A, 3.8/3
1%
25338-55-0 (DIMETHYLAMINO)METHYLPHENOL
Danger: 3.1.O/2, 3.1.D/2, 3.4.S/1, 3.8/3; 3.2/1B
Warning: 2.6/4
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(Contd. on page 2)
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Material Safety Data Sheet
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Printing date 02/27/2008 Reviewed on 02/27/2008
Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 1)
3 Hazards identification
?Hazard description:
Toxic
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Toxic in contact with skin and if swallowed.
Causes burns.
Irritating to respiratory system.
May cause sensitisation by inhalation and skin contact.
?Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
?NFPA ratings (scale 0 - 4)
Health = 2
1 Fire = 1
2 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
Fire = 1
FIRE 1
Reactivity = 0
REACTIVITY 0
?GHS label elements
Danger
3.1/3 - Toxic if swallowed.
3.1/3 - Toxic in contact with skin.
3.4/1 - May cause an allergic skin reaction.
3.8/3 - May cause respiratory irritation.
Danger
3.4/1 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Danger
3.2/1B - Causes severe skin burns and eye damage.
?Prevention:
Do not breathe dust/fume/gas/mist/vapours/spray.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
(Contd. on page 3)
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Material Safety Data Sheet
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Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 2)
Wear protective gloves/protective clothing/eye protection/face protection.
In case of inadequate ventilation wear respiratory protection.
?Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment (see label).
Specific measures (see label).
Rinse mouth.
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Remove/Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse.
?Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
4 First aid measures
?General information:
Immediately remove any clothing soiled by the product.
In case of irregular breathing or respiratory arrest provide artificial respiration.
?After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
?After swallowing:
Do not induce vomiting; immediately call for medical help.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
5 Fire fighting measures
?Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
(Contd. on page 4)
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Material Safety Data Sheet
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Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 3)
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires: No special measures required.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
108-95-2 phenol
PEL 19 mg/m? 5 ppm
Skin
REL Short-term value: C60* mg/m? C 15.6* ppm
Long-term value: 19 mg/m? 5 ppm
*15-min; Skin
TLV 19 mg/m? 5 ppm
Skin; BEI
111-40-0 2,2'-iminodiethylamine
REL 4 mg/m? 1 ppm
Skin
TLV 4.2 mg/m? 1 ppm
Skin
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 5)
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Material Safety Data Sheet
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Printing date 02/27/2008 Reviewed on 02/27/2008
Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 4)
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Liquid
Form:
According to product specification
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 181癈 (358癋)
94癈 (201癋)
?Flash point:
595癈 (1103癋)
?Ignition temperature:
Product is not selfigniting.
?Auto igniting:
Product does not present an explosion hazard.
?Danger of explosion:
In use, may form flammable/explosive vapour-air mixture.
1.05 g/cm?br>
?Density at 20癈 (68癋):
?Solubility in / Miscibility with
Not miscible or difficult to mix.
Water:
?Solvent content:
0.0 %
Organic solvents:
1.4 g/l / 0.01 lb/gl
VOC content:
(Contd. on page 6)
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Material Safety Data Sheet
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Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 5)
99.9 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
108-95-2 phenol
Oral LD50 317 mg/kg (rat)
Dermal LD50 850 mg/kg (rabbit)
?Primary irritant effect:
?on the skin: Caustic effect on skin and mucous membranes.
?on the eye: Strong caustic effect.
?Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
12 Ecological information
?General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 7)
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Material Safety Data Sheet
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Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 6)
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?DOT regulations:
8
?Hazard class:
UN2922
?Identification number:
III
?Packing group:
?Proper shipping name (technical name): C O R R O S I V E LIQUID, TOXIC, N.O.S.
(POLYOXYPROPOLENEDIAMINE, phenol)
8+6.1
?Label
ORM-D 49CFR ?173.154 b) Limited Quantities of Class 8
?Remarks:
?Land transport TDG (Canada) and ADR/RID (Europe):
8 Corrosive substances
?Hazard class:
2922
?UN-Number:
III
?Packaging group:
8+6.1
?Label:
2922 CORROSIVE LIQUID, TOXIC, N.O.S.
?Description of goods:
(POLYOXYPROPOLENEDIAMINE, phenol)
?Maritime transport IMDG:
8
?IMDG Class:
2922
?UN Number:
8+6.1
?Label
III
?Packaging group:
F-A,S-B
?EMS Number:
No
?Marine pollutant:
CORROSIVE LIQUID, TOXIC, N.O.S.
?Propper shipping name:
(POLYOXYPROPOLENEDIAMINE, phenol)
(Contd. on page 8)
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Material Safety Data Sheet
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Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 7)
?Air transport ICAO-TI and IATA-DGR:
8
?ICAO/IATA Class:
2922
?UN/ID Number:
8+6.1
?Label
III
?Packaging group:
CORROSIVE LIQUID, TOXIC, N.O.S.
?Propper shipping name:
(POLYOXYPROPOLENEDIAMINE, phenol)
?UN "Model Regulation": UN2922; CORROSIVE LIQUID, TOXIC, N.O.S.; 8 (6.1); III
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
108-95-2 phenol
107-15-3 ethylenediamine
?Section 313 (Specific toxic chemical listings):
163440-98-0 ELASTOMER MODIFIED DIGLYCIDAL ETHER
108-95-2 phenol
25338-55-0 (DIMETHYLAMINO)METHYLPHENOL
107-21-1 ethanediol
67-56-1 methanol
?TSCA (Toxic Substances Control Act):
108-95-2 phenol
111-40-0 2,2'-iminodiethylamine
112-24-3 3,6-diazaoctanethylenediamin
919-30-2 3-aminopropyltriethoxysilane
2530-83-8 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane
616-47-7 1-methylimidazole
1760-24-3 N-(3-(trimethoxysilyl)propyl)ethylenediamine
140-31-8 2-piperazin-1-ylethylamine
1333-86-4 Carbon black
107-21-1 ethanediol
67-56-1 methanol
107-15-3 ethylenediamine
64-17-5 ethanol
?Proposition 65
?Chemicals known to cause cancer:
28064-14-4 BISPHENOL F EPOXY RESIN
(Contd. on page 9)
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Material Safety Data Sheet
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Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 8)
163440-98-0 ELASTOMER MODIFIED DIGLYCIDAL ETHER
1333-86-4 Carbon black
107-21-1 ethanediol
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
64-17-5 ethanol
?Cancerogenity categories
?EPA (Environmental Protection Agency)
108-95-2 phenol D
107-15-3 ethylenediamine D
?IARC (International Agency for Research on Cancer)
108-95-2 phenol 3
1333-86-4 Carbon black 2B
?NTP (National Toxicology Program)
None of the ingredients is listed.
?TLV (Threshold Limit Value established by ACGIH)
108-95-2 phenol A4
1333-86-4 Carbon black A4
107-21-1 ethanediol A4
107-15-3 ethylenediamine A4
64-17-5 ethanol A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
1333-86-4 Carbon black
?OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Toxic
?Hazard-determining components of labelling:
phenol
BISPHENOL F EPOXY RESIN
ELASTOMER MODIFIED DIGLYCIDAL ETHER
CYCLOHEXANEDIMETHANOL DIGLYCIDAL ETHER
2,2'-iminodiethylamine
?Risk phrases:
Toxic in contact with skin and if swallowed.
Causes burns.
Irritating to respiratory system.
May cause sensitisation by inhalation and skin contact.
(Contd. on page 10)
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Material Safety Data Sheet
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Trade name: 39747 Multi-Purpose Panel Adhesive
(Contd. of page 9)
?Safety phrases:
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
This material and its container must be disposed of as hazardous waste.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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