MATERIAL SAFETY DATA SHEET

Manufactured by:                                      Distributed by:

Marianna Industries, Inc.                             Durvet

11222 "I" Street                                      100 SE Magellan Dr

Omaha, Nebraska 68137-1296                            Blue Springs MO 64014

                                                      Non-Emergency (816) 229-9101

                                                      EMERGENCY: (800) 424-9300









Revised: 03/2009



I.     PRODUCT INFORMATION                                                           Page 1



PRODUCT NAME: Hydrogel Spray with Phenol



CHEMICAL NAME:



CAS NUMBER:



CHEMICAL FAMILY:



CHEMICAL FORMULA:



 II.    SUMMARY OF HAZARDS

Product contains Phenol. Phenol is a known poison to humans. Large dosages can be fatal. Eye

contact may cause burns or blindness. This product is not for human use.





III.   HAZARDOUS COMPONENTS

                                        EXPOSURE LIMITS

       NAME                    CAS NO. %        PEL                TLV       OTHER

Phenol 0.40%                   108-95-2         5ppm               5ppm





IV.    CHEMICAL AND PHYSICAL PROPERTIES



BOILING POINT: NA                                     VAPOR PRESSURE: NA



MELTING POINT: NA                                     VAPOR DENSITY: NA



SOL. IN WATER: Yes                                    SPECIFIC GRAVITY: 1.000-1.003



pH:5.00-5.50 @ 22c



APPEARANCE/ODOR: Clear Liquid



EVAPORATION RATE: NA                          .

V.           HEALTH HAZARD DATA & FIRST AID PROCEDURES                                    Page 2



                                                 TOXICITY DATA

CHEMICAL NAME                            LD50                        LC50

Phenol                                   317mg/KG Rat               315mg/m3 Rat

                                         850mg/Kg Rabbit Skin       5mg Severe eye Rabbit



EYE CONTACT: Wash eyes with plenty of water for at least 15 minutes, lifting lower and upper eye

lids occasionally, Get immediate medical attention.



SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at

least15minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Call a

Physician immediately.



INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is

difficult, give artificial respiration. If breathing is difficult, give oxygen. Call Physicians



INGESTION: If swallowed, get immediate medical attention. Give large quantities of milk

or water. Never give anything by mouth to an unconscious person. May cause burns, pain bleeding,

central nervous system depression. Early symptoms included Headaches, drunken behavior, nausea,

diarrhea, vomiting, tiredness and drowsiness.



CHRONIC EFFECTS OF EXPOSURE: May cause damage, disorders or adversely affect the

following systems, organs: Kidneys, liver, nervous system, skin or lungs.



 VI.       EXPOSURE CONTROL MEASURES



EYE PROTECTION: Chemical goggles, faceshield always wear eye protection when working with

chemicals.



PROTECTIVE GLOVES: Imperious gloves clean body covering.



RESPIRATORYPROTECTION: None required normally. If exposure limits are exceeded or if

exposure may occur use a NIOSH/MSHA respirator approved for your conditions of exposure.



OTHER PROTECTION: Safety shower, eye wash stations.



VENTILATION: Adequate ventilation is required to minimize exposure or maintain exposure levels

below OSHA/ACGIH requirements



PERSONAL HYGIENE/WORK PRACTICES: Always a wash hand with warm soapy water after all

uses.



 VII.        FIRE AND EXPLOSION HAZARD DATA



FLASH POINT (METHOD USED) : NA



FLAMMABLE LIMITS                         LOWER:                  UPPER:



EXTINGUISHING MEDIA: Water, Carbon Dioxide, dry chemical foam.



FIRE FIGHTING INSTRUCTIONS: Prevent human exposure to fire, fumes, smoke and product

combustion.



UNUSUAL FIRE AND EXPLOSION HAZARDS: None

Hydrogel Spray with Phenol

 VIII.       REACTIVITY DATA                                                                    Page 3



STABILITY: Stable at room temperatures



INCOMPATIBILITY: Oxidizers



HAZARDOUS PRODUCTS OF COMPOSITION: Phenol <1%



HAZARDOUS POLYMERIZATION: None known.



 XI.       ENVIRONMENTAL & DISPOSAL INFORMATION



GENERAL: Evacuate non essential personnel, Shut of source of the leak. Recover free product.

Clean residue, flush sparingly with water or use an absorbent. Avoid runoff to ground water, surface

water, or sewers. It may be necessary to remove contaminated soil. Notify state and local authorities.



ACTION TO TAKE FOR SPILLS/LEAKS:



DISPOSAL METHOD: Solids must be disposed of in a permitted hazardous waste management

facility. Recovered liquids may be reprocessed or incinerated. Incineration must be handled in a

permitted hazardous waste management facility Dispose of material in accordance with all Federal,

State and Local regulations.



 X.    PRECAUTIONS FOR SAFE HANDLING, STORAGE AND USE

Wear protective equipment when handling. Use only with adequate ventilation. Wash thoroughly

after handling. Do not breather vapor or mist. Do not get in eyes, on skin, or clothing. Do not

swallow.



XI.       SHIPPING INFORMATION





 XII.        ADDITIONAL INFORMATION



THIS MATERIAL IS IN COMPLIANCE WITH THE TOXIC SUBSTANCES CONTROL ACT



For additional product safety or product use information, contact the Product Manager at

Address or phone number listed on page one.





                                                  DISCLAIMER

The information in this MSDS was obtained from current and reliable sources. However, the data is provided

without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions for use,

handling, storage and disposal of this product are beyond this company's control it is the users responsibility

both to determine safe conditions for use of this product and to assume liability for loss, injury, damage or

expense arising out of the product's improper use. No warranty, expressed or implied, regarding the product

described herein shall be created by of inferred from any statement or omission in this MSDS. Various

government agencies (e.g. DOT, EPA and FDA) may have specific regulations concerning the transportation,

handling, storage, use or disposal of this product which may not be reflected in this MSDS. The user should

review these regulations to ensure full compliance.





Hydrogel Spray with Phenol