Material Safety Data Sheet
Page 1 of 8 Issue date: July 2009
AD-1147
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: AD-1147
Synonym: None
Use: Polyurethane Adhesive
Era Polymers Pty Ltd
25-27 Green Street
East Botany NSW 2019
Australia
Ph: +61 2 9666 3788
Fax: +61 2 9666 4805
Emergency Advice All Hours:
Technical Manager +61 2 9666 3788
2. HAZARDS IDENTIFICATION
HAZARDOUS ACCORDING TO NOHSC CRITERIA
Hazard Category: Harmful (Xn), Irritant (Xi)
Hazard Classification: HAZARDOUS SUBSTANCE, DANGEROUS GOOD
RISK PHRASES
R11 Highly flammable.
R20/21 Harmful by inhalation and in contact with skin.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R67 Vapours may cause drowsiness and dizziness.
SAFETY PHRASES
S7/9 Keep container tightly closed and in a well-ventilated place.
S16 Keep away from sources of ignition - No smoking.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and contact a doctor.
S36/37 Wear suitable protective clothing and gloves.
Poison Schedule: S6 [Aust]
This material is a Scheduled S6 Poison and must be stored, handled and used according to the appropriate regulations.
Warning Statement:
Avoid breathing vapours. Avoid skin and eye contact. Skin contact may cause allergic reaction. Avoid release to the
aquatic environment. Flammable.
3. COMPOSITION / INFORMATION ON INGREDIENTS
SUBSTANCE NAME Proportion CAS Number
ISOPROPANOL (ISOPROPYL ALCOHOL) 30 to 60% 67-63-0
TOLUENE 30 to 60% 108-88-3
PHENOL-FORMALDEHYDE POLYMER 10 to 30% 9003-35-4
ETHANOL 1 to 10% 64-17-5
PHENOL 1 to 10% 108-95-2
All other ingredients not hazardous according to NOHSC Criteria.
Material Safety Data Sheet
Page 2 of 8 Issue date: July 2009
AD-1147
4. FIRST AID MEASURES
Swallowed:
If swallowed, seek medical attention immediately. Only induce vomiting at the instructions of a medical professional.
Eye:
If material is splashed into eyes, flush with plenty of water for at least 15 minutes, ensuring eyelids are held open. Seek
medical attention immediately.
Skin:
If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with water and soap.
Seek medical attention. Do not reuse contaminated clothing without laundering.
Inhaled:
Remove victim to fresh air. Apply resuscitation if victim is not breathing. Administer oxygen if breathing is difficult.
Seek medical attention if there are persistent symptoms.
First Aid Facilities:
Eye wash fountain, safety shower and normal washroom facilities.
Advice to Doctor:
Treat symptomatically.
In case of poisoning, contact Poisons Information Centre
In Australia call Tel: 131126
In New Zealand Tel: 034747000
5. FIRE-FIGHTING MEASURES
Fire/Explosion Hazard
EXTINGUISHING MEDIA: Use water spray, alcohol foam, carbon dioxide or dry chemical to extinguish fires.
SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus (SCBA) required for fire-fighting
personnel. If possible to do so safely, shut off fuel to fire. Use water spray to spray to cool fire-exposed surfaces and to
protect personnel.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapours from this product may travel or be moved by air currents
and be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharge or other
ignition sources at locations distant from the point of handling.
HAZCHEM CODE: 3[Y]E [Aust]
FLAMMABILITY
Highly flammable liquid. Avoid all sources of ignition, heat and naked flames. Vapours may travel a considerable
distance to source of ignition and ignite.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS:
Where exposure level is known, wear approved respirator suitable for level of exposure. Where exposure level is not
known, wear approved positive pressure self-contained respirator. In addition to the protective clothing / equipment in
Section 8 (Exposure Controls / Personal Protection), wear impermeable boots.
METHODS FOR CLEANING UP:
Remove sources of ignition. Cover spills with some inert absorbent material; sweep up and place in a waste disposal
container. Flush spill area with water.
Material Safety Data Sheet
Page 3 of 8 Issue date: July 2009
AD-1147
7. HANDLING AND STORAGE
Store in a cool place and out of direct sunlight. Store away from sources of heat or ignition, strong alkalis, acids,
combustibles and oxidizing agents. All equipment must be earthed. Store in original packages as approved by
manufacturer. Check all fittings, valves, reticulation (piping) and any ancillary equipment for leaks. A supplied air
respirator or a Self-Contained Breathing Apparatus (SCBA) for emergencies should be available and checked regularly.
Areas containing this material should have fire safe practices and electrical equipment in accordance with applicable
regulations and/or guidelines. In Australia, refer to AS1940 - The Storage and Handling of Flammable and
Combustible Liquids.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards
No exposure standards are available for this product, however, the following exposure standards have been assigned by
[NOHSC] to the following components of the product:
ISOPROPANOL (ISOPROPYL ALCOHOL)
(Worksafe Australia)
[TWA] 400 ppm 983 mg/m?br>
[STEL] 500 ppm 1,230 mg/m?br>
References: H;R
(ACGIH)
[TWA] 400 ppm 983 mg/m?br>
[STEL] 500 ppm 1,230 mg/m?br>
TOLUENE
(Worksafe Australia)
[TWA] 100 ppm 377 mg/m?br>
[STEL] 150 ppm 565 mg/m?br>
References: H;R
(ACGIH)
[TWA] 50 ppm 188 mg/m?br>
Carcinogen Category: A4
Notices: Sk
PHENOL-FORMALDEHYDE POLYMER
No Exposure details available
ETHANOL
(Worksafe Australia)
[TWA] 1,000 ppm 1,880 mg/m?br>
References: H
(ACGIH)
[TWA] 1,000 ppm 1,880 mg/m?br>
Carcinogen Category: A4
PHENOL
(Worksafe Australia)
[TWA] 1 ppm 4 mg/m?br>
Notices: Sk
References: A
(ACGIH)
[TWA] 5 ppm 19 mg/m?br>
Carcinogen Category: A4
Material Safety Data Sheet
Page 4 of 8 Issue date: July 2009
AD-1147
Engineering Controls
Highly flammable liquid. Maintain adequate ventilation at all times. Utilise a closed system process where feasible.
Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to
control exposure. Prevent accumulation of vapours in hollows or sumps. Eliminate any sources of ignition.
Personal Protection Equipment
CLOTHING: Wear suitable protective clothing to prevent contamination of skin.
GLOVES: Wear impermeable gloves to prevent contamination of skin.
EYES: Wear eye/face protection such as chemical splash proof goggles or face shield. Provide eye wash fountain and
safety shower in close proximity to points of potential exposure.
RESPIRATORY PROTECTION: Avoid breathing of vapours/gases. Select and use respirators in accordance with
AS/NZS 1715/1716. When gases exceed the exposure standards then the use of a half-face respirator with organic
vapour cartridge is recommended. For high concentrations use an atmosphere-supplied, positive pressure demand self-
contained or airline breathing apparatus, complying with the requirements of AS/NZS 1715 is recommended. Filter
capacity and respirator type depends on exposure levels and type of contaminant. If entering spaces where the airborne
concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive
pressure air supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is
recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Amber liquid
Boiling Point Melting Point: Not determined
Vapour Pressure: Not determined
Specific Gravity: 0.885 (calculated)
Flash Point: Approx. 10癈 (closed cup)
Flammability Limits: Not determined
Solubility in Water: Not determined
Other Properties
None determined.
10. STABILITY AND REACTIVITY
STABILITY:
Stable under normal conditions of use.
HAZARDOUS DECOMPOSITION PRODUCTS:
May emits oxides of carbon and nitrogen, phenols, formaldehyde, butyraldehyde, butyric acid, acrolein,
crotonaldehyde, sulphur and silicon when heated to decomposition.
HAZARDOUS POLYMERIZATION:
May occur.
INCOMPATIBILITIES:
Avoid strong oxidisers, alkaline materials and acids.
CONDITIONS TO AVOID:
Heat, sparks, flames, ignition sources and incompatibles.
Material Safety Data Sheet
Page 5 of 8 Issue date: July 2009
AD-1147
11. TOXICOLOGICAL INFORMATION
No adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and
the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE HEALTH EFFECTS:
Swallowed:
Harmful if swallowed.
May cause irritation to mouth, throat and stomach with effects including mucous build up, irritation to the tongue and
lips and pains in the stomach, which may lead to nausea, vomiting and diarrhoea.
Eye:
Will cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. Depending upon
duration of exposure, eye damage may occur.
Skin:
Harmful by skin contact.
Will cause irritation to the skin, with effects including: redness, itchiness, and possible dermatitis.
Inhaled:
Harmful if inhaled.
May cause irritation to the nose, throat and respiratory system with effects including: dizziness, headache and loss of
co-ordination.
Chronic:
Prolonged or repeated skin contact may lead to dermatitis.
Prolonged contact may cause severe eye irritation and some form of permanent eye damage may occur.
Product may also be absorbed through the skin with resultant toxic effects.
Prolonged or repeated exposure may lead to irreversible damage to health.
Prolonged or repeated contact with this substance will cause sensitisation by skin contact.
Toxicological Data:
ACUTE TOXICITY DATA:
Oral: LD50 (rat) > 3300 mg/kg
Dermal: LD50 (rabbit) > no data
Inhalation: LC50 (rat, 4 hour) > 5 mg/L
LOCAL EFFECTS ON SKIN AND EYE:
Dermal: irritating
Eye: no data
ALLERGIC SENSITISATION:
Dermal: sensitising
Inhalation: no data
GENOTOXICITY:
Ames Salmonella Assay: no data
Toxicological Data for Ingredient(s):
ACUTE TOXICITY DATA:
(1) Isopropanol
Oral: LD50 (rat) = 5000 mg/kg
Dermal: LD50 (rabbit) = 12800 mg/kg
Inhalation: LC50 (rat, 4 hour) > 16000 ppm
Material Safety Data Sheet
Page 6 of 8 Issue date: July 2009
AD-1147
(2) Toluene
Oral: LD50 (rat) = 5580 mg/kg
Dermal: LD50 (rabbit) = 12124 mg/kg
Inhalation: LC50 (rat, 4 hour) = 5060 ppm
Inhalation: LC50 (4 hour) = 8000 ppm
(3) Ethanol
Oral: LD50 (rat) = 7060 mg/kg
Dermal: LD50 (rabbit) = 20000 mg/kg
Inhalation: LC50 (rat, 10 hour) = 20000 ppm
(4) Phenol
Oral: LD50 (rat) = 414 mg/kg
Dermal: LC50 (rabbit) = 669 mg/kg
Inhalation: LC50 (rat, 4 hour) = 0.3 mg/L
(5) Formaldehyde
Oral: LD50 (rat) = 100 mg/kg
Dermal: LD50 (rabbit) = 270 mg/kg
Inhalation: LC50 (rat, 4 hour) = 250 - 478 ppm
LOCAL EFFECTS ON SKIN AND EYE:
(1) Isopropanol
Eye: irritating
(2) Toluene
Dermal: no data
Eye: no data
(3) Ethanol
Dermal: not irritating
Eye: irritating
(4) Phenol
Dermal: corrosive
Eye: causes severe damage
(5) Formaldehyde
Dermal: irritating
Eye: causes serious damage
(6) Phenol-formaldehyde polymer
Eye: irritating
ALLERGIC SENSITISATON:
(1) Formaldehyde
Dermal: sensitising
Inhalation: not sensitising
(2) Phenol-formaldehyde polymer
Dermal: sensitising
OTHER INFORMATION:
(1) Toluene
Reproductive toxin in laboratory animals
(2) Ethanol
Human teratogen
Human reproductive toxin
(3) Formaldehyde
Carcinogenic to laboratory animals
May cause irritation of respiratory tract and eyes
The International Agency for Research on Cancer (IARC) has classified formaldehyde as a Group 1 (known) human
carcinogen based on epidemiological evidence linking formaldehyde exposure to the occurrence of nasopharyngeal
cancer, a rare type of cancer. IARC also found limited evidence of cancer of the nasal cavity and paranasal sinuses and
insufficient evidence for an association between formaldehyde and leukaemia.
Material Safety Data Sheet
Page 7 of 8 Issue date: July 2009
AD-1147
12. ECOLOGICAL INFORMATION
Ecotoxity:
There is no information available for this substance.
Mobility:
There is no information available for this substance.
Persistence / Degradability:
There is no information available for this substance.
Chemical Fate Information:
No adverse environmental effects are expected with proper use and disposal of this product. The ecological assessment
for this material is based on an evaluation of its components. This product may cause long-term adverse effects in the
aquatic environment, so avoid release to watercourses, sewers and drains.
13. DISPOSAL CONSIDERATIONS
Recycling, recovery and reuse of material is encouraged where permitted. If disposal is necessary, it is recommended
that the material be disposed of by thermal treatment or incineration at approved facilities. All local and national
regulations should be followed.
14. TRANSPORT INFORMATION
Road Transport
UN Number: 1133
Proper Shipping Name: ADHESIVES
Dangerous Goods Class: 3
Packing Group: II
Label: Harmful (Xn), Irritant (Xi)
Air Transport
UN Number: 1133
Proper Shipping Name: ADHESIVES
Dangerous Goods Class: 3
Packing Group: II
Label: Harmful (Xn), Irritant (Xi)
Sea Transport
UN Number: 1133
Proper Shipping Name: ADHESIVES
Dangerous Goods Class: 3
Packing Group: II
Label: Harmful (Xn), Irritant (Xi)
15. REGULATORY INFORMATION
Poison Schedule: S6 [Aust]
Inventory Status:
Inventory Status
Australia (AICS) Y
United States (TSCA) Y
Canada (DSL) Y
Europe (EINECS) Y
Y = all ingredients are on the inventory or are not required to be listed on the inventory.
Material Safety Data Sheet
Page 8 of 8 Issue date: July 2009
AD-1147
16. OTHER INFORMATION
Date of Preparation:
Issue date: 10 July 2009
Supersedes: April 2005
Reasons for Update:
Review in all sections
Key Legend Information:
NOHSC - National Occupational Health & Safety Commission {Formerly Worksafe}[Aust]
SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons [Aust]
TWA - Time Weighted Average [Int]
STEL - Short Term Exposure Limit [Int]
AICS - Australian Inventory of Chemical Substances
EPA - Environmental Protection Agency [Int]
NIOSH - National Institute for Occupational Safety and Health [US]
AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust/NZ]
AS/NZS 1716 - Respiratory protective devices. [Aust/NZ]
IATA - International Aviation Transport Authority [Int]
ICAO - International Civil Aviation Organization [Int]
IMO - International Maritime Organisation. [Int]
IMDG - International Maritime Dangerous Goods [Int]
United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the
classification and labelling of Chemicals. [Int]
EU - European Union
[Aust/NZ] = Australian New Zealand
[Int] = International
[US] = United States of America
Removal of the heading of Poison Schedule [Aust], in section 3 and 15 of this Material Safety Data Sheet (MSDS)
makes this a valid health and safety document in other international jurisdictions/countries. For full compliance please
contact your Federal, State or Local regulators for further information.
Disclaimer
This MSDS summarises our best knowledge of the health and safety hazard information available on the product and
the measures to be used to handle and use the product safely. Each user should read this MSDS and consider the
information in connection with the way the product is intended to be handled or used.
Principal References:
Information supplied by manufacturer, reference sources including the public domain.
END OF MSDS
|