MATERIAL SAFETY DATA SHEET (MSDS)
MATERIAL SAFETY DATA SHEET
EM SCIENCE
|1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufacturer.............: Preparation Date.: 9/9/97
EM SCIENCE
A Division of EM Industries Information Phone Number.: 856-423-6300
P.O. Box 70 Hours: Mon. to Fri. 8:30-5
480 Democrat Road Chemtrec Emergency Number: 800-424-9300
Gibbstown, N.J. 08027 Hours: 24 hrs a day
Catalog Number(s):
6610 6650 PX0509 PX0510 PX0510MB PX0514 PX0515
Product Name:
Phenol
Synonyms:
Carbolic Acid
Chemical Family:
Aromatic Acid
Formula:
C6H5OH
Molecular Weight.:
94.11
2. COMPOSITION / INFORMATION ON INGREDIENTS
Component CAS # Appr %
____________________________________________________________
Phenol
108-95-2 100%
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Hazardous Liquid Or Solid.
CAUSES SEVERE BURNS.
HARMFUL IF INHALED, SWALLOWED OR ABSORBED THROUGH SKIN.
COMBUSTIBLE LIQUID AND VAPOR.
May Cause Damage To Central Nervous System, Kidneys, Liver, Pancreas,
Heart, Spleen and Lungs.
Appearance:
Colorless or white to reddish crystals; medicinal odor
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
Symptoms of Exposure:
Highly toxic by inhalation, ingestion or skin contact. Causes burns on contact. The skin may turn white, and later yellowish-
brown and may be deeply eroded and scarred. Can cause headache, dizziness, muscle weakness, convulsions and death
(ingestion of 1.5 grams has killed). Absorption of phenolic solutions through the skin may be very rapid, and can cause death
within 30 minutes to several hours by exposure of as little as 64 square inches of skin. May cause damage to Central Nervous
System (CNS), kidneys, liver, pancreas, heart, spleen and lungs.
Medical Cond. Aggravated by Exposure:
Liver, kidney, CNS, respiratory,
pancreatic, and circulatory conditions.
Routes of Entry:
Inhalation, ingestion or skin contact.
Carcinogenicity:
The material is not listed (IARC, NTP, OSHA) as cancer causing
agent.
4. FIRST AID MEASURES
Emergency First Aid:
GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE.
Skin: Immediately flush thoroughly with large amounts of water.
Eyes: Immediately flush thoroughly with water for at least 15
minutes.
Inhalation: Remove to fresh air; give artificial respiration if
breathing has stopped.
Ingestion: Do not induce vomiting; get immediate medical
attention.
Remove contaminated clothing and wash before reuse.
5. FIRE FIGHTING MEASURES
Flash Point (F): 175F (cc)
Flammable Limits LEL (%): 1.80
Flammable Limits UEL (%): 8.60
Extinguishing Media:
Use water spray, foam, dry chemical, or CO2.
Fire Fighting Procedures:
Wear self-contained breathing apparatus and protective clothing.
Fire & Explosion Hazards:
Dangerous fire and explosive hazard. Potentially explosive reaction with aluminum chloride + nitromethane (at 110C/100
bar); formaldehyde; peroxydisulfuric acid; peroxymonosulfuric acid; sodium nitrite + heat. Violent reaction with aluminum
chloride + nitrobenzene (at 120C); sodium nitrate + trifluoroacetic acid; butadiene.
6. ACCIDENTAL RELEASE MEASURES
Spill Response:
Evacuate the area of all unnecessary personnel. Wear suitable protective equipment listed under Exposure / Personal
Protection. Eliminate any ignition sources until the area is determined to be free from explosion or fire hazards. Contain the
release and eliminate its source, if this can be done without risk. Take up and containerize for proper disposal as described
under Disposal. Comply with Federal, State, and local regulations on reporting releases. Refer to Regulatory Information for
reportable quantity and other regulatory data.
7. HANDLING AND STORAGE
Handling & Storage:
Keep container tightly closed and protected against physical damage. Store in a cool, dry, well-ventilated area away from
ignition sources and oxidizers. Do not breathe dust or vapor. Do not get in eyes, on skin, or on clothing. Retained residue may
make empty containers hazardous; use caution!
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT:
Ventilation, Respiratory Protection, Protective Clothing, Eye Protection:
Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), a
NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations
also permit other NIOSH/MSHA respirators (negative pressure type) under specified conditions (see your safety equipment
supplier). Engineering and/or administrative controls should be implemented to reduce exposure. Material must be handled or
transferred in an approved fume hood or with equivalent ventilation. Protective gloves must be worn to prevent skin contact
(Neoprene or equivalent) Safety glasses with side shields must be worn at all times. Impervious protective clothing should be
worn to prevent skin contact.
Work/Hygenic Practices:
Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available.
EXPOSURE GUIDELINES
OSHA - PEL:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Phenol
5 19 X
ACGIH - TLV:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Phenol
5 19 X
If there are no exposure limit numbers listed in the Exposure Guidelines chart, this indicates that no OSHA or ACGIH
exposure limts have been established.
9. PHYSICAL AND CHEMCIAL PROPERTIES
Boiling Point (C 760 mmHg) : 181C
Melting Point (C) : 40.6C
Specific Gravity (H2 0 = 1) : 1.07
Vapor Pressure (mm Hg) : 1.0 40C
Percent Volatile by vol (%): 100%
Vapor Density (Air = 1) : 3.2
Evaporation Rate (BuAc = 1): 0.01
Solubility in Water (%) : Miscible
Appearance :
Colorless or white to reddish crystals; medicinal odor
10. STABILITY AND REACTIVITY
Stability: Yes
Hazardous Polymerization:
Does not occur
Hazardous Decomposition:
COx
Conditions to Avoid:
Heat above 100F (material discolors)
Materials To Avoid:
( ) Water
(X) Acids
( ) Bases
( ) Corrosives
(X) Oxidizers
(X) Other: Al, Mg, Pb and Zn are quickly attacked by
hot phenol Calcium hypochlorite, alkalies,
acetaldehyde
11. TOXICOLOGICAL INFORMATION
Toxicity Data
orl-rat LD50: 317 mg/kg ivn-mus LD50: 112 mg/kg
ihl-mus LC50: 177 mg/cu.m.
Toxicological Findings:
Tests on laboratory animals indicate material may cause tumors
and produce adverse mutagenic and reproductive effects.
Cited in Registry of Toxic Effects of Chemical Substances (RTECS)
12. DISPOSAL CONSIDERATIONS
EPA Waste Numbers: U188
Treatment:
Specified Technology - Incineration to a level below TCA (Total Constituent Analyses) levels. Contact your local permitted
waste disposal company (TSD) for permissible treatment site.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL
CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
13. TRANSPORT INFORMATION
DOT Proper Shipping Name:
Phenol, Solid
DOT ID Number :
UN1671
14. REGULATORY INFORMATION
TSCA Statement:
The CAS number of this product is listed on the TSCA Inventory.
SARA SARA CERCLA
Component EHS EHS TPQ RQ
(302) (lbs) (lbs)
____________________________________________________________
Phenol
Y 500/10000 1000
OSHA SARA
DeMinimis
Component Floor List 313
for SARA 313
(%)
____________________________________________________________
Phenol
Y Y 1.0
If there is no information listed on the regulatory information chart, this indicates that the chemical is not covered by the
specific regulation listed.
15. OTHER INFORMATION
Comments:
None
NFPA Hazard Ratings:
Health :3
Flammability :2
Reactivity :0
Special Hazards :
Revision History: 11/1/81 5/1/84 10/27/87 3/21/88
3/1/91 5/1/93 1/25/94 5/26/94 1/12/96
| = Revised Section
N/A = Not Available
N/E = None Establised
The statements contained herein are offered for informational purposes only and are based upon technical data that EM
Science believes to be accurate. It is intended for use only by persons having the necessary technical skill and at their own
discretion and risk. Since conditions and manner of use are outside our control, we make NO WARRANTY, EXPRESS OR
IMPLIED, OR MERCHANTABILITY, FITNESS OR OTHERWISE.
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