New Zealand Supplier: Car Clean Products NZ Limited
Address: 739 Great South Road
Otahuhu
Auckland
Telephone: 09 276 8232
Fax Number: 09 276 7952
Emergency Telephone: 0800 POISON (0800 764 766)
Date of MSDS Preparation: 25 November 2008 - version 2
Section 2. Hazards Identification
Flammable liquid. Eye and respiratory irritant. Not expected to be a sensitiser
Potential Health Effects
Swallowed Irritant
Eyes Irritant. Can cause painful burning or sting or eyes and lids
Skin Slight irritant except in very high concentrations may cause
dizziness, nausea and narcosis
Inhalation Slight Irritant
Product Name: Solvent Blend 44 Copyright?Car Clean Products NZ Ltd
Date of SDS : November 2008
Page 2 of 5
Section 3. Composition / Information on Ingredients
Ingredients Proportion (% mass) Cas No
N-Methylpyrrolidone >50 872-50-4
Toluene >20 108-88-3
Methylisobutylketone 20 108-10-1
Section 4. First Aid Measures
Routes of Exposure:
Eye Flush eye immediately with water. If persistent irritation occurs,
obtain medical attention
Skin Remove contaminated clothing. Wash skin with water using
soap. If irritation persists seek medical attention.
Ingestion Do not induce vomiting. Give nothing by mouth. If rapid recovery
does not occur, obtain medical attention
Inhalation Remove to fresh air. If rapid recovery does not occur, obtain
medical attention
Section 5. Fire Fighting Measures
Suitable Extinguishing media Foam, Dry Chemical Powder, Carbon Dioxide, and Sand
or earth may be used for small fires
Fire and Explosion hazards Flammable
Fire Fighting Instructions Fire fighters must wear full protective clothing and self
contained breathing apparatus. Carbon Monoxide may be
evolved. Product will float on water and can be reignited
on surface water
Hazchem 3Y
Section 6. Accidental Release Measures
Land Spill or Leaks Absorb with sand, earth or other non-flammable spill
material. Scrub contaminated surfaces with detergent
solution. Transfer spill to a labelled, sealable container for
safe disposal
Product Name: Solvent Blend 44 Copyright?Car Clean Products NZ Ltd
Date of SDS : November 2008
Page 3 of 5
Section 7. Handling and Storage
Handling Advice: Ensure good ventilation.
Storing Procedures: Store away from sparks, flames, or a build up of static
Electricity.
Section 8 Exposure Controls / Personal Protection
Engineering Controls: Avoid conditions of naked flames, static discharges,
sparks or electrical sources of ignition. Ensure good
ventillation
Personal Protective Equipment: For small quantities wear PVC gloves and safety goggles.
For bulk handling and transfer wear chemical
monogoggles. Wear silver shield gloves under gauntlet
type nitrile rubber gloves. Where local exhaust ventilation
is not available wear half mask respirator with organic
vapour cartridge NPF20
Section 9 Physical and Chemical Properties
Physical State: Liquid
Colour: Colourless
Odour: Aromatic, slight ammonia smell.
pH: Not applicable
Solubility in water: .515 %
Relative Vapour Density (air=1):
Boiling point,: 110癈
Flash Point,: 4癈 (ABEL)
Specific Gravity: 0.95
Vapour Pressure@ 25癈, mmHg: 3.1
Volatiles: 100%
Section 10. Stability and Reactivity
Chemical Stability Stable but partly decomposes in light. Flammable
Conditions to Avoid High temperatures above 40癈
Incompatibility Strong oxidizers, acids and alkalis
Hazardous Decomposition
Products Carbon Monoxide if incomplete combustion occurs
Product Name: Solvent Blend 44 Copyright?Car Clean Products NZ Ltd
Date of SDS : November 2008
Page 4 of 5
Section 11 Toxicological Information
Acute Oral Toxicity LD50 Rat (oral) 1660 (by composition mixture rule)
Acute Dermal Toxicity LD50 Rat (dermal) > 2000 mg / kg
Inhalation Slight Irritant
Toxicological Data Not expected to be carcinogenic, tumorgenic or
mutagenic
Section 12. Ecotoxicological Information
Environmental Precautions:
Ecological Toxicity Slight hazard to aquatic and soil organisms
Environmental Fate:
Soil Expected to evaporate fairly quickly and not
bioaccumulate
Water Expected to evaporate fairly quickly and not
bioaccumulate
Environmental Exposure Limits EEL water Not set
Section 13. Disposal Considerations
Dispose of waste as per local by-laws
Section 14 Transport Information
Road, Rail, Marine and Air Transport
UN No : 1993
Class-primary : 3
Packing Group : II
Proper Shipping Name: : Flammable Liquids N.O.S (n-methylpyrolidone)
Section 15 Regulatory Information
Classification 3.1B, 6.1D, 6.3B. 6.4A, 9.1C
Group Standard Solvents (flammable)
ERMA Approval No. HSR002650
Under the NZ Land Transport Rule Dangerous Goods 2005 up to 250L may be transported
on land without vehicle placarding or a DG endorsed drivers license providing it is not for
hire or direct reward.
Product Name: Solvent Blend 44 Copyright?Car Clean Products NZ Ltd
Date of SDS : November 2008
Page 5 of 5
Section 16 Other Information
Under the HSNO Regulations, for quantities of class 3.1B flammable liquids held on a site
over ;
?250L in containers > 5L or
500 L in containers < 5L a certificated approved handler is required to be available
?100L in containers > 5L or 250 L in containers < 5L, or 50L continuously open a
Location Test Certificate for storage is required
?250L hazchem site signage is required
?250L an emergency response plan is required