FLEXITALLIC L.P.
Material Safety Data Sheet
No. FDP-012
REVISED: 13 July 2009
Contact Number 281-604-2400
GENERAL INFORMATION
Manufacturer:
Flexitallic L.P.
6915 La Porte Road
Deer Park, TX 77536
Common Name, Trade Name, or Specification:
Permanite Fluoroseal DOT Hazard Code - N/A
1. HAZARDOUS INGREDIENTS AND EXPOSURE LIMITS
Although several of the ingredients used to formulate this product may be hazardous in the raw
state, the manufacturing process results in a solid, infusible form, binding or otherwise rendering
the mixture inert. We have identified below those hazardous constituents present in quantities
greater than 1% (0.1% for carcinogens) that may be released from the product by overheating,
burning, machining, abrading, or riveting.
CAS
Component Number % OSHA PEL ACGIH TLV
PTFE Binder None <95 N/A 3ppm(HFl) / 2ppm(CFl)
Rubber None <1 N/A N/A
Phenolic Resin None <1 N/A N/A
Acrylonitrile 107-13-1 <1 2 ppm 2 ppm
3
Methyl Isobutyl 108-10-1 <1 50 ppm
205 mg/m
Ketone
3
Ethyl Alcohol 64-17-5 <1 1000 ppm
1900 mg/m
Methyl Ethyl Ketone 3
78-93-3 <1 200 ppm
590 mg/m
2. PHYSICAL AND CHEMICAL CHARACTERISTICS
Melting Point - None Solubility in water - Insoluble Odor -None
Color - White Cord Specific Gravity - 0.4 - 0.5 Form - Solid
3. FIRE AND EXPLOSION DATA
Auto-ignition Temperature: This product is inherently flame resistent.
Flammable Limits in Air: % in Air by Volume: LEL: N/A UEL: N/A
Extinguisher Media: Carbon dioxide, chemical, or foam
Special Firefighting Procedure: Material in or near fires should be cooled with a water
spray or fog. A self-contained breathing apparatus, operating in the positive pressure
mode, and full fire fighting protective clothing should be worn for combative fires.
Unusual Fire and Explosion Hazards: Thermal decomposition or combustion may
produce dense smoke, oxides of carbon, and low molecular weight organic compounds
whose composition has not been characterized.
4. PHYSICAL HAZARDS AND REACTIVITY DATA
Stability: Stable at normal temperatures and storage conditions
Incompatibility: None
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not polymerize. This product is fully cured in the
manufacturing process.
5. HEALTH HAZARDS
Carcenogenicity NTP Listed IARC Listed OSHA Listed
PTFE Binder No No No
Rubber No No No
Phenolic Resin No No No
Acrylonitrile Yes Yes* Yes
M.I.B.K No No No
Ethyl Alcohol No No No
M.E.K No No No
* IARC classifies acrylonitrile as "probably carcinogenic to humans." (Group 2A)
RUBBER (POWDERED)
Inhalation hazards - May cause mild irritation of respiratory tract. Repeated and prolonged inhalation of
dust may lead to a benign pneumoconiosis. This condition may cause some lung function impairment but
is reversible with reduced exposure.
Other hazards - Eyes - may cause mild transient eye irritation.
PTFE (Teflon?
Inhalation of fumes from overheating PTFE may cause polymer fume fever, a temporary flu-like illness with
fever, chills, and sometimes cough, of approximately 24 hours duration. Smokers should avoid
contamination of tobacco products, and should wash their hands before smoking. Small amounts of
carbonyl fluoride and hydrogen fluoride may also be evolved when PTFE is overheated or burned.
Inhalation of low concentrations of Hydrogen Fluoride can initially include symptoms of choking, coughing,
and severe eye, nose and throat irritation. Possibly followed after a symptomless period of 1 to 2 days by
fever, chills, difficulty in breathing, cyanosis, and pulmonary edema. Acute or chronic overexposure to HF
can injure the liver and kidneys.
Inhalation, ingestion, or skin or eye contact with Carbonyl fluoride may initially include: skin irritation with
discomfort or rash; eye corrosion with corneal or conjunctival ulceration; irritation of the upper respiratory
passages; or temporary lung irritation effects with cough, discomfort, difficulty breathing, or shortness of
breath.
Individuals with preexisting diseases of the lungs may have increased susceptibility to the toxicity of excessive
exposures from thermal decomposition products.
PHENOLIC RESIN - CURED
Inhalation hazards - Dust may cause irritation of nasal and respiratory tracts. If formaldehyde vapors are
present, inhalation may cause a form of nasal cancer. Other hazards - Prolonged exposure can cause
irritation, redness, and tearingof the eyes and may lead to sensitization of the skin and dermatitis.
ACRYLONITRILE
Inhalation Hazards - Exposure to acrylonitrile may cause somnolence, general anesthesia, cyanosis, and
diarrhea. Symptoms include flushing of the face, salivation, irritation of the eyes and nose, photophobia,
deepened respiration, nausau, weakness, and headache. IARC classifies acrolynitrile as "probably
carcinogenic to humans." (Group 2A)
Other hazards - Acrolynitrile is a human systematic irritant and may be poisonous by skin absorption and
ingestion. Target organs include the liver, central nervous system, brain, kidneys, and cardiovascular
system.
METHYL ISOBUTYL KETONE (HEXONE)
Inhalation hazards - M.I.K. is a systemic irritation.
Other hazards - exposure will irritate skin, eyes and mucous membranes. Moderately toxic by ingestion,
narcotic in high concentrations.
ETHYL ALCOHOL
Inhalation hazards - Moderately toxic if inhaled, may cause cough or irritation of lungs.
Other hazards - Ethyl Alcohol is moderately toxic by ingestion. May cause sleep disorders, convulsions,
nausea or coma. Prolonged exposure may cause headache, iritation of the eyes.
METHYL ETHYL KETONE (M.E.K.)
Inhalation hazards - M.E.K. is a systemic irritation.
Other hazards - Moderately toxic by ingestion, skin contact, and imperitoneal routes. Will irritate eyes and
nasal passages.
6. FIRST AID
Inhalation: Move to fresh air. Obtain medical attention.
Eyes: Flush with water to remove particulate. Obtain medical attention.
Skin: Wash thoroughly with soap and water. If persistent irritation develops, obtain
medical attention.
Ingestion: Obtain medical attention.
7. SPECIAL PRECAUTIONS AND SPILL / LEAK PROCEDURES
Handling and Storage : Shipping and storage may result in accumulation of dust in
shipping containers. If this occurs, dispose of the container in an airtight
polyethylene bag (see disposal instructions below) or remove dust by vacuuming or
wet mopping. Vacuums used for this purpose should be equipped with HEPA
filters. Do not use compressed air to blow dust from storage containers.
Release or Spill : If a release of dust occurs during machining, abrading, or riveting,
remove dust by vacuuming or wet mopping. Vacuums used for this purpose
should be equipped with HEPA filters. Do not use compressed air to blow dust
from the workplace.
Waste Disposal : Disposal of solid waste is regulated by federal and state law. Waste
should be placed in airtight containers, and disposed of properly. Contact local
regulatory agency for guidance.
8. PERSONAL PROTECTION AND CONTROL
Respiratory Protection : Use NIOSH-approved respirator if exposure to dust, vapors, or
fumes in concentrations exceeding PEL's or TLV's is possible. (See 29 CFR
1910.134 for respiratory protection standards)
Ventilation : Any operations which may produce dust, including machining, grinding,
riveting, or abrading of this product, should be adequately exhausted to prevent
inhalation of dust.
Personal Protective Equipment : Suitable respiratory protection should be worn if dust
exposure is possible. All regulations and safe practices related to the use of
respiratory protection must be observed. Refer to OSHA standards and NIOSH
guidelines. If skin irritation occurs, gloves and other protective garments may be
worn.
The information and recommendations set forth herein are taken from sources believed to
be accurate as of the date of revision. Flexitallic, Inc. makes no warranty with respect to the
accuracy of the information or the suitability of the recommendations, and assumes no
liability, including direct, incidental or consequential damages for any reliance thereon.
This MSDS should not be used as a complete or accurate summary of the content of the
product. For specific information on brand names, manufacturer's, or quantities, please refer
to specific product specification documents where available.
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