** - Indicates chemicals subject to reporting requirements of SARA 313 and 40 CFR.
SECTION III - HAZARDS: (IDENTIFY)
INHALATION: Exposure to over 1000ppm may cause headache, drowsiness and lassitude, loss of appetite
and inability to concentrate. Irritation of throat.
INGESTION: Can cause depression of central nervous system, vomiting, nausea and diarrhea.
EYE CONTACT: Liquid or vapor may cause irritation.
SKIN CONTACT: May cause irritation and defatting of skin on prolonged contact.
HMIS RATING: 2/3/0
OTHER: Individual responses to methyl alcohol vary. Ingestion of less than 30ml (0.34 g/kg) has been fatal
to humans. In general, a few ounces may cause blindness and death. As little as 4ml may be toxic if ingested.
SECTION IV - FIRST AID MEASURES
FOR OVEREXPOSURE BY:
SWALLOWING: If victim is conscious and able to swallow, have victim drink water or milk to dilute.
Never give anything by mouth if victim is unconscious or having convulsions. CALL A PHYSICIAN OR
POISON CONTROL CENTER IMMEDIATELY. Induce vomiting only if advised by physician of poison
control center.
INHALATION: Immediately remove victim to fresh air. If victim has stopped breathing, give artificial
respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY.
CONTACT WITH EYES OR SKIN: Immediately flush affected area with plenty of cool water. Eyes
should be flushed for at least 15 minutes. Remove and wash contaminated clothing before re-use. GET
MEDICAL ATTENTION IMMEDIATELY!!
SECTION V - FIRE FIGHTING MEASURES
Use dry chemical, "alcohol" foam, or Carbon Dioxide. Water may be ineffective, but water should be used
to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors
and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from
exposures.
UNUSUAL FIRE & EXPLOSION HAZARDS:
Fire fighters should wear self-contained breathing apparatus in the positive pressure mode with a full
facepiece when there is a possibility of exposure to smoke, fumes or hazardous decomposition products.
FLAMMABLE LIMITS IN AIR, % BY VOL.: LOWER 3.3 UPPER: 19*
NFPA RATING: HEALTH ( ) FIRE ( 3) REACTIVITY ( )
(does not apply to exposure hazards other than during a fire)
* - For Pure Ethyl Alcohol
SECTION VI - ACCIDENTAL RELEASE MEASURES
Wear appropriate respiratory protection and protective clothing as described in Section VIII. Contain
Spilled Material. Transfer to secure containers. Where necessary, collect using absorbent media. In the
event of an uncontrolled release of this material, the user should determine if the release is reportable under
applicable laws and regulations.
SECTION VII - HANDLING & STORAGE
Protect container against physical damage. Detached or outside storage is preferred. Inside storage should
be in a NFPA approved flammable liquids storage room or cabinet. All ignition sources should be
eliminated. Smoking should be prohibited in storage areas. Electrical installations should be in accordance
with article 501 of the National Electrical Code. NFPA 30, Flammable and combustible liquids code should
be followed for all storage and handling . Frequent careful leakage inspection should be done. Automatic
sprinkler system should be provided. Isolate from oxidizers, chemicals capable of spontaneous heating
materials reacting with air or moisture to liberate heat ignition sources and explosives. Consult local fire
codes for additional storage information.
Keep closure up to prevent leakage and remove closure carefully because internal pressure may be present.
Avoid breathing vapor and use with adequate ventiliation.
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Handle in the presence of adequate ventilation.
Respiratory protection: Where exposure is likely to exceed acceptable criteria, use NIOSH/MSHA
approved respiratory protection equipment. Respirators should be selected based on the form and
concentration of contaminant in air.
Protective Clothing: Wear chemically resistant gloves and protective clothing which are impervious to this
product for the duration of anticipated exposure if there is potential for skin contact.
Eye Protection: If no eye contact is anticipated, wear safety glasses meeting specifications of ANSI
Standard Z87.1. If eye contact is anticipated, wear chemical safety goggles meeting specs of ANSI Standard
Z87.1.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES:
BOILING POINT: 173稦 SPECIFIC GRAVITY: 0.823 @ 60稦
MELTING POINT: -173 稦 SOLUBILITY IN WATER: N/D VAPOR PRESSURE: 44.6@68稦
EVAPORATION RATE (Butyl Acetate = 1): >1 VAPOR DENSITY: 1.59* APPEARANCE/COLOR: Pale
Yellow Liquid
pH: N/D FLASH POINT: 61稦 ASTM D-56 (Tag Closed Cup) ODOR: Characteristic pleasant odor.
FLAMMABLE LIMITS IN AIR, % BY VOL: LOWER: 3.3 UPPER: 19*
NFPA RATING: HEALTH ( ) FIRE ( 3 ) REACTIVITY ( )
(Does not apply to exposure hazards other than during a fire.)
Max Voc = 684 GPL
* - For Pure Ethyl Alcohol
SECTION X - STABILITY AND REACTIVITY
STABILITY: Generally Stable HAZARDOUS POLYMERIZATION: Not Likely
CONDITIONS/MATERIALS TO AVOID: Contact with acetyl chloride and a wide range of oxidizing
agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Burning may produce Carbon Monoxide and/or Carbon
Dioxide.
SECTION XI - TOXICOLOGICAL INFORMATION
No Data
SECTION XII - ECOLOGICAL INFORMATION
Avoid uncontrolled releases of this material. Where spills are possible, a comprehensive spill response plan
should be developed and implemented.
SECTION XIII - DISPOSAL INFORMATION
All recovered material should be packaged, labeled, transferred and disposed of or reclaimed in
conformance with applicable laws and regulations and in conformance with good engineering practices.
SECTION XIV TRANSPORTATION INFORMATION
DEPARTMENT OF TRANSPORTATION: DOMESTIC & EUROPEAN
DOT CLASSIFICATION: Flammable Liquid
DOT PROPER SHIPPING NAME: Paint
OTHER DOT INFORMATION: UN 1263
SECTION XV - REGULATORY INFORMATION:
Subject to requirements of SARA 313 and 40 CFR.
SECTION XVI - OTHER INFORMATION:
Revision issued to conform to DSD 67/548 EEC, DPD 88/379 EEC, DPD 91/155 EEC.
REVISION LOG:
Date: Reason; By whom:
5/21/01 Remove MBZ name & change int'l phone number. SAS