SDS Nbr: W71851
Revision: E01.01
Date of issue: 11/02/2009
BL.Rev.: 6
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Material Safety Data Sheet
(In accordance with 2001.58.EC - L212/14)
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W71851 - Dry Fuel
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY
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IDENTIFICATION OF THE SUBSTANCE OR PREPARATION
W71851 - Dry Fuel
USE OF THE SUBSTANCE/PREPARATION
Fuel Additive.
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COMPANY IDENTIFICATION
COMPANY Wynn's Belgium B.V.B.A.
ADDRESS Industriepark-West 46
9100 SINT-NIKLAAS
TEL +32 (0)3 766.60.20
FAX +32 (0)3 778 16 56
WEBSITE www.wynns.eu
E-MAIL msds@wynns.eu
EMERGENCY TELEPHONE NUMBER
EMERGENCY TELEPHONE NUMBER BIG: +32(0)14/58.45.45
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2. HAZARDS IDENTIFICATION
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F - highly Xn - N-
flammable harmful dangerous
for the
environment
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HAZARDS FOR HUMANS AND THE ENVIRONMENT
Highly flammable - Irritating to eyes and skin - Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment - Harmful: may cause lung damage if swallowed - Vapours may cause drowsiness and
dizziness
OTHER DANGERS
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3. COMPOSITION/INFORMATION ON INGREDIENTS
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INFORMATION ON INGREDIENTS
NAME CAS NO EINICS/ELINCS MIN/MAX SYMBOL R-PHRASES
(Z)-N-methyl-N-(1-oxo-9-octadecenyl)glycine 110-25-8 203-749-3 0,5 < C < 1 % Xi,N R38, R41, R50
2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol 95-38-5 202-414-9 0,5 < C < 1 % C,N R22, R34, R50/53
4-methyl-2-pentanol 108-11-2 203-551-7 5 <= C < 10 % Xi R10, R37
Kerosine (petroleum); Straight run kerosine 8008-20-6 232-366-4 25 < C < 50 % Xn,N R10, R38, R51/53, R65
ethanol; ethyl alcohol 64-17-5 200-578-6 25 < C < 50 % F R11
propan-2-ol; isopropyl alcohol; isopropanol 67-63-0 200-661-7 25 < C < 50 % F,Xi R11, R36, R67
4. FIRST AID MEASURES
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IN GENERAL
Check the vital functions
Unconscious: maintain adequate airway and respiration
Respiratory arrest: artificial respiration or oxygen
Cardiac arrest: perform resuscitation
Victim conscious with laboured breathing: half-seated
Victim in shock: on his back with legs slightly raised
Vomiting: prevent asphyxia/aspiration pneumonia
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Prevent cooling by covering the victim (no warming up)
Keep watching the victim
Give psychological aid
Keep the victim calm, avoid physical strain
Depending on the victim's condition: doctor/hospital
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INHALATION
Remove the victim into fresh air
Respiratory problems: consult a doctor/medical service
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SKIN
In case of burns
Rinse immediately with plenty of water for 15 minutes
Remove clothing before washing
Take victim to a doctor if irritation persists
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EYES
Rinse immediately with plenty of water for 15 minutes
Consult a doctor/medical service
Take victim to an ophtalmologist if irritation persists
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INGESTION
Do not induce vomiting
Immediately consult a doctor/medical service
Ingestion of large quantities: immediately to hospital
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5. FIRE-FIGHTING MEASURES
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EXTINGUISH. AGENTS-FIRE FIGHTING INSTR.
FIRE EXTINGUISHING MEDIA
Carbon dioxide
Dry chemical powder
AFFF/AR-foam
FIREFIGHTING INSTRUCTIONS:
If no hazard for/from the surroundings: controlled burning
If hazardous substances are nearby: consider extinguishment
Cool tanks/drums with water spray/remove them into safety
Extinguish/cool from behind cover/unmanned monitors
Solid water jet ineffective as extinguishing medium
FIRE HAZARD
DIRECT FIRE HAZARD
Highly flammable
Gas/vapour flammable with air within explosion limits
INDIRECT FIRE HAZARD
May build up electrostatic charges: risk of ignition
May be ignited by sparks
Gas/vapour spreads at floor level: ignition hazard
EXPLOSION HAZARD
Gas/vapour explosive with air within explosion limits
May be ignited by sparks
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS
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6. ACCIDENTAL RELEASE MEASURES
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PERSONAL PROTECTION
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Protective clothing
Gloves
Protective goggles
Face-shield
Large spills/in enclosed spaces: compressed air apparatus
Heat/fire exposure: compressed air/oxygen apparatus
GENERAL MEASURES
Keep upwind - Mark the danger area - Consider evacuation - Seal off low-lying
areas - Close doors and windows of adjacent premises - Stop engines and no
smoking - No naked flames or sparks - Spark- and explosionproof appliances
and lighting equipment - Prevent soil and water pollution - Prevent spreading in
sewers - Keep containers closed - Wash contaminated clothes
LEAK
Dam up the liquid spill
Contain released substance, pump over in suitable containers
Plug the leak, cut off the supply
Try to reduce evaporation
Dilute/disperse combustible gas/vapour with water curtain
Provide equipment/receptacles with earthing
Do not use compressed air for pumping over spills
DISPOSAL
Take up liquid spill into a non combustible material e.g.: dry
sand/earth/vermiculite
Scoop absorbed substance into closing containers
Clean contaminated surfaces with an excess of water
Wash clothing and equipment after handling
7. HANDLING AND STORAGE
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HANDLING THE PRODUCT
Comply with the legal requirements
Work under local exhaust/ventilation
Observe normal hygiene standards
Remove contaminated clothing immediately
Clean contaminated clothing
Keep container tightly closed
Use spark-/explosionproof appliances and lighting system
Take precautions against electrostatic charges
Keep away from naked flames/heat
Keep away from ignition sources/sparks
Handle uncleaned empty containers as full ones
Do not discharge the waste into the drain
Do not use compressed air for pumping over
STORAGE
STORAGE AREA Meet the legal requirements - Keep out of direct sunlight - container tightly
closed - Store in a dry area - Store in a cool area - Keep container in a
well-ventilated place
STORAGE TEMPERATURE <45癈
CONTAINERS
CONTAINERS : MATERIAL SELECTION SUITABLE MATERIAL:
carbon steel
polyethylene
polypropylene
stainless steel
CONTAINERS : REQUIREMENTS closing
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clean
correctly labelled
meet the legal requirements
Secure fragile packagings in solid containers
SPECIFIC APPLICATIONS
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
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VME/VLE
PRODUCT NAME VME (PPM) VME (MG/M? VLE (PPM) VLE (MG/M?
4-M?thyl-2-pentanol 25 ppm 100 mg/m? - -
ethanol 1000 1900 5000 9500
isopropylalcohol 400 980
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MAC
PRODUCT NAME MAC (MG/M? MAC (PPM) MAC SHORT TIME MAC SHORT TIME
(MG/M? (PPM)
4-Methyl-2-pentanol 100 mg/m?br>
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MAK
PRODUCT NAME MAK (MG/M? MAK (PPM) MAK SKIN RESORPTION MAK
CARCINOGENICITY
4-Methylpentan-2-ol 85 mg/m? 20 ppm
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TLV
PRODUCT NAME TLV-TWA (MG/M? TLV-TWA (PPM) TLV-STEL TLV-STEL (PPM)
(MG/M?
Methyl isobutyl carbinol 25 ppm 40 ppm
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PERSONAL PROTECTION
PERSONAL PROTECTION Protective clothing
Gloves
Protective goggles
Head/neck protection
Gas mask with filter type A
High gas/vapour concentration: compressed air/oxygen
BA
ENVIRONMENTAL PROTECTION EQUIPMENT
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MATERIALS FOR PROTECTIVE CLOTHING
GIVE GOOD RESISTANCE:
nitrile rubber
neoprene
GIVE POOR RESISTANCE:
PVA
9. PHYSICAL AND CHEMICAL PROPERTIES
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GENERAL INFORMATION
STATE OF AGGREGATION Liquid
ODOUR alcohol odour
COLOUR Blue
SOLUBILITY IN WATER >50%
OTHER PROPERTIES Clear, May generate electrostatic charges, The physical and chemical data in
this section are typical values for this product and are not intended as product
specifications.
VALUES OF PHYSICAL PROPERTIES
SPECIFIC GRAVITY 796.3 kg/m?@ 15癈
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REFRACTIVE INDEX @ 20癈 1.3939
HAZARDS FOR EXPLOSION AND FIRE
FLASHPOINT 12 癈
AUTO-IGNITION TEMPERATURE >300 癈
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EXPLOSION RISK
EXPLOSIVE LIMITS (VOL%) 1.8 - 12%
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10.STABILITY AND REACTIVITY
STABILITY
Stable under normal conditions
CHEMICAL REACTIONS
Upon combustion CO and CO2 are formed
Reacts violently with (strong) oxidizers: (increased) risk of fire
(strong) acids
PROHIBITIONS ON MIXED STORAGE
KEEP SUBSTANCE AWAY FROM:
heat sources
ignition sources
oxidizing agents
(strong) acids
HAZARDOUS DECOMPOSITION PRODUCTS
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11.TOXICOLOGICAL INFORMATION
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VALUES OF CHRONIC TOXICITY
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TOXICITY
Vapours may cause drowsiness and dizziness - Irritant to the eyes - Repeated
exposure may cause skin dryness or - cracking
TOXICITY HAZARD
DIRECT TOXICITY HAZARD - Literature reports harmful - Irritating -
Anesthetic in high concentrations
EFFECTS/SYMPTOMS
SYMPTOMS/INJURIES ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: - Headache - Dizziness -
Nausea - Dry skin - Red skin - Swelling of the skin - Skin rash/inflammation
SYMPTOMS/INJURIES AFTER SKIN CONTACT
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
Degreasing
Dry skin
SYMPTOMS/INJURIES AFTER INHALATION
drowsiness
Dizziness
Irritation of the respiratory tract
Nausea
Disturbances of consciousness
CNS depression
SYMPTOMS/INJURIES AFTER EYE CONTACT
Irritation of the eye tissue
SYMPTOMS/INJURIES AFTER INGESTION
Risk of aspiration pneumonia
Risk of lung oedema
12.ECOLOGICAL PROPERTIES
MOBILITY
ECOLOGY - GENERAL Contains environmentally dangerous component(s)
ECOLOGY - WATER Harmful to aquatic organisms
May cause long-term adverse effects in the aquatic
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environment
Water pollutant (surface water)
Ground water pollutant
Contains non readily biodegradable component(s)
PERSISTENCE AND DEGRADABILITY
WGK 2
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13.DISPOSAL CONSIDERATIONS
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DISPOSAL CONSIDERATIONS
Do not discharge into drains or the environment
Remove to an authorized waste treatment plant
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DISPOSAL CODE
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Package
Plastic 15.01.10*
Metal 15.01.11*
Product
Oil additives 12.01.12*
Fuel additives 14.06.03*
Aqueous solutions 20.01.29*
Airco-cleaner 20.01.19
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14.TRANSPORT INFORMATION
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UN
UN number 1993
UN 1993 FLAMMABLE LIQUID, N.O.S. (ethanol, kerosine), 3, II
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ROAD (ADR)
ADR CLASS 3 ADR CLASSIFICATION CODE F1
ADR SYMBOL
3 black -
Flammable liquids
ADR-PACKING GROUP II
DANGER CODE 33 STATE DURING TRANSPORT (ADR-RID)
Special Provision: 640D
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SEA (IMDG)
IMDG CLASS 3 EMS NUMBER F-E, S-E
MARINE POLLUTANT P IMDG PACKAGE GROUP II
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AIR (IATA/ICAO)
ICAO CLASS 3 ICAO PACKAGE GROUP II
ICAO INSTRUCTION PASSENGER ICAO INSTRUCTION CARGO 307
305/Y305
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15.REGULATORY INFORMATION
Classification and labelling according to the directives 67/548/EEC,
1999/45/EC, 98/8/EC and Regulation (EC) 648/2004.
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NAME OF THE COMPONENTS DETERMING THE DANGER
NAME CAS NO
Kerosine (petroleum); Straight run kerosine 8008-20-6
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SYMBOL
F - highly Xn - N-
flammable harmful dangerous
for the
environment
R-PHRASES R11 - Highly flammable
R36/38 - Irritating to eyes and skin
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness
S-PHRASES S(02) - (Keep out of reach of children)
S7 - Keep container tightly closed
S16 - Keep away from sources of ignition - No smoking
S26 - In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice
S61 - Avoid release to the environment. Refer to special instructions/safety
data sheets.
S(62) - (If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label)
16.OTHER INFORMATION
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R-PHRASES R10 - Flammable
R11 - Highly flammable
R22 - Harmful if swallowed
R34 - Causes burns
R36 - Irritating to eyes
R37 - Irritating to respiratory system
R38 - Irritating to skin
R41 - Risk of serious damage to eyes
R50 - Very toxic to aquatic organisms
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment
R65 - Harmful: may cause lung damage if swallowed
R67 - Vapours may cause drowsiness and dizziness
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REVISION ?
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Sources of key data used: Raw material suppliers' data sheets were used as key data sources in the preparation of
this safety data sheet.
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This safety data sheet has been made in accordance with the directives 91/155/EEG, 93/112/EEG, 2001/58/EG and
Reach regulation 1907/2006.
It completes the technical directions for use, but does not replace it.
The data mentioned on these documents are to our knowledge correct on the date of publication and are provided on
the assumption that the product will be used as indicated by the manufacturer/supplier. The indication of these safety
data, without being considered as complete, helps the user to fulfil his obligations with regard to dangerous
substances. The user is obliged to evaluate the product and use it in a safe way in compliance with the effective laws
and stipulations. The user has to make sure that all regulations as to human and environmental protection
during handling, storage and use of the products are observed.
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