Page 1/8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
?Application of the substance / the preparation Priming
?Manufacturer/Supplier: EFTEC Aftermarket GmbH Pyrmonterstr. 76 D-32676 L黦de
?Further information obtainable from:
Tel. +49(0)5281 98298 0, FAX +49(0)5281 98298 60
Hans.Pfau@eftec.de
?Information in case of emergency: +49(0)30 19240 Beratungsstelle f黵 Vergiftungserscheinungen, D-Berlin
2 Hazards identification
?Hazard description:
Xn Harmful
F+ Extremely flammable
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
Warning! Pressurized container.
R 12 Extremely flammable.
R 20 Harmful by inhalation.
R 36 Irritating to eyes.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈. Do not pierce or
burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking.
Buildup of explosive mixtures possible without sufficient ventilation.
Keep out of the reach of children
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data.
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 67-64-1 acetone Xi, F; R 11-36-66-67 10-25%
EINECS: 200-662-2
CAS: 74-98-6 propane F+; R 12 10-25%
EINECS: 200-827-9
CAS: 106-97-8 butane F+; R 12 10-25%
EINECS: 203-448-7
CAS: 108-10-1 4-methylpentan-2-one Xn, Xi, F; R 11-20-36/37-66 10-25%
EINECS: 203-550-1
(Contd. on page 2)
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Page 2/8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
(Contd. of page 1)
CAS: 141-78-6 ethyl acetate Xi, F; R 11-36-66-67 10-25%
EINECS: 205-500-4
CAS: 1330-20-7 xylene, mixture of isomers Xn, Xi; R 10-20/21-38 5-10%
EINECS: 215-535-7
CAS: 123-86-4 n-butyl acetate R 10-66-67 1-5%
EINECS: 204-658-1
cellulose nitrate E; R 3 1-5%
CAS: 7779-90-0 trizinc bis(orthophosphate) N; R 50/53 0.1-1%
EINECS: 231-944-3
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First-aid measures
?General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
?After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
5 Fire-fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents:
Water
Water with full jet
?Protective equipment: Mount respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling:
No special measures required.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
(Contd. on page 3)
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Page 3/8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
(Contd. of page 2)
?Information about fire - and explosion protection:
Do not spray onto a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈, i.e. electric
lights. Do not pierce or burn, even after use.
?Storage:
?Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurized containers.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep container tightly sealed.
Do not seal receptacle gas tight.
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
67-64-1 acetone
WEL Short-term value: 3620 mg/m? 1500 ppm
Long-term value: 1210 mg/m? 500 ppm
106-97-8 butane
WEL Short-term value: 1810 mg/m? 750 ppm
Long-term value: 1450 mg/m? 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
108-10-1 4-methylpentan-2-one
WEL Short-term value: 416 mg/m? 100 ppm
Long-term value: 208 mg/m? 50 ppm
Sk
141-78-6 ethyl acetate
WEL Short-term value: 400 ppm
Long-term value: 200 ppm
1330-20-7 xylene, mixture of isomers
WEL Short-term value: 441 mg/m? 100 ppm
Long-term value: 220 mg/m? 50 ppm
Sk; BMGV
123-86-4 n-butyl acetate
WEL Short-term value: 966 mg/m? 200 ppm
Long-term value: 724 mg/m? 150 ppm
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
(Contd. of page 3)
Avoid contact with the eyes and skin.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
?Protection of hands: Not required.
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Aerosol
Form:
Grey
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Not applicable, as aerosol.
< -20癈
?Flash point:
365癈
?Ignition temperature:
Product is not selfigniting.
?Self-igniting:
Product is not explosive. However, formation of explosive air/vapour mixtures
?Danger of explosion:
are possible.
?Explosion limits:
1.5 Vol %
Lower:
13.0 Vol %
Upper:
3600 hPa
?Vapour pressure at 20癈:
0.788 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Not miscible or difficult to mix.
water:
?Solvent content:
78.6 %
Organic solvents:
20.0 %
?Solids content:
GB
(Contd. on page 5)
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Page 5/8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
(Contd. of page 4)
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
7779-90-0 trizinc bis(orthophosphate)
Oral LD50 >5000 mg/kg (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
12 Ecological information
?Ecotoxical effects:
?Remark: Harmful to fish
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?European waste catalogue
15 00 00 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED
15 01 00 packaging (including separately collected municipal packaging waste)
15 01 10 packaging containing residues of or contaminated by dangerous substances
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND
PRINTING INKS
08 01 00 wastes from MFSU and removal of paint and varnish
08 01 11 waste paint and varnish containing organic solvents or other dangerous substances
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
(Contd. of page 5)
16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST
16 05 00 gases in pressure containers and discarded chemicals
16 05 04 gases in pressure containers (including halons) containing dangerous substances
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
2 5F Gases.
?ADR/RID class:
?Danger code (Kemler): -
1950
?UN-Number:
-
?Packaging group:
2.1
?Hazard label
?Description of goods: 1950 AEROSOLS
?Maritime transport IMDG:
2.1
?IMDG Class:
1950
?UN Number:
2.1
?Label
-
?Packaging group:
F-D,S-U
?EMS Number:
No
?Marine pollutant:
?Proper shipping name: AEROSOLS
?Air transport ICAO-TI and IATA-DGR:
2.1
?ICAO/IATA Class:
1950
?UN/ID Number:
2.1
?Label
-
?Packaging group:
?Proper shipping name: AEROSOLS, flammable
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
(Contd. on page 7)
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Page 7/8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
(Contd. of page 6)
?Code letter and hazard designation of product:
Xn Harmful
F+ Extremely flammable
?Risk phrases:
12 Extremely flammable.
20 Harmful by inhalation.
36 Irritating to eyes.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
25 Avoid contact with eyes.
51 Use only in well-ventilated areas.
61 Avoid release to the environment. Refer to special instructions/safety data sheets.
?Special labelling of certain preparations:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50癈. Do not pierce or
burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking.
Buildup of explosive mixtures possible without sufficient ventilation.
Keep out of the reach of children
?National regulations:
141-78-6 ethyl acetate
1330-20-7 xylene, mixture of isomers
?Technical instructions (air):
Class Share in %
NK 50-100
?Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
?EU-VOC: 80,00 %
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
12 Extremely flammable.
20 Harmful by inhalation.
20/21 Harmful by inhalation and in contact with skin.
3 Extreme risk of explosion by shock, friction, fire or other sources of ignition.
36 Irritating to eyes.
36/37 Irritating to eyes and respiratory system.
38 Irritating to skin.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 25.03.2009 Revision: 25.03.2009
Trade name: Dinitrol 8500 Lackgrundierer Grau AC Spray
(Contd. of page 7)
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
?Department issuing MSDS: Entwicklung
?Contact: H. Pfau
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