Page 1/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 30.05.2004 Reviewed on 30.05.2004
1 Identification of substance:
?Product details:
?Trade name: AUTODUR SATIN GLOSS SAINLESS STELL BLUE PART
?Article number: 392-217/1
?Application of the substance / the preparation paint
?Manufacturer/Supplier: TAMBOUR LTD.
?Further information obtainable from: Health & Safety
2 Composition/Data on components:
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 1330-20-7 xylene (mix) 10-25%
EINECS: 215-535-7 Xn; R 10-20/21-38
CAS: 123-86-4 n-butyl acetate 2.5-10%
EINECS: 204-658-1 R 10-66-67
CAS: 64742-95-6 Solvent naphtha (petroleum), light arom. 2.5-10%
EINECS: 265-199-0 Xn; R 10-65
CAS: 108-10-1 4-methylpentan-2-one 2.5-10%
EINECS: 203-550-1 Xn, F; R 11-20-36/37-66
CAS: 100-41-4 ethylbenzene 1.0-2.5%
EINECS: 202-849-4 Xn, F; R 11-20
?Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazard identification
?Hazard description:
Xn Harmful
?Information concerning to particular hazards to man and environment
Th e pro duct has t o be l abel led d ue to the calculat ion p rocedure of t he "General C lassifi cati on
guideline for preparations of the EU" in the latest valid version.
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with skin.
?Classification system
The classi ficatio n is accord ing to the latest edit ions o f the EU-li sts, a nd extended by company and
literature data.
GB
(Contd. on page 2)
DR
Page 2/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 30.05.2004 Reviewed on 30.05.2004
Trade name: AUTODUR SATIN GLOSS SAINLESS STELL BLUE PART
(Contd. of page 1)
4 First aid measures
?General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
?After inhalation
Sup ply fresh air. If requ ired , provide art ificial respira tion . K eep pa tien t w arm. C onsul t doct or if
symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact Generally the product does not irritate the skin.
?After eye contact Rinse opened eye for several minutes under running water.
?After swallowing If symptoms persist consult doctor.
5 Fire fighting measures
?Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents
Water.
Water with full jet.
?Protective equipment: Mount respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection gear
?Additional information about design of technical facilities: No further data; see item 7.
(Contd. on page 3)
GB
DR
Page 3/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 30.05.2004 Reviewed on 30.05.2004
Trade name: AUTODUR SATIN GLOSS SAINLESS STELL BLUE PART
(Contd. of page 2)
?Ingredients with limit values that require monitoring at the workplace:
1330-20-7 xylene (mix)
OES Short-term value: 662 mg/m? 150 ppm
Long-term value: 441 mg/m? 100 ppm
Sk
123-86-4 n-butyl acetate
OES Short-term value: 966 mg/m? 200 ppm
Long-term value: 724 mg/m? 150 ppm
108-10-1 4-methylpentan-2-one
OES Short-term value: 416 mg/m? 100 ppm
Long-term value: 208 mg/m? 50 ppm
IOELV, Sk, Bmgv
100-41-4 ethylbenzene
OES Short-term value: 552 mg/m? 125 ppm
Long-term value: 441 mg/m? 100 ppm
New, IOELV, Sk
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
?Respiratory protection:
In ca se of brief exposure or low p ollution use respiratory filter device. In case of in tensive or longer
exposure use self-contained respiratory protective device.
?Protection of hands:
Protective gloves.
The g lo ve ma teri al h as to b e imp ermeab le a nd resi st an t t o th e pro du ct / th e sub st an ce/ th e
preparation.
Du e to mi ssin g tests no recommend ati on to t he glo ve ma teri al ca n be gi ven fo r the p rod uct/ t he
preparation/ the chemical mixture.
Selection of the glove material on considerat ion of the penetrati on times, rat es of diffusi on and the
degradation
?Material of gloves
The selection of the suita ble gloves does not only depen d on the material, but also on further marks
of q uality a nd varies from manufacturer to ma nufacturer. As th e product is a preparati on of several
substa nces, the resistance of the glove material can not b e calculat ed in a dvance and has therefore
to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
?Eye protection:
Tightly sealed goggles.
GB
(Contd. on page 4)
DR
Page 4/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 30.05.2004 Reviewed on 30.05.2004
Trade name: AUTODUR SATIN GLOSS SAINLESS STELL BLUE PART
(Contd. of page 3)
9 Physical and chemical properties:
?General Information
Form: Fluid
Colour: According to product specification
Odour: Characteristic
?Change in condition
Melting point/Melting range: undetermined
Boiling point/Boiling range: 124癈
?Flash point: 21 - 55癈
?Ignition temperature: 370.0癈
?Self-igniting: Product is not selfigniting.
?Danger of explosion: Prod uct is no t expl osive. Ho wever, format io n of expl osive ai r/
vapour mixtures are possible.
?Explosion limits:
Lower: 1.1 Vol %
Upper: 7.0 Vol %
?Vapour pressure at 20癈: 6.7 hPa
?Density: Not determined
?Solubility in / Miscibility with
Water: Not miscible or difficult to mix
?Solvent content:
Organic solvents: 32.6 %
Water: 0.0 %
VOC Content 32.6 %
0.33 kg/l / 2.72 lb/gl
?Solids content: 67.4 %
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known
?Dangerous decomposition products: No dangerous decomposition products known
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
1330-20-7 xylene (mix)
Oral LD50 8700 mg/kg (rat)
Dermal LD50 2000 mg/kg (rbt)
Inhalative LC50/4 h 6350 mg/l (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
(Contd. on page 5)
GB
DR
Page 5/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 30.05.2004 Reviewed on 30.05.2004
Trade name: AUTODUR SATIN GLOSS SAINLESS STELL BLUE PART
(Contd. of page 4)
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The pro duct show s t he follow ing dangers accord ing to the calcu latio n method of the Gen eral EU
Classification Guidelines for Preparations as issued in the latest version.
Harmful
12 Ecological information:
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation
Mu st no t be d ispo sed t ogether with hou seho ld ga rba ge. Do not allo w pro duct to reach sewa ge
system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: 3 Flammable liquids.
?Danger code (Kemler): 30
?UN-Number: 1263
?Packaging group: III
?Hazard label 3
?Description of goods: 1263 PAINT (not viscous)
?Maritime transport IMDG:
?IMDG Class: 3
?UN Number: 1263
?Label 3
?Packaging group: III
?EMS Number: F-E,S-E
?Marine pollutant: No
(Contd. on page 6)
GB
DR
Page 6/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 30.05.2004 Reviewed on 30.05.2004
Trade name: AUTODUR SATIN GLOSS SAINLESS STELL BLUE PART
(Contd. of page 5)
?Proper shipping name: PAINT
?Air transport ICAO-TI and IATA-DGR:
15 Regulations
?Labelling according to EU guidelines:
Th e produ ct h as been classified and marked in accordan ce w ith EU Directi ves / Ord ina nce on
Hazardous Materials
?Code letter and hazard designation of product:
Xn Harmful
?Hazard-determining components of labelling:
xylene (mix)
?Risk phrases:
10 Flammable.
20/21 Harmful by inhalation and in contact with skin.
?Safety phrases:
9 Keep container in a well-ventilated place.
23 Do no t b rea th e g as/fu mes/ vap ou r/ spray (a pp rop ri at e w o rd in g t o b e speci fi ed b y th e
manufacturer).
25 Avoid contact with eyes.
36/37 Wear suitable protective clothing and gloves.
51 Use only in well-ventilated areas.
60 This material and its container must be disposed of as hazardous waste.
?National regulations
?Technical instructions (air):
Class Share in %
NK 32.6
?Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
16 Other information:
This information is based o n our present knowledg e. However, this shall not const itute a gu arantee
for any specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
20 Harmful by inhalation.
20/21 Harmful by inhalation and in contact with skin.
(Contd. on page 7)
GB
DR
Page 7/7
Material Safety Data Sheet
According to 91/155 EEC
Printing date 30.05.2004 Reviewed on 30.05.2004
Trade name: AUTODUR SATIN GLOSS SAINLESS STELL BLUE PART
(Contd. of page 6)
36/37 Irritating to eyes and respiratory system.
38 Irritating to skin.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
?Department issuing MSDS: Tambour Ltd.- Health & Safety Department.
?Contact:
Haim Yahav
Phone: +972(4)987-7483
Fax: +972(4)985-3540
e-mail: h.yahav@tambour.co.il
GB