SDS Nbr: W89195
Revision: E01.00
Date of issue: 20/05/2008
BL.Rev.: 4
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Material Safety Data Sheet
(In accordance with 2001.58.EC - L212/14)
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W89195 - Diesel System Purge
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY
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IDENTIFICATION OF THE SUBSTANCE OR PREPARATION
W89195 - Diesel System Purge
USE OF THE SUBSTANCE/PREPARATION
Diesel injection cleaner
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COMPANY IDENTIFICATION
COMPANY Wynn's Belgium B.V.B.A.
ADDRESS Industriepark-West 46
9100 SINT-NIKLAAS
TEL +32 (0)3 766.60.20
FAX +32 (0)3 778 16 56
WEBSITE www.wynns.eu
E-MAIL msds@wynns.eu
EMERGENCY TELEPHONE NUMBER
EMERGENCY TELEPHONE NUMBER BIG: +32(0)14/58.45.45
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2. HAZARDS IDENTIFICATION
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Xn - N-
harmful dangerous
for the
environment
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HAZARDS FOR HUMANS AND THE ENVIRONMENT
Flammable - Irritating to skin - Risk of explosion if heated under confinement - Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment - Harmful: may cause lung damage if swallowed
OTHER DANGERS
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3. COMPOSITION/INFORMATION ON INGREDIENTS
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INFORMATION ON INGREDIENTS
NAME CAS NO EINICS/ELINCS MIN/MAX SYMBOL R-PHRASES
2-ethylhexyl nitrate 27247-96-7 248-363-6 5 < C < 15 % Xn,N R20, R44, R51/53, R65
4-methyl-2-pentanol 108-11-2 203-551-7 10 < C < 20 % Xi R10, R37
Kerosine (petroleum); Straight run kerosine 8008-20-6 232-366-4 > 70 % Xn,N R10, R38, R51/53, R65
Solvent naphtha (petroleum), heavy arom.; Kerosine - unspecified 64742-94-5 265-198-5 2.5 < C < 5 % Xn,N R51/53, R65, R66, R67
naphthalene 91-20-3 202-049-5 < 0.5 % Xn,N R22, R40, R50/53
4. FIRST AID MEASURES
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IN GENERAL
Check the vital functions
Unconscious: maintain adequate airway and respiration
Respiratory arrest: artificial respiration or oxygen
Cardiac arrest: perform resuscitation
Victim conscious with laboured breathing: half-seated
Victim in shock: on his back with legs slightly raised
Vomiting: prevent asphyxia/aspiration pneumonia
Prevent cooling by covering the victim (no warming up)
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Keep watching the victim
Give psychological aid
Keep the victim calm, avoid physical strain
Depending on the victim's condition: doctor/hospital
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INHALATION
Remove the victim into fresh air
Respiratory problems: consult a doctor/medical service
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SKIN
wash immediately with plenty of water and soap
Take victim to a doctor if irritation persists
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EYES
Rinse immediately with plenty of water
Take victim to an ophtalmologist if irritation persists
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INGESTION
Rinse mouth with water
Do not induce vomiting
Consult a doctor/medical service if you feel unwell
Ingestion of large quantities: immediately to hospital
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5. FIRE-FIGHTING MEASURES
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EXTINGUISH. AGENTS-FIRE FIGHTING INSTR.
FIRE EXTINGUISHING MEDIA
Water spray
AFFF foam
BC powder
Carbon dioxide
FIREFIGHTING INSTRUCTIONS:
Cool tanks/drums with water spray/remove them into safety
Take account of environmentally hazardous firefighting water
Use water moderately and if possible collect or contain it
Do not move the load if exposed to heat
Solid water jet ineffective as extinguishing medium
FIRE HAZARD
DIRECT FIRE HAZARD
Flammable
Gas/vapour flammable with air within explosion limits
INDIRECT FIRE HAZARD
May build up electrostatic charges: risk of ignition
May be ignited by sparks
EXPLOSION HAZARD
DIRECT EXPLOSION HAZARD
Gas/vapour explosive with air within explosion limits
INDIRECT EXPLOSION HAZARD
May be ignited by sparks
Risk of explosion if heated under confinement
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS
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6. ACCIDENTAL RELEASE MEASURES
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PERSONAL PROTECTION
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Gloves
Face-shield
Protective goggles
Protective clothing
Large spills/in enclosed spaces: compressed air apparatus
Heat/fire exposure: compressed air/oxygen apparatus
GENERAL MEASURES
Mark the danger area - Stop engines and no smoking - No naked flames or
sparks - Spark- and explosionproof appliances and lighting equipment -
Prevent soil and water pollution - Prevent spreading in sewers - Keep upwind -
Seal off low-lying areas - Wash contaminated clothes
LEAK
Contain released substance, pump over in suitable containers
Plug the leak, cut off the supply
Dam up the liquid spill
Provide equipment/receptacles with earthing
Do not use compressed air for pumping over spills
DISPOSAL
Do not use compressed air for pumping over spills
Take up liquid spill into inert absorbent material, e.g.: sand
Scoop absorbed substance into closing containers
Carefully collect the spill/leftovers
Clean contaminated surfaces with an excess of water and soap solution
Wash clothing and equipment after handling
7. HANDLING AND STORAGE
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HANDLING THE PRODUCT
Comply with the legal requirements
Carry operations in the open/under local
exhaust/ventilation or with respiratory protection
Observe normal hygiene standards
Remove contaminated clothing immediately
Clean contaminated clothing
Keep container tightly closed
Use spark-/explosionproof appliances and lighting system
Keep away from naked flames/heat
Keep away from ignition sources/sparks
Take precautions against electrostatic charges
Do not discharge the waste into the drain
Do not use compressed air for pumping over
STORAGE
STORAGE AREA Keep out of direct sunlight - Fireproof storeroom - Provide for a tub to collect
spills - Meet the legal requirements - Keep container in a well-ventilated place
- Ventilation at floor level - Store in a cool area - Store in a dry area
STORAGE TEMPERATURE < 45癈
CONTAINERS
CONTAINERS : REQUIREMENTS closing
correctly labelled
meet the legal requirements
Secure fragile packagings in solid containers
SPECIFIC APPLICATIONS
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
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VME/VLE
PRODUCT NAME VME (PPM) VME (MG/M? VLE (PPM) VLE (MG/M?
4-M?thyl-2-pentanol 25 ppm 100 mg/m? - -
Naphtal?ne 10 ppm 50 mg/m? - -
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MAC
PRODUCT NAME MAC (MG/M? MAC (PPM) MAC SHORT TIME (MG/M? MAC SHORT
TIME (PPM)
4-Methyl-2-pentanol 100 mg/m?br>
Naftaleen 50 mg/m? 80 mg/m?br>
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MAK
PRODUCT NAME MAK (MG/M? MAK (PPM) MAK SKIN RESORPTION MAK
CARCINOGENICITY
4-Methylpentan-2-ol 85 mg/m? 20 ppm
Naphtalin - - H 2
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OEL/TRK
PRODUCT NAME TRK (MG/M? TRK (PPM) TRK SKIN RESORPTION TRK
CARCINOGENICITY
Naphtalin 50 mg/m? 10 ppm
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TLV
PRODUCT NAME TLV-TWA (MG/M? TLV-TWA (PPM) TLV-STEL TLV-STEL (PPM)
(MG/M?
Methyl isobutyl carbinol 25 ppm 40 ppm
Naphthalene 10 ppm 15 ppm
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PERSONAL PROTECTION
PERSONAL PROTECTION Gloves
safety glasses or face shield
Protective clothing
High gas/vapour concentration: gas mask
ENVIRONMENTAL PROTECTION EQUIPMENT
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MATERIALS FOR PROTECTIVE CLOTHING
GIVE GOOD RESISTANCE:
neoprene
nitrile rubber
GIVE POOR RESISTANCE:
natural rubber
PVC
9. PHYSICAL AND CHEMICAL PROPERTIES
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GENERAL INFORMATION
STATE OF AGGREGATION Liquid
ODOUR kerosine
COLOUR Yellow
OTHER PROPERTIES Clear, Insoluble in water
VALUES OF PHYSICAL PROPERTIES
SPECIFIC GRAVITY 821.8 kg/m?@ 15癈
REFRACTIVE INDEX @ 20癈 1.4436
HAZARDS FOR EXPLOSION AND FIRE
FLASHPOINT 38.5癈
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EXPLOSION RISK
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10.STABILITY AND REACTIVITY
STABILITY
Stable under normal conditions
CHEMICAL REACTIONS
Upon combustion CO and CO2 are formed
On heating: decomposes exothermically: pressure rise and possible bursting
of container
Reacts with (strong) oxidizers
(strong) acids
PROHIBITIONS ON MIXED STORAGE
KEEP SUBSTANCE AWAY FROM:
heat sources
ignition sources
HAZARDOUS DECOMPOSITION PRODUCTS
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11.TOXICOLOGICAL INFORMATION
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VALUES OF CHRONIC TOXICITY
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TOXICITY
ACUTE TOXICITY - Harmful: may cause lung damage if swallowed - Irritant to
the skin - Moderately irritant for eyes - Slightly irritant to respiratory organs -
CHRONIC TOXICITY - Not listed in carcinogenicity class (IARC,EC,TLV,MAK) -
Not listed in mutagenicity class (EC,MAK) - Not classified as toxic to
reproduction (EC)
TOXICITY HAZARD
DIRECT TOXICITY HAZARD - Literature reports harmful - Irritating
EFFECTS/SYMPTOMS
SYMPTOMS/INJURIES AFTER SKIN CONTACT
Red skin
Dry skin
Tingling/irritation of the skin
SYMPTOMS/INJURIES AFTER EYE CONTACT
Redness of the eye tissue
Irritation of the eye tissue
SYMPTOMS/INJURIES AFTER INGESTION
Headache
Abdominal pain
Diarrhoea
Risk of aspiration pneumonia
12.ECOLOGICAL PROPERTIES
MOBILITY
ECOLOGY - GENERAL According to literature: environmental hazard
ECOLOGY - WATER Contains ground water contaminating component(s)
Water pollutant (surface water)
Literature reports: toxic to aquatic organisms
Literature reports may cause long-term adverse effects in
the aquatic environment
PERSISTENCE AND DEGRADABILITY
WGK 2
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13.DISPOSAL CONSIDERATIONS
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DISPOSAL CONSIDERATIONS
Hazardous waste (91/689/EEC)
Remove to an authorized plant for the destruction,
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neutralization and elimination of hazardous waste
Use appropriate containment to avoid environmental
contamination
PACKAGING/CONTAINER
Waste material code packaging (91/689/EEC, Council Decision
2001/118/EC, O.J. L47 of 16/2/2001):
15 01 10*
packaging containing residues of or contaminated by
dangerous substances
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DISPOSAL CODE
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Package
Plastic 15.01.10*
Metal 15.01.11*
Product
Oil additives 12.01.12*
Fuel additives 14.06.03*
Aqueous solutions 20.01.29*
Airco-cleaner 20.01.19
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14.TRANSPORT INFORMATION
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UN
UN number 1993
UN 1993 FLAMMABLE LIQUID, N.O.S. (Kerosine), 3, III
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ROAD (ADR)
ADR CLASS 3 ADR CLASSIFICATION CODE F1
ADR SYMBOL
3 black -
Flammable liquids
ADR-PACKING GROUP III
DANGER CODE 30
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RAIL (RID)
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SEA (IMDG)
IMDG CLASS 3 EMS NUMBER F-E, S-E
MARINE POLLUTANT P IMDG PACKAGE GROUP III
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AIR (IATA/ICAO)
ICAO CLASS 3 ICAO PACKAGE GROUP III
ICAO INSTRUCTION PASSENGER ICAO INSTRUCTION CARGO 310
309/Y309
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15.REGULATORY INFORMATION
Classification and labelling according to the directives 67/548/EEC,
1999/45/EC, 98/8/EC and Regulation (EC) 648/2004.
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NAME OF THE COMPONENTS DETERMING THE DANGER
NAME CAS NO
Kerosine (petroleum); Straight run kerosine 8008-20-6
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SYMBOL
Xn - N-
harmful dangerous
for the
environment
R-PHRASES R10 - Flammable
R38 - Irritating to skin
R44 - Risk of explosion if heated under confinement
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment
R65 - Harmful: may cause lung damage if swallowed
S-PHRASES S(02) - (Keep out of reach of children)
S37 - Wear suitable gloves
S61 - Avoid release to the environment. Refer to special instructions/safety
data sheets.
S(62) - (If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label)
SURFACTANTS
SURFACTANTS: <5% aromatic hydrocarbons
non-ionic surfactants
SURFACTANTS: >30% aliphatic hydrocarbons
16.OTHER INFORMATION
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R-PHRASES R10 - Flammable
R20 - Harmful by inhalation
R22 - Harmful if swallowed
R37 - Irritating to respiratory system
R38 - Irritating to skin
R40 - Limited evidence of a carcinogenic effect
R44 - Risk of explosion if heated under confinement
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment
R65 - Harmful: may cause lung damage if swallowed
R66 - Repeated exposure may cause skin dryness or cracking
R67 - Vapours may cause drowsiness and dizziness
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Sources of key data used: Raw material suppliers' data sheets were used as key data sources in the preparation of
this safety data sheet.
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This safety data sheet has been made in accordance with the directives 91/155/EEG, 93/112/EEG, 2001/58/EG and
Reach regulation 1907/2006.
It completes the technical directions for use, but does not replace it.
The data mentioned on these documents are to our knowledge correct on the date of publication and are provided on
the assumption that the product will be used as indicated by the manufacturer/supplier. The indication of these safety
data, without being considered as complete, helps the user to fulfil his obligations with regard to dangerous
substances. The user is obliged to evaluate the product and use it in a safe way in compliance with the effective laws
and stipulations. The user has to make sure that all regulations as to human and environmental protection
during handling, storage and use of the products are observed.
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