MATERIAL SAFETY DATA SHEET
ICI Paints North America
PRE-PRIME 167
prepared 08/08/06
HAZARDS IDENTIFICATION (ANSI Section 3) ACCIDENTAL RELEASE MEASURES (ANSI Section 6)
Primary route(s) of exposure : Inhalation, skin contact, eye contact, ingestion. Steps to be taken in case material is released or spilled : Comply with all applicable health and
environmental regulations. Eliminate all sources of ignition. Ventilate area. Use non-sparking tools.
Effects of overexposure :
Evacuate all unnecessary personnel. Wet down spilled material with water. Complete personal
Inhalation : Irritation of respiratory tract. Prolonged inhalation may lead to mucous membrane
protective equipment must be used during cleanup. Large spills - shut off leak if safe to do so. Dike
irritation, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea,
and contain spill. Pump to storage or salvage vessels. Use absorbent to pick up excess residue.
vomiting, diarrhea, abdominal pain, coughing, central nervous system depression, anesthetic
Keep salvageable material and rinse water out of sewers and water courses. Small spills - use
effect or narcosis, difficulty of breathing, allergic response, abnormal blood pressure,
15885 Sprague Road Strongsville, Ohio 44136
absorbent to pick up residue and dispose of properly.
respiratory tract burns, severe lung irritation or burns, liver damage, kidney damage,
convulsions, loss of consciousness. Possible sensitization to respiratory tract.
HANDLING AND STORAGE (ANSI Section 7)
Skin contact : Irritation of skin. Prolonged or repeated contact can cause dermatitis, defatting, allergic
response, severe skin irritation or burns. Possible sensitization to skin. Skin contact may result Handling and storage : Store below 100f (38c). Store in original containers. Isolated storage is
in dermal absorption of component(s) of this product which may cause dizziness and/or desirable. Keep away from heat, sparks and open flame.
lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, central nervous system Other precautions : Use only with adequate ventilation. Do not take internally. Keep out of reach of
depression, convulsions, loss of consciousness. children. Avoid contact with skin and eyes, and breathing of vapors. Wash hands thoroughly after
Eye contact : Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis, blurred vision, handling, especially before eating or smoking. Keep containers tightly closed and upright when not
tearing of eyes, redness of eyes, severe eye irritation, severe eye irritation or burns, corneal in use. Empty containers may contain hazardous residues. Ground equipment when transferring to
injury, blindness. prevent accumulation of static charge.
Ingestion : Ingestion may cause lung inflammation and damage due to aspiration of material into
lungs, mouth and throat irritation, dizziness and/or lightheadedness, headache, uncoordination, EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8)
nausea, vomiting, diarrhea, gastro-intestinal disturbances, severe abdominal pain, abdominal
Respiratory protection : Control environmental concentrations below applicable exposure standards
pain, central nervous system depression, intoxication, difficulty of breathing, burns of the
when using this material. When respiratory protection is determined to be necessary, use a
mouth, throat, stomach, convulsions, loss of consciousness.
NIOSH/MSHA (Canadian z94.4) Approved elastomeric sealing- surface facepiece respirator
Medical conditions aggravated by exposure : Eye, skin, respiratory disorders, lung disorders,
outfitted with organic vapor cartridges and paint spray (dust/mist) prefilters. Determine the proper
asthma-like conditions, respiratory disorders.
level of protection by conducting appropriate air monitoring. Consult 29CFR1910.134 For selection
of respirators (Canadian z94.4).
FIRST-AID MEASURES (ANSI Section 4) Ventilation : Provide dilution ventilation or local exhaust to prevent build-up of vapors. Use explosion-
EMERGENCY TELEPHONE NO. (800) 545-2643
Inhalation : Remove to fresh air. Restore and support continued breathing. Get emergency medical proof equipment.
attention. Have trained person give oxygen if necessary. Get medical help for any breathing Personal protective equipment : Eye wash, safety shower, safety glasses or goggles. Impervious
difficulty. gloves, impervious clothing, face shield, apron.
Skin contact : Wash thoroughly with soap and water. If any product remains, gently rub petroleum
jelly, vegetable or mineral/baby oil onto skin. Repeated applications may be needed. Remove STABILITY AND REACTIVITY (ANSI Section 10)
contaminated clothing. Wash contaminated clothing before re-use. Dispose of contaminated
Under normal conditions : Stable see section 5 fire fighting measures
leather items, such as shoes and belts.
Materials to avoid : Oxidizers, acids, reducing agents, bases, aldehydes, isocyanates, amines,
Eye contact : Flush immediately with large amounts of water, especially under lids for at least 15
aluminum, epoxides, nitric acid, combustible materials, lewis acids, curing agents, mineral acids.
minutes. If irritation or other effects persist, obtain medical treatment.
Nitrates.
Ingestion : If swallowed, obtain medical treatment immediately.
Conditions to avoid : Elevated temperatures, moisture, contact with oxidizing agent, sparks, open
flame, ignition sources.
FIRE-FIGHTING MEASURES (ANSI Section 5) Hazardous polymerization : May occur will not occur polymerization can occur in presence of
Fire extinguishing media : Dry chemical or foam water fog. Dry chemical may be ineffective. Carbon cationic initiators, such as selected lewis acids or strong proton acids. May polymerize in presence of
dioxide. Closed containers may explode when exposed to extreme heat or fire. Vapors are heavier aliphatic amines.
than air and may travel long distances to a source of ignition and flash back. Vapors can form
explosive mixtures in air at elevated temperatures. Closed containers may burst if exposed to extreme
TOXICOLOGICAL INFORMATION (ANSI Section 11)
heat or fire. May decompose under fire conditions emitting irritant and/or toxic gases. In closed
Supplemental health information : Contains a chemical that is moderately toxic by ingestion.
tanks, water or foam may cause frothing or eruption.
Contains a chemical that is toxic by ingestion. Contains a chemical that is toxic by inhalation.
Fire fighting procedures : Water may be used to cool and protect exposed containers. Firefighters
This material is corrosive; avoid contact. Contains a chemical that may be absorbed through
should use full protective clothing, eye protection, and self-contained breathing apparatus.
skin. Notice - reports have associated repeated and prolonged occupational overexposure to
Hazardous decomposition or combustion products : Carbon monoxide, carbon dioxide, oxides of
solvents with permanent brain and nervous system damage. Intentional misuse by deliberately
nitrogen, acrid fumes, aldehydes, nitrogen containing organic compounds, acids, methyl isobutyl
concentrating and inhaling the contents may be harmful or fatal. Other effects of overexposure
ketone (mibk), unidentified organic compounds. Phenolics
may include toxicity to liver, kidney, blood.
167K
The information contained herein is based on data available at the time of preparation of this data sheet which ICI Paints believes to be reliable. However, no warranty is expressed or implied regarding the accuracy of this
data. ICI Paints shall not be responsible for the use of this information, or of any product, method or apparatus mentioned and you must make your own determination of its suitability and completeness for your own use,
for the protection of the environment, and the health and safety of your employees and the users of this material.
Complies with OSHA hazard communication standard 29CFR1910.1200.
DISPOSAL CONSIDERATIONS (ANSI Section 13)
Carcinogenicity : No carcinogenic effects are anticipated
Reproductive effects : No reproductive effects are anticipated Waste disposal : Dispose in accordance with all applicable regulations. Avoid discharge to natural waters.
Mutagenicity : No mutagenic effects are anticipated
Teratogenicity : No teratogenic effects are anticipated REGULATORY INFORMATION (ANSI Section 15)
As of the date of this MSDS, all of the components in this product are listed (or are otherwise exempt from
ECOLOGICAL INFORMATION (ANSI Section 12) listing) on the TSCA inventory. This product has been classified in accordance with the hazard criteria of the
No ecological testing has been done by ICI paints on this product as a whole. CPR (controlled products regulations) and the MSDS contains all the information required by the CPR.
Physical Data (ANSI Sections 1, 9, and 14)
Product VOC % Volatile Flash Boiling
Description Wt. / Gal. HMIS DOT, proper shipping name
Code gr. / ltr. by Volume Point Range
167B0929 pre-prime 167 penetrating sealer - clear bas e 8.54 91.08 8.71 above 200f 401-401 311 paint ** protect from freezing **
167C0920 pre-prime 167 penetraing sealer - converter 7.25 121.03 14.10 135 f 212-212 321 corrosive liquid, flammable, n. o. s., 8(3), UN2920,
PGII, (ethylenediamine, methyl isobutyl ketone,)
Ingredients Product Codes with % by Weight (ANSI Section 2)
Chemical Name Common Name CAS. No. 167B0929 167C0920
benzenemethanol benzyl alcohol 100-51-6 5-10 1-5
1,2-ethanediamine ethylenediamine 107-15-3 1-5
2-pentanone, 4-methyl- methyl isobutyl ketone 108-10-1 5-10
oxirane,2,2'-((1-methylethylidene)bis(4,1- phenyleneoxymethylene))bis, homopolymer epoxy resin 25085-99-8 40-50
1,2-ethanediamine, n,n'-bis(1,3- dimethylbutylidene)- ethylenediamine/methyl isobutyl ketone ketimine 25707-70-4 80-90
neodecanoic acid, oxiranylmethyl ester glycidyl neodecanoate 26761-45-5 30-40
oxirane, mono((c12-c14-alkoxy)methyl) derivatives c12-c14 alkyl glycidyl ether 68609-97-2 10-20
phenol, 2,4,6-tris((dimethylamino)methyl)- 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 5-10
Chemical Hazard Data (ANSI Sections 2, 8, 11, and 15)
ACGIH-TLV OSHA-PEL S.R.
S2 S3 CC
Std.
Common Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I O
benzyl alcohol 100-51-6 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
ethylenediamine 107-15-3 10 ppm not est. not est. y 10 ppm not est. not est. not est. not est. y n y n n n n n
methyl isobutyl ketone 108-10-1 50 ppm 75 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n n n
epoxy resin 25085-99-8 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
ethylenediamine/methyl isobutyl ketone ketimine 25707-70-4 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
glycidyl neodecanoate 26761-45-5 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
c12-c14 alkyl glycidyl ether 68609-97-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n
Footnotes: H=Hazardous Air Pollutant, M=Marine Pollutant
C=Ceiling - Concentration that S=Skin - Additional exposure, n/a=not applicable ppm=parts per million S2=Sara Section 302 EHS P=Pollutant, S=Severe Pollutant
should not be exceeded, over and above airborn exposure, not est=not established mg/m3=milligrams per cubic meter S3=Sara Section 313 Chemical Carcinogenicity Listed By:
even instantaneously. may result from skin absorption. CC=CERCLA Chemical Sup Conf=Supplier Confidential S.R.Std.=Supplier Recommended Standard N=NTP, I=IARC, O=OSHA, y=yes, n=no
Form: 167K, Page 2 of 2, prepared 08/08/06
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