Guardian Energy Technologies FOR EMERGENCY, CALL CHEMTREC: 1-800-424-9300
2033 Milwaukee Ave #136 OUTSIDE U.S.A., CALL COLLECT: 001-(703) 527-3887
Riverwoods IL 60015 USA
1-800-516-0949 DATE OF PREPARATION: January 30, 2009
Mark Munns
PREPARED BY:
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT IDENTIFICATION
FOAM IT GREEN Kits 202 and 602 SLOW RISE
Name of product:
Component A
SECTION 2 - CHEMICAL COMPOSITION
CHEMICAL CAS # CONCENTRATION
Polymethylene polyphenyl isocyanate 9016-87-9 80% to 100%
Containing 4,4 Methylene bisphenylisocyanate (MDI) 101-68-8
(Approximately 40% - 50% MDI)
Tetrafluoroethane (134a) 811-97-2 <15%
SECTION 3 - HAZARDS IDENTIFICATION
CAUTION!! CONTENTS UNDER PRESSURE. Reacts slowly with water, releasing carbon dioxide,
which can cause pressure buildup and rupture of closed containers. Elevated temperatures
accelerate this process.
POTENTIAL HEALTH EFFECTS
Eyes: May cause moderate eye irritation. May cause very temporary corneal injury.
Skin: Prolonged or repeated exposure may cause slight irritation. May cause allergic skin reaction in
susceptible individuals. Animal studies have shown that skin contact with isocyanates may play a
role in respiratory sensitization. May stain skin. A single prolonged exposure is not likely to result in
the material being absorbed in harmful amounts.
Ingestion: No hazards anticipated from swallowing small amounts.
Inhalation: At room temperature, there are minimal vapors. Excessive exposure may cause irritation to upper
respiratory tract and lungs. May cause respiratory sensitization to susceptible individuals. Symptoms
may include coughing, difficult breathing and tightness in the chest. Effects may be delayed.
SECTION 4 - FIRST AID PROCEDURES In all cases, seek additional medical attention.
EYE CONTACT Flush with clean, low pressure water for 15 minutes while holding eyelids open.
SKIN CONTACT Remove contaminated clothing. Immediately wash skin with soap and warm water.
INHALATION Remove from contaminated area to fresh air. If not breathing, administer artificial respiration or oxygen.
INGESTION In case of excessive ingestion, give large amounts of liquids. DO NOT INDUCE
VOMITING
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point >400癋/>204癈 (estimated)
Extinguishing Media Carbon dioxide, dry chemical, foam, water fog or fine spray.
Special Protective Equipment Positive pressure self contained breathing apparatus (SCBA) and
protective fire fighting clothing.
Hazardous Decomposition Products During combustion, Carbon Monoxide and Carbon
Dioxide, Nitrogen Oxides, Ammonia, Hydrochloric Acid, Hydrofluoric
Acid, Chlorine, Fluorine, Phosgene, Phosphorous oxides and trace
amounts of Hydrogen Cyanide are given off.
SECTION 6 - HANDLING AN ACCIDENTAL RELEASE OR SPILL
Provide adequate ventilation.
Wear suitable personal protective clothing and equipment.
Contain spill and collect using suitable absorbent material, such as sawdust or
vermiculite. Shovel into waste container adding 10%-20% decontaminate solution (90%
water, 7% ammonia and 3% liquid detergent). Leave uncovered for 24 hours
prior to disposal. Dispose of as ordinary industrial waste in compliance with
pertinent regulations.
FOAM IT GREEN 202 AND 602 SLOW RISE COMPONENT A PAGE TWO
SECTION 7 ?HANDLING AND STORAGE
CAUTION!! Contents under pressure.
Avoid open flames and contact with water.
Storage temperature: <120?F (<49?C) ; 75?F (24?C) is ideal
Do not puncture or incinerate.
SECTION 8 - PERSONAL PROTECTION
EYE PROTECTION Wear safety goggles.
SKIN PROTECTION Wear protective clothing and chemical resistant gloves.
RESPIRATORY PROTECTION Use only in well ventilated areas. When atmospheric levels may exceed exposure guideline, use a approved
air-purifying respirator equipped with an organic vapor sorbent and a particle filter. In situations of insufficient
ventilation, or in situations where the potential exists for exceeding the TLV, wear self-contained breathing
apparatus.
EXPOSURE GUIDELINES: Methylene bisphenyl isocyanate (MDI): ACGIH TLV is 0.005 ppm TWA and OSHA PEL is 0.02 ppm ceiling.
Tetrafluoroethane (HFC-134a): TLV is 1000 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Vapor Pressure(70癋/21癈) <25 psi @ 25?C
Vapor Density Heavier Than Air
Boiling Point Not Available
Specific Gravity 1.24
VOC Content (lb./gal) 0
Appearance and Color Dark brown, frothy liquid with mild musty odor
SECTION 10 - REACTIVITY AND STABILITY
STABILITY Stable under recommended storage conditions
REACTIVITY Reacts with water. Avoid alkalis, acids, alcohol, ammonia, bases, moist air and strong oxidizers. Reaction
may be violent at elevated temperatures. Avoid open flames and storage temperatures above 120?F
(49癈). DO NOT INCINERATE CYLINDERS.
SECTION 11 ?TOXICOLOGICAL INFORMATION
Concentration of components (Sec. 2) must be considered to determine effects of this mixture.
MDI: LD50 2000mg/kg (rats,); ingestion
SECTION 12 ?ECOLOGICAL INFORMATION
Material is practically non-toxic to aquatic organisms on an acute basis (LC50 >100 mg/L)
The LC50 in earthworm Eisenia foetida is >1000 mg/kg
SECTION 13 - DISPOSAL INFORMATION
Prior to disposal, cylinders must be properly vented. Do not puncture or incinerate
cylinders. Once pressure has been relieved, empty cylinders can be disposed of as ordinary industrial waste in
compliance with pertinent regulations. Dispose of leftover chemical by following instructions under Section 6
"Handling an accidental release or spill".
SECTION 14 ?TRANSPORTATION INFORMATION
UN 1956, Compressed Gas n.o.s. (Fluoronated Hydrocarbon, Nitrogen), Class 2.2, PKG GRP N/A
SECTION 15 - REGULATORY INFORMATION
SARA 313: Contains: Methylene Bisphenylisocyanate (MDI) CAS Number 101-68-8
Polymeric Diphenylmethane Diisocyanate CAS Number 9016-87-9
SARA 311/312 Categories: An immediate health hazard
A delayed health hazard
All ingredients are on the TSC Inventory
This product is defined as a "Hazardous Chemical" under OSHA Hazard Communication Standard, 29 CFR 1910.1200
SECTION 16 ?OTHER INFORMATION
Guardian Energy Technologies FOR EMERGENCY, CALL CHEMTREC: 1-800-424-9300
2033 Milwaukee Ave #136 OUTSIDE U.S.A., CALL COLLECT: 001-(703) 527-3887
Riverwoods IL 60015 USA
1-800-516-0949 DATE OF PREPARATION: January 30, 2009
Mark Munns
PREPARED BY:
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT IDENTIFICATION
FOAM IT GREEN Kits 202 and 602 SLOW RISE
Name of product:
Component B
SECTION 2 - CHEMICAL COMPOSITION
CHEMICAL CAS # CONCENTRATION
Amine catalyst Proprietary 0% - 2%
Oxyehtylated aliphatic amine 62476-52-2 0% - 15%
Aromatic phosphates triaryl phosphates, isopropylated Proprietary 0% - 2%
Triphenyl phosphate 115866 0% - 1%
Tetrafluoroethane (134a) 811-97-2 10% - 20%
2
Different raw materials sources - proprietary mixture
SECTION 3 ?HAZARDS IDENTIFICATION
CAUTION!! CONTENTS UNDER PRESSURE
POTENTIAL HEALTH EFFECTS
Eyes: May cause slight eye irritation
Skin: Not likely to cause significant skin irritation.
Ingestion: Swallowing small amounts not likely to cause injury. Larger amounts may cause injury
Inhalation: Single exposure is not likely to be hazardous. High concentrations may cause respiratory irritation
SECTION 4 - FIRST AID PROCEDURES In all cases, seek additional medical attention.
EYE CONTACT Flush with clean, low pressure water for 15 minutes while holding eyelids open.
SKIN CONTACT Remove contaminated clothing. Wash skin with soap and warm water.
INHALATION Remove from contaminated area to fresh air.
INGESTION In case of excessive ingestion, give large amounts of liquids. DO NOT INDUCE
VOMITING.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point >300?F/>149?C (estimated)
Extinguishing Media Carbon dioxide, dry chemical, foam, water fog or fine spray
Special Protective Equipment Positive pressure self-contained breathing apparatus (SCBA) and protective fire fighting
clothing
Hazardous Decomposition Products During combustion, Carbon Monoxide and Carbon Dioxide, Nitrogen
Oxides, Ammonia, Hydrochloric Acid, Hydrofluoric Acid, Chlorine, Fluorine, Phosgene,
Phosphorus oxides and trace amounts of Hydrogen Cyanide are given off.
SECTION 6 - HANDLING AND ACCIDENTAL RELEASE OR SPILL
Provide adequate ventilation.
Wear suitable personal protective clothing and equipment. Contain spill and collect using
a suitable absorbent material such as sawdust or vermiculite. Dispose of as ordinary
industrial waste in compliance with pertinent regulations. Wash areas with residue with warm water and soap.
FOAM IT GREEN 202 AND 602 SLOW RISE COMPONENT B PAGE TWO
SECTION 7 ?HANDLING AND STORAGE
CAUTION!! Contents under pressure.
Keep away from sparks, flame and sources of heat.
Protect containers from physical abuse. Do not puncture or incinerate.
Avoid direct sunlight.
Storage temperature: <120?F (<49癈), 75?F (24?C) is ideal
SECTION 8 - PERSONAL PROTECTION
EYE PROTECTION Wear safety goggles.
SKIN PROTECTION Wear protective clothing and chemical resistant gloves
RESPIRATORY PROTECTION Use only in well-ventilated areas. With insufficient ventilation, wear suitable respiratory
protection. When used with Component "A", follow recommendation for respiratory protection for Component
"A".
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Flash Point >300?F/>149?C
Vapor Pressure (70癋/21癈) 2500 mmHg
Specific Gravity 1.2
Appearance and Color Brown to light yellow frothy liquid with mild odor
SECTION 10 - REACTIVITY AND STABILITY
STABILITY Stable under normal use and recommended storage conditions
REACTIVITY Avoid open flames, storage temperatures above 120癋/49癈. DO NOT INCINERATE
CYLINDERS.
SECTION 11 - TOXICOLOGICAL INFORMATION
Concentration of components (Sec.2) must be considered to determine effects of this mixture.
LD50 >3000 mg/kg (rats), skin and ingestion
SECTION 12 ?ECOLOGICAL INFORMATION
None available
SECTION 13 - DISPOSAL INFORMATION
Prior to disposal, cylinders must be properly vented. Do not puncture or incinerate. Once
pressure has been relieved, empty cylinders can be disposed of as ordinary industrial
waste in compliance with pertinent regulations. Cylinders containing chemical must be
emptied prior to disposal, and chemicals should be disposed of by following instructions in
Section 6
SECTION 14 ?TRANSPORTATION INFORMATION
UN 1956, Compressed Gas n.o.s. (Fluoronated Hydrocarbon, Nitrogen), Class 2.2, PKG GRP N/A
SECTION 15- REGULATORY INFORMATION
SARA 313:
SARA 311/312 Categories: Immediate health hazard
Delayed health hazard
All ingredients are on the TSC Inventory.
This product is defined as a "Hazardous Chemical" under OSHA Hazard Communication Standard, 29 CFR 1910.1200
SECTION 16 ?OTHER INFORMATION
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