Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 3. Print Date 11/06/2009
REVISION DATE: 11/05/2009
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information
Trade name : BURMASTIC ADHESIVE SF - 5 GAL
Product code : 365600 805
Supplier : Tremco Canada division
220 Wicksteed Avenue
Toronto, ON M4H 1G7
Telephone : (416) 421-3300
Emergency Phone: : (613) 996-6666
Product use : Adhesive
Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 11/05/2009
Telephone : (416) 421-3300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Black. Liquid. May cause slight irritation to the respiratory system. May cause nausea, headaches, and dizziness.
May cause drowsiness, weakness, and fatigue. May cause allergic respiratory sensitization. Leave area to
breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention. Move to fresh air. If
required, artificial respiration or administration of oxygen can be performed by trained personnel.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system. May cause nausea, headaches, and
:
dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory
sensitization.
Eyes Direct contact may cause mild irritation.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.
Prolonged or repeated contact/exposure to aromatic petroleum distillates may cause defatting, drying, and
irritation of the skin, dermatitis, and central nervous system (CNS) effects. Prolonged or repeated exposure to
butyl benzyl phthalate may cause reduced body weights and adverse effects on the liver, kidney, spleen,
pancreas, and reproductive organs. Overexposure to maleic anhydride can cause allergic asthmatic responses
and, after long-term exposure, bronchitis.
Target Organs: Skin, Eye, Ingestion, Lung
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range
1/5 365600 805
Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 3. Print Date 11/06/2009
REVISION DATE: 11/05/2009
Asphalt 8052-42-4 15.0 - 40.0
Butyl benzyl phthalate 85-68-7 15.0 - 40.0
Heavy aromatic naphtha 64742-94-5 7.0 - 13.0
Maleic anhydride 108-31-6 0.1 - 1.0
4,4'-Methylene bis(phenylisocyanate) 101-68-8 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.Move to fresh air. If required, artificial respiration or administration
of oxygen can be performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : 149 ?300 ?br>
C, F
Method : Setaflash Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Hydrocyanic acid and
products nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate
container for disposal.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents in
one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change soiled
work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep container
closed when not in use. Since emptied containers retain product residue and vapor, observe precautions even
after container is emptied. Store under dry warehouse conditions away from heat and all ignition sources.
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Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 3. Print Date 11/06/2009
REVISION DATE: 11/05/2009
SECTION 8 - PREVENTIVE MEASURES/EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely.
Remove and wash contaminated clothing before reuse.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use general ventilation and/ or local exhaust to reduce the airborne
contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Asphalt 8052-42-4 ACGIH TWA: 0.5 mg/m3 Inhalable fraction.as
benzene solubles
Ontario TWAEV: 0.5 mg/m3 Inhalable fumeas
benzene solubles
Butyl benzyl phthalate 85-68-7
Maleic anhydride 108-31-6 Ontario TWAEV: 0.1 ppm
ACGIH TWA: 0.1 ppm
4,4'-Methylene 101-68-8 Ontario TWAEV: 0.005 ppm
bis(phenylisocyanate) ACGIH TWA: 0.005 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : Black
Odor : Petroleum
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Insoluble
Evaporation Rate: : Not available.
Specific Gravity : 1.066
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Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 3. Print Date 11/06/2009
REVISION DATE: 11/05/2009
% Volatile Weight : 1%
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Amines.Water or moisture and oxidizing agents.Alcohols.Strong acids.Strong
bases.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Butyl benzyl phthalate, CAS-No.: 85-68-7
Acute oral toxicity (LD-50 oral) 13,500 mg/kg ( Rat )
Maleic anhydride, CAS-No.: 108-31-6
Acute oral toxicity (LD-50 oral) 465 mg/kg ( Mouse ) 1,050 mg/kg ( Albino Sprague-Dawley rat
) 900 mg/kg ( Albino Sprague-Dawley rat )
Acute dermal toxicity (LD-50 dermal) 631 mg/kg ( Albino rabbit ) 398 mg/kg ( Albino rabbit )
4,4'-Methylene bis(phenylisocyanate), CAS-No.: 101-68-8
Acute inhalation toxicity (LC-50) 0.369 mg/l for 4 h ( Rat ) 0.38 mg/l for 4 h ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
4/5 365600 805
Material Safety Data Sheet
BURMASTIC ADHESIVE SF - 5 GAL
Version 3. Print Date 11/06/2009
REVISION DATE: 11/05/2009
Canadian Regulations:
WHMIS Classification : D2B, D2A
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Other Regulations:
Regulatory VOC (less water and : 21 g/l
exempt solvent)
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 1
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan
Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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