MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, and Canadian WHMIS
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
SRP VELOCITYTM
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Isocyanate Mixture
PRODUCT USE: Automotive Glass Polyurethane Adhesive
N.A. NUMBER: Not Applicable
U.N. DANGEROUS GOODS CLASS/SUBSIDIARY RISK: Not Applicable
HAZCHEM CODE (AUSTRALIA): Not Applicable
POISONS SCHEDULE NUMBER (AUSTRALIA): Not Applicable
U.S./DISTRIBUTOR'S NAME: SHAT-R-PROOF, INC.
U.S. ADDRESS: 12800 Highway 13 South, Suite 500
Savage, MN 55378
U.S. EMERGENCY PHONE: 1-800-420-8036 (in use)
1-800-424-9300 (ChemTrec)
1-703-527-3887 (ChemTrec International)
DATE OF PREPARATION: April 19, 2004
DATE OF REVISION: July 2, 2004
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # Proportion EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
mg/m 3 mg/m 3 mg/m 3 mg/m 3 mg/m 3 mg/m 3
Methoxy Propyl 108-65-6 Proprietary NE NE NE NE NE DFG MAKs:
Acetate TWA = 5
PEAK = 1稭AK 15 min.
average value, 1-hr
interval
DFG MAK Pregnancy Risk
Classification: C
Triphenyl ester Proprietary 0.1-0.5 NE NE NE NE NE NE
Morpholine Ether Proprietary 0.1-1.0 NE NE NE NE NE NE
Diphenyl Methane 101-68-8 0.1-0.7 0.051 NE NE 0.2 75 NIOSH RELs:
Diisocyanate (ceiling) TWA = 0.05
STEL = 0.2 (ceiling) 10
minutes
DFG MAKs:
TWA = 0.05 (inhalable
fraction)
PEAK = 1稭AK 15 min.,
average value, 1 hr
interval; 0.1 (ceiling)
MAK Danger of
Sensitization of the
Airways and Skin
Carcinogen: EPA-D, EPA-
CBD, IARC-3B, MAK-3
Proprietary Isocyanato Polymer 1.0-2.0% NE NE NE NE NE NE
Proprietary Olefin 2.0-3.0% NE NE NE NE NE NE
Calcium Carbonate 1317-65-3 0.5-8.0% 10 NE 5 (Respirable NE NE NIOSH REL:
Fraction); 15 TWA 5 (Respirable
(Total Dust) Fraction); 10 (Total Dust)
NE = Not Established. See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
SRP VELOCITYTM MSDS
PAGE 1 OF 11
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # Proportion EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
mg/m 3 mg/m 3 mg/m 3 mg/m 3 mg/m 3 mg/m 3
Carbon Black 1333-86-4 10-30% 3.5 NE 3.5 NE 1750 NIOSH RELs:
TWA = 3.5 (0.1 in
presence of Polycyclic
Aromatic
Hydrocarbons; 10-hr
TWA)
Carcinogen: IARC-2B,
MAK-3B, NIOSH-Ca,
TLV-A4
Diisononyl 28553-12-0 15-30% NE NE NE NE NE NE
Phthalate
Polyurethane 9048-57-1 25-45% NE NE NE NE NE NE
Prepolymer
NE = Not Established. See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product is a black, combustible liquid with a fruity odor. Health Hazards: This
product may mildly to moderately irritate contaminated tissue, especially upon prolonged exposure. Inhalation of high
concentrations of vapors may cause central nervous system depression (e.g., dizziness, headaches, and nausea).
This product contains a potential respiratory and skin sensitizer; susceptible individuals may experience allergic
reaction after inhalation or skin exposure. This product contains a potential occupational carcinogen. Flammability
Hazards: This product is a combustible liquid that may be ignited if exposed to sources of ignition or if highly heated.
Vapors of the product may travel to a distant source of ignition and flashback. In the event of a fire, the components
of this product may decompose to release smoke, irritating vapors and toxic gases (e.g., carbon dioxide, carbon
monoxide, nitrogen oxides, hydrogen cyanide, calcium oxides, carbon oxides and sulfur oxides). Reactivity
Hazards: This product is not normally reactive. Environmental Hazards: Releases of this product to the
environment, especially in large quantity, may result in environmental damage. Emergency Recommendations:
Emergency responders must wear personal protective equipment, and appropriate fire equipment suitable for the
situation to which they are responding.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of occupational
overexposure are inhalation of vapors and contact with skin and eyes. The symptoms of overexposure to this product,
via route of exposure, are as follows:
INHALATION: Inhalation of high concentrations of vapors of this product, as may occur if this material is used in a poorly
ventilated area, may cause immediate irritation of the respiratory system. If vapor high concentrations of this product
occur, symptoms of central nervous system depression may occur (e.g., headaches, dizziness, nausea). Symptoms are
generally alleviated upon breathing fresh air. The Diphenyl Methane Diisocyanate component is a potential respiratory
sensitizer. Inhalation of vapors of this product may cause allergic reaction in susceptible individuals. Symptoms may
include wheezing, coughing, difficulty breathing and angina. After initial exposure, this reaction can occur in susceptible
individuals when exposed to very small amounts of the product. Symptoms of sensitization may be delayed. Chronic
exposure to this product via inhalation may aggravate existing symptoms of bronchitis and emphysema
CONTACT WITH SKIN or EYES: Skin contact may cause reddening, discomfort, and irritation. Symptoms are generally
alleviated upon rinsing. The Diphenyl Methane Diisocyanate component is a potential skin sensitizer. Susceptible
individuals may experience allergic reaction after exposure to this product, including itching, eczema, welts and other
reaction. Prolonged or repeated skin contact may cause dermatitis (dry, red skin), skin discoloration, and hardening of
the skin. Direct contact with the eyes and the liquid product will be irritating and will result in immediate pain, and tearing
of the eyes. Vapors of the product may cause watering and irritation of the eyes. Irritation should be reversible upon
decontamination.
SRP VELOCITYTM MSDS
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3. HAZARD IDENTIFICATION
SKIN ABSORPTION: The Diisononyl Phthalate component of this
product can be absorbed via intact skin, possibly causing depression HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
of the central nervous system if a large enough area of the skin is
involved. In addition, Diisononyl Phthalate may carry of other toxic
compounds into the system. (BLUE) 2
HEALTH HAZARD
INGESTION: Ingestion is not anticipated to be a likely route of
exposure to this product. If this material is swallowed, it may cause
nausea, diarrhea, and vomiting and symptoms of central nervous
system depression, such as described under "Inhalation". A danger
FLAMMABILITY HAZARD (RED) 1
of aspiration into the lungs exists after ingestion and can cause
damage to the tissues of the lungs, resulting in chemical pneumonia
and edema (accumulation of fluid in the lungs). Ingestion of large
quantities of this product may be fatal.
PHYSICAL HAZARD (YELLOW) 0
INJECTION: Though not anticipated to be a likely route of
occupational exposure, injection of this material (via puncture or
laceration by a contaminated object) may cause local reddening,
PROTECTIVE EQUIPMENT
tissue swelling, and discomfort in addition to the wound.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An
Explanation in Lay Terms.
EYES HANDS BODY
RESPIRATORY
ACUTE: This material may irritate the eyes, skin, and mucous
membranes. Inhalation of high concentrations of this product's
vapors may cause dizziness, headaches, and nausea. Due to the SEE SECTION 8 SEE SECTION 8
presence of Diisononyl Phthalate, contamination of a large area of
skin may result in adverse effects on the central nervous system. For Routine Industrial Use and Handling Applications
CHRONIC: Prolonged or repeated skin contact may cause
dermatitis (inflammation of the skin, resulting in redness and
See Section 16 for Definition of Ratings
dryness). Due to the presence of the Diphenyl Methane Diisocyanate
component, a risk of respiratory and skin sensitization exists for susceptible individuals. Based on animal data, adverse
effects to the liver and kidneys may result after chronic exposure to this product. The Diphenyl Methane Diisocyanate
component of this product is also a suspect carcinogen and mutagen (based on animal data). Refer to Section 11,
Toxicological Information, for additional information.
TARGET ORGANS: Acute: Skin, eyes, central nervous system. Chronic: Skin, respiratory system.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Contaminated individuals should be taken for medical attention if they feel unwell or if adverse effects occur. Take copy
of label and MSDS to physician or health professional with contaminated individual.
SKIN EXPOSURE: If this material contaminates the skin, begin decontamination with running water. Recommended
flushing is for 15 minutes if any sign of skin irritation develops. Contaminated individual should seek immediate medical
attention if any adverse exposure symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open contaminated individual's eyes while under gently running water.
Use sufficient force to open eyelids. Have contaminated individual "roll" eyes. Minimum flushing is for 15 minutes. Do
not interrupt flushing. Contaminated individual must seek medical attention if any adverse effect occurs.
INHALATION: If this product is inhaled, remove contaminated individual to fresh air.
INGESTION: If this material is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST
CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Victim should drink milk, egg
whites, or large quantities of water. Never induce vomiting or give diluents (milk or water) to someone who is
unconscious, having convulsions, or unable to swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin disorders and central nervous system conditions may
be aggravated by prolonged overexposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Consider gastric lavage with
activated charcoal of ingestion.
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5. FIRE-FIGHTING MEASURES
FLASH POINT: Not established.
NFPA RATING
AUTOIGNITION TEMPERATURE: Not established for product.
FLAMMABLE LIMITS (in air by volume, %): Not established. FLAMMABILITY
FIRE EXTINGUISHING MATERIALS: Use extinguishing material
suitable to the surrounding fire.
1
Water Spray: YES (for cooling of containers) CarbonDioxide: YES
Foam: YES Dry Chemical: YES
2 0
HEALTH REACTIVITY
Halon: YES Other: Any "A" Class
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is a
Class IIIB, combustible liquid. When involved in a fire, this material
may decompose and produce irritating vapors and toxic gases (e.g.,
carbon dioxide, carbon monoxide, nitrogen oxides, hydrogen cyanide, OTHER
calcium oxides and sodium oxides). The vapors of this product may
travel to a source of ignition, and flashback to a leak or open container. See Section 16 for
Explosion Sensitivity to Mechanical Impact: Not applicable. Definition of Ratings
Explosion Sensitivity to Static Discharge: May be sensitive to static
discharge.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus and
full protective equipment. Chemical resistant clothing may be necessary. Move containers from fire area if it can be
done without risk to personnel. Water spray can be used to cool fire-exposed containers. Water fog or spray can also
be used by trained fire-fighters to disperse this product's vapors and to protect personnel. If possible, prevent runoff
water from entering storm drains, bodies of water, or other environmentally sensitive areas. Rinse contaminated
equipment thoroughly with soapy water before returning such equipment to service.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned
procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people.
Eliminate all sources of ignition before clean-up begins. Use non-sparking tools. Care should be taken as vapors of this
product are heavier than air and can accumulate in low-lying pockets, creating a fire hazard. The atmosphere must have
levels of components lower than those listed in Section 2, (Composition and Information on Ingredients) and at least 19.5
percent oxygen before personnel can be allowed into the area without Self-Contained Breathing Apparatus (SCBA).
For small spills, absorb spilled liquid with polypads or other suitable absorbent materials, wearing gloves, goggles and
apron. In the event of a non-incidental release, minimum Personal Protective Equipment should be Level B: triple-
gloves (rubber gloves and nitrile gloves, over latex gloves), chemically resistant suit and boots, hard-hat, and
Self-Contained Breathing Apparatus. Monitor area for combustible vapor levels. Absorb spilled liquid with activated
carbon, polypads, or other suitable absorbent materials. Decontaminate the area thoroughly. Prevent material from
entering sewer or confined spaces. Place all spill residue in a double plastic bag and seal. Dispose of in accordance
with applicable U.S. Federal, State, or local procedures or appropriate standards of Australia, or Canada, (see Section
13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid
breathing vapors or mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Keep away from heat, sparks, and other sources of ignition. Keep container tightly closed when not in use. Use non-
sparking tools. Bond and ground containers during transfers of material. If this product is transferred into another
container, only use portable containers and dispensing equipment (faucet, pump, drip can) approved for combustible
liquids. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is
possible. Material should be stored in secondary containers or in a diked area, as appropriate. Store containers away
from incompatible chemicals (see Section 10, Stability and Reactivity). Separate from oxidizing materials by a minimum
distance of 20 ft. or by a barrier of non-combustible material at least 5 ft. high having a fire-resistance rating of at least 0.5
hours. Storage areas should be made of fire resistant materials. Post warning and "NO SMOKING" signs in storage and
use areas, as appropriate. Have appropriate extinguishing equipment in the storage area (i.e., sprinkler system, portable
SRP VELOCITYTM MSDS
PAGE 4 OF 11
fire extinguishers). Inspect all incoming containers before storage to ensure containers are properly labeled and not
damaged. Refer to NFPA 30, Flammable and Combustible Liquids Code, for additional information on storage. Empty
containers may contain residual liquid or vapors which are combustible; therefore, empty containers should be handled
with care. Never perform any welding, cutting, soldering, drilling, or other hot work on an empty container or piping until all
liquid, vapors, and residue have been cleared.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated
in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if
necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures and
appropriate standards of Canada.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Use a mechanical fan or vent area to
outside. Where appropriate, use a non-sparking, grounded ventilation system separate from other exhaust ventilation
systems. Ensure eyewash/safety shower stations are available near areas where this product is used. If necessary,
refer to Australian National Code of Practice for the Control of Workplace Hazardous Substances [NOHSC: 2007 (1994)]
for further information.
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: In addition to the exposure limit values cited in Section 2
(Composition and Information on Ingredients), other exposure limits have been established by various countries for the
components of this mixture, as provided below (no listing for a component indicates no values are available):
CALCIUM CARBONATE: METHYLENE BISPHENYL ISOCYANATE:
Australia :TWA = 10 mg/m 3, JAN 1993 Austria: MAK = 0.005 ppm (0.05 mg/m 3), Suspected Carcinogen, JAN 1999
Belgium: TWA = 10 mg/m 3, JAN 1993 Belgium: TWA = 0.005 ppm (0.051 mg/m 3), STEL 0.02 ppm, JAN 1993
The Netherlands: MAC-TGG = 10 mg/m 3, JAN 1999 Denmark: TWA = 0.005 ppm (0.05 mg/m 3), JAN 1999
Poland: MAC(TWA) dust = 10 mg/m 3, JAN 1999 France: VLE = 0.01 ppm (0.1 mg/m 3), VLE = 0.02 ppm (0.2 mg/m 3), JAN
Russia: STEL = 6 mg/m 3, JAN 1993 1999
Switzerland: MAK-W = 6 mg/m 3 (resp. dust), JAN 1999 Germany: MAK = 0.005 ppm (0.05 mg/m 3), JAN 1999
United Kingdom: TWA = 10 mg/m 3, total inhalable dust, SEP 2000 Hungary: TWA 0.05 mg/m 3, STEL = 0.1 mg/m 3, JAN 1993
United Kingdom: TWA = 4 mg/m 3, respirable dust, SEP 2000 Japan: OEL = 0.05 mg/m 3, JAN 1999
The Netherlands: MAC-TGG = 0.005 ppm (0.05 mg/m 3), MAC-K = 0.02
In Argentina, Bulgaria, Colombia, Jordan, Korea, New Zealand, Singapore,
Vietnam check ACGIH TLV ppm, JAN 1999
Norway: TWA = 0.005 ppm (0.05 mg/m 3), JAN 1999
CARBON BLACK:
The Philippines: TWA = 0.02 ppm (0.2 mg/m 3), JAN 1993
Australia: TWA = 3 mg/m 3
Poland: MAC (TWA) = 0.05 mg/m 3, MAC(C) = 0.2 mg/m 3, JAN 1999
Belgium: TWA = 3.5 mg/m 3
Russia: STEL = 0.5 mg/m 3, Skin, JAN 1993
Denmark: TWA = 3.5 mg/m 3
Finland: TWA = 3.5 mg/m 3; STEL = 7 mg/m 3 Sweden: NGV = 0.005 ppm , TGV 0.01 ppm, JAN 1999
Switzerland: MAK-W = 5 ppm (15 mg/m 3), STEL = 25 ppm (75 mg/m 3), JAN
France: TWA = 3.5 mg/m 3
The Netherlands: TWA = 3.5 mg/m 3 1999
Thailand: TWA = 0.02 ppm (0.2 mg/m 3), JAN 1993
The Philippines: TWA = 3.5 mg/m 3
United Kingdom: TWA = 0.02 mg(NCO)/m 3, STEL 0.07 mg(NCO)/m 3, SEP
Russia: STEL = 4 mg/m 3
Sweden: TWA = 3 mg/m 3 2000
United Kingdom: TWA = 3.5 mg/m 3; STEL = 7 mg/m 3 In Argentina, Bulgaria, Colombia, Jordan, Korea, New Zealand, Singapore,
Vietnam check ACGIH TLV
In Bulgaria, Columbia, Jordan, Korea, New Zealand, Singapore, and Vietnam
check ACGIH TLV.
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed in Section 2
(Composition and Information on Ingredients) if applicable. If respiratory protection is needed, use only protection
authorized in 29 CFR 1910.134 or applicable State regulations. For operations in which mists or sprays of this product
will be generated use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard
(29 CFR 1910.134), or equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, or the Australian Standard
1716-Respiratory Protective Devices, and Australian Standard 1715-Selection, Use, and Maintenance of Respiratory
Protective Devices. The following are NIOSH respiratory protection recommendations are for the Methylene Bisphenyl
Diisocyanate component, which is known respiratory sensitizer.
METHYLENE BISPHENYL DIISOCYANATE
CONCENTRATION RESPIRATORY PROTECTION
Up to 0.5 mg/m3: Any Supplied-Air Respirator (SAR).
Up to 1.25 mg/m3: Any SAR operated in a continuous-flow mode.
Up to 2.5 mg/m3: Any Self-Contained Breathing Apparatus(SCBA) with a full facepiece, or any SAR with a full
facepiece.
Up to 75 mg/m3: Any SAR that has a full facepiece and is operated in a pressure-demand or other positive-
pressure mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and
is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in combination
with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
SRP VELOCITYTM MSDS
PAGE 5 OF 11
Escape: Any Air-Purifying, Full-Facepiece Respirator (gas mask) with a chin-style, front- or back-mounted
organic vapor canister having a high-efficiency particulate filter, or any appropriate escape-type,
SCBA.
EYE PROTECTION: Splash goggles or safety glasses may be worn if operations can generate mists of this product. If
necessary, refer to U.S. OSHA 29 CFR 1910.133, or the Australian Standard 1337-Eye Protection for Industrial
Applications and Australian Standard 1336-Recommended Practices for Eye Protection in the Industrial Environment for
further information.
HAND PROTECTION: Polyvinyl alcohol, polyethylene/ethylene vinyl alcohol, 4HTM, BarricadeTM, or ResponderTM gloves.
Natural rubber, butyl rubber, neoprene, polyvinyl chloride, and nitrile gloves are not recommended. If necessary, refer to
U.S. OSHA 29 CFR 1910.138 appropriate Standards of Canada, or the Australian Standard 2161-Industrial Safety
Gloves and Mittens for further information.
BODY PROTECTION: None normally needed under typical circumstances of use. If necessary, use body protection
appropriate for task (e.g., Tyvek suit, rubber apron). If necessary, refer appropriate Standards of Canada, the European
Economic Community or the to Australian Standard 3765-Clothing for Protection Against Hazardous Chemicals for
further information. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce
the soles of the feet or where employee's feet may be exposed to electrical hazards, use foot protection, as described in
U.S. OSHA 29 CFR 1910.136.
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): > 1 EVAPORATION RATE (nBuAc = 1): Not established.
SPECIFIC GRAVITY (water = 1): > 1 MELTING/FREEZING POINT: Not established.
SOLUBILITY IN WATER: Insoluble. BOILING POINT: Not established.
VAPOR PRESSURE: < 110 kPa (1.10 bar) pH: Not established.
ODOR THRESHOLD: Not established for product.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
APPEARANCE, ODOR and COLOR: This product is a black, viscous, liquid with a acrylate odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The color and viscosity of this product may be a warning
property.
10. STABILITY and REACTIVITY
STABILITY: Stable under normal conditions of temperature and pressure.
DECOMPOSITION PRODUCTS: The products of thermal decomposition of this material include irritating vapors and
toxic gases (e.g., carbon dioxide, carbon monoxide, nitrogen oxides, hydrogen cyanide, phosgene, phosphorous
oxides).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is incompatible with strong oxidizers,
strong acids. This product will attack some forms of rubber, plastics and coatings.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible chemicals, exposure to elevated temperatures.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The specific toxicology data available for the components of this product present in greater than 1
percent concentration are presented below:
TCLo (Inhalation-rat) 11600 礸/m3/18 hours/2
CALCIUM CARBONATE: TDLo (Oral-Mouse) 201 gm/kg/2 years-
TCLo (Inhalation-Rat) 84 mg/m 3/4 hours/40 continuous: Tumorigenic: carcinogenic by
years-intermittent; Tumorigenic: Carcinogenic
RTECS criteria; Liver: tumors
weeks-intermittent: Lungs, Thorax, or by RTECS criteria; Lungs, Thorax, or
DIPHENYL METHANE DIISOCYANATE:
Respiration: fibrosis (interstitial); Liver:-other Respiration: tumors
changes; Kidney, Ureter, Bladder: other Standard Draize Test (Skin-Rabbit) 500 mg/24
DIISONONYL PHTHALATE
changes hours
TDLo (Oral-Rat) 11,256 mg/kg/28 days-
TCLo (Inhalation-Rat) 250 mg/m 3/2 hours/24 Standard Draize Test (Eye-Rabbit) 100 mg:
continuous: Liver: other changes, changes in
weeks-intermittent: Lungs, Thorax, or Moderate
liver weight; Blood: changes in serum
Respiration: fibrosis, focal (pneumoconiosis) TCLo (Inhalation-Human) 130 ppb/30 minutes:
composition (e.g. TP, bilirubin, cholesterol)
CARBON BLACK: Immunological Including Allergic: increased
TDLo (Oral-Rat) 109 gm/kg/13 weeks-
immune response; Nutritional and Gross
Mutation in Microorganisms-Salmonella continuous: Kidney, Ureter, Bladder: changes
Metabolic: body temperature increase
typhimurium 1 mg/plate in bladder weight; Blood: normocytic anemia;
add-Mouse-Inhalation 6200 mg/m 3/16 hours/12 LD50 (Oral-Rat) 9200 mg/kg: Behavioral:
Related to Chronic Data: changes in uterine
somnolence (general depressed activity),
weeks-intermittent weight
ataxia; Nutritional and Gross Metabolic: body
LD50 (Oral-rat) > 15400 mg/kg; Behavioral: TDLo (Oral-Rat) 10 gm/kg: female 6 -15 day(s)
temperature decrease
somnolence (general depressed activity) after conception: Reproductive: Maternal
LD50 (Oral-Mouse) 2200 mg/kg
LD50 (Skin-rabbit) >3 gm/kg Effects: other effects; Reproductive: Effects
LC50 (Inhalation-Rat) 178 mg/m 3
TCLo (Inhalation-rat) 50 mg/m 3/6 hours/90 days- on Embryo or Fetus: fetotoxicity (except
intermittent; Lungs, Thorax, or Respiration: death, e.g., stunted fetus)
other changes.
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DIPHENYL METHANE DIISOCYANATE DIPHENYL METHANE DIISOCYANATE TRIPHENYL ESTER (continued):
(continued): (continued): LDLo (Subcutaneous-Cat) 300 mg/kg:
TCLo (Inhalation-Rat) 8 mg/m 3/6 hours: Lungs, Behavioral: ataxia
Cytogenetic Analysis (Human-Lymphocyte) 540
LDLo (Intraperitoneal-Cat) 100 mg/kg: Peripheral
Thorax, or Respiration: respiratory mg/L
Nerve and Sensation: spastic paralysis with
depression; Skin and Appendages: Sister Chromatid Exchange (Human-
or without sensory change; Behavioral:
cutaneous sensitization, experimental (after Lymphocyte) 2170 mg/L
DNA Adduct (Inhalation-Rat) 2 mg/m 3/52 weeks- somnolence (general depressed activity),
topical exposure); Biochemical: Enzyme
tremor
inhibition, induction, or change in blood or intermittent
Micronucleus Test (Inhalation-Rat) 7.1 mg/m 3/3 LDLo (Subcutaneous-Chicken) 375 mg/kg:
tissue levels: phosphatases
TCLo (Inhalation-Rat) 20 mg/m 3/6 hours: Lungs, Behavioral: food intake (animal), ataxia
hours
LDLo (Skin-Rabbit) 5 gm/kg: Behavioral:
Thorax, or Respiration: changes in lung TRIPHENYL ESTER:
somnolence (general depressed activity)
weight, other changes Standard Draize Test (Skin-Human) 125 mg/48
TCLo (Inhalation-Rat) 2.4 mg/m 3/6 hours: Lungs, LDLo (Oral-Chicken) 250 mg/kg: Behavioral:
hours: Severe
ataxia
Thorax, or Respiration: other changes; Standard Draize Test (Skin-Rabbit) 500 mg:
TDLo (Subcutaneous-Rat) 3 552 mg/kg/7 days-
Biochemical: Metabolism (Intermediary): Severe
intermittent: Brain and Coverings: recordings
lipids including transport Standard Draize Test (Skin-Rabbit) 20 mg/24
TCLo (Inhalation-Rat) 0.7 mg/m 3/6 hours: Lungs, from specific areas of CNS; Autonomic
hours: Moderate
Nervous System: other (direct)
Thorax, or Respiration: structural or Standard Draize Test (Eye-Rabbit) 500 mg/24
parasympathomimetic; Behavioral: ataxia
functional change in trachea or bronchi, other hours: Mild
TDLo (Skin-Chicken) 5 gm/kg/5 days-intermittent:
changes; Biochemical: Metabolism LD50 (Oral-Rat) 444 mg/kg
Behavioral: ataxia; Skin and Appendages:
(Intermediary): other proteins LD50 (Oral-Mouse) 1080 mg/kg
3
dermatitis, other (after systemic exposure);
TCLo (Inhalation-Rat) 3 mg/m /18 hours/90 days- LD50 (Intraperitoneal-Rat) 250 mg/kg
Biochemical: Enzyme inhibition, induction, or
intermittent: Sense Organs and Special LD50 (Intraperitoneal-Mammal-species
change in blood or tissue levels: true
Senses (Olfaction): effect, not otherwise unspecified) 250 mg/kg: Brain and
cholinesterase
specified; Lungs, Thorax, or Respiration: Coverings: other degenerative changes;
TCLo (Inhalation-Mammal-species unspecified) 9
other changes Behavioral: convulsions or effect on seizure
mg/m 3/4 hours/45 days-intermittent:: Blood:
TCLo (Inhalation-Guinea Pig) 2 mg/m 3/3 threshold; Cardiac: other changes
changes in erythrocyte (RBC) count,
hours/days-intermittent: Lungs, Thorax, or LD50 (Intraperitoneal-Mouse) 266 mg/kg
changes in leukocyte (WBC) count;
Respiration: structural or functional change in LD50 (Unreported-Rat) 1490 mg/kg: Behavioral:
Nutritional and Gross Metabolic: weight loss
trachea or bronchi, changes in lung weight somnolence (general depressed activity),
TCLo (Inhalation-Rat) 9 mg/m 3/6H\ hours: female or decreased weight gain
tremor, changes in motor activity (specific
MORPHOLINE ETHER:
6-15 day(s) after conception: Reproductive: assay)
Maternal Effects: other effects; Specific Currently, there are no data available for this
LD50 (Unreported-Mouse)1360 mg/kg:
Developmental Abnormalities: compound.
Behavioral: somnolence (general depressed
musculoskeletal system PROPRIETARY OLEFIN:
activity), tremor, changes in motor activity
Mutation in Microorganisms (Bacteria-Salmonella (specific assay) Currently, there are no data available for this
typhimurium) 50 礸/plate LC (Inhalation-Rat) >6700 mg/m 3/1 hour compound.
LDLo (Subcutaneous-Rat) 2 gm/kg: Peripheral PROPRIETARY ISOCYANOTO POLYMER:
DNA Damage (Inhalation-Human) 20 ppb/15
Nerve and Sensation: flaccid paralysis
minutes-continuous Currently, there are no data available for this
without anesthesia (usually neuromuscular compound.
blockage); Behavioral: tremor, muscle
weakness
SUSPECTED CANCER AGENT: Two components are listed by agencies tracking potential carcinogenic effects, as
follows:
CARBON BLACK: ACGIH-TLV A4 (Not Classifiable as a Human Carcinogen); IARC-2B (Possibly Carcinogenic to Humans) ; MAK-3 (Substances that
Cause Concern that They Could Be Carcinogenic for Man but Which Cannot Be Assessed Conclusively Because of Lack of Data); NIOSH-Ca (Potential
Occupational Carcinogen with No Further Categorization)
DIPHENYL METHANE DIISOCYANATE: EPA-D (Not Classifiable as to Human Carcinogenicity); EPA-CBD (Cannot Be Determined); IARC-3B
(Substances for Which in vitro Tests or Animal Studies Have Yielded Evidence of Carcinogenic Effects That is Not Sufficient for Classification of the
Substance in One of the Other Categories); MAK3B (Substances Which Cause Concern That They Could Be Carcinogenic for Man, But Which Cannot
Be Assessed Conclusively Because of Lack of Data. )
The remaining components are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and CAL/OSHA,
and therefore are neither considered to be nor suspected to be cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: This product may be mildly irritating to contaminated, skin, and moderately to severely
irritating to the eyes and mucous membranes.
SENSITIZATION TO THE PRODUCT: The Diphenyl Methane Diisocyanate component of this product is a respiratory
and skin sensitizer. Subsequent exposure to susceptible individuals may result in allergic respiratory reaction.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: In one case report, the Diphenyl Methane Diisocyanate component caused DNA damage in human white
blood cells after inhalation exposure to 5 to 20 ppb. This report provides insufficient information for determining the
mutagenicity of Diphenyl Methane Diisocyanate. No other human or animal in vivo studies have been reported.
Methylene Bisphenyl Isocyanate induced chromosome aberrations in cultured human lymphocytes, with and without
metabolic activation. Methylene Bisphenyl Isocyanate only marginally increased sister chromatid exchanges at a
high dose, with and without metabolic activation.
Embryotoxicity: The components of this product are not reported to produce embryotoxic effects in humans.
Teratogenicity: The components of this product are not reported to cause teratogenic effects in humans. There are
animal teratogenic data for the Diisononyl Phthalate component of this product. In a 6-day oral-rat study, Diisononyl
Phthalate caused adverse effects on the mother and stunted fetus growth.
Reproductive Toxicity: The components of this product are not reported to cause reproductive effects in humans.
SRP VELOCITYTM MSDS
PAGE 7 OF 11
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through
generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of
pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which causes damage
to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance which
interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURES INDICES (BEIs): Currently, there are no ACGIH Biological Exposure Indices (BEIs)
determined for the components of this product.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The components of this product are relatively stable under ambient environmental
conditions. The following data are available for one of the main components, Diisononyl Phthalate:
DIISONONYL PHTHALATE:
Terrestrial Fate: Based on a recommended classification scheme, an estimated Koc value of 10,580, determined from a measured water solubility of 0.2
mg/L and a recommended regression-derived equation, indicates that Diisononyl Phthalate is expected to have no mobility in soil. Volatilization of
Diisononyl Phthalate is expected from moist soil surfaces given an estimated Henry's Law constant of 1.49X10-6 atm-cu m/mole, determined from an
experimental vapor pressure of 5.4X10-7 mm Hg at 25癈 and the measured water solubility of 0.2 mg/L at 20癈; but this process may be considerably
attenuated due to adsorption. Diisononyl phthalate is not expected to volatilize from dry soil surfaces based on the measured vapor pressure of this
compound. Aqueous screening studies and die-away tests suggest that Diisononyl Phthalate may biodegrade in soil.
Aquatic Fate: Based on a recommended classification scheme, an estimated Koc value of 10,580, determined from a measured water solubility of 0.2
mg/L and a recommended regression-derived equation, indicates that Diisononyl Phthalate is expected to adsorb to suspended solids and sediment in
water. Diisononyl Phthalate is expected to volatilize from water surfaces based on an estimated Henry's Law constant of 1.49X10-6 atm-cu m/mole,
determined from an experimental vapor pressure of 5.4X10-7 mm Hg at 25癈 and the measured water solubility of 0.2 mg/L at 20癈; but adsorption
may severely attenuate this process. Estimated half-lives for a model river and model lake are 51 and 374, days respectively when adsorption is
neglected. The volatilization half-life from a model pond is approximately 120 years when adsorption is considered. According to a classification
scheme, an estimated BCF value of 1,500, from the measured water solubility, suggests that bioconcentration in aquatic organisms is high.
Bioconcentration studies on other phthalate esters suggest that bioconcentration may be lower than indicated by the regression derived equations due
to aquatic organisms ability to metabolize phthalate esters. Screening studies and die-away tests indicate that Diisononyl Phthalate will biodegrade in
the environment.
Atmospheric Fate: According to a model of gas/particle partitioning of semi-volatile organic compounds in the atmosphere, Diisononyl Phthalate, which
has a measured vapor pressure of 5.4X10-7 mm Hg at 25癈, is expected to exist in both the vapor and particulate phases in the ambient atmosphere.
Vapor-phase Diisononyl Phthalate is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this
reaction in air is estimated to be about 16 hours. Particulate-phase Diisononyl Phthalate will be removed from the atmosphere by wet and dry
deposition.
Bioconcentration: An estimated BCF value of 1,530 was calculated for Diisononyl Phthalate, using a measured water solubility of 0.2 mg/L and a
recommended regression-derived equation. According to a classification scheme, this BCF value suggests that bioconcentration in aquatic
organisms is high. Bioconcentration studies on other phthalate esters suggest that bioconcentration may be lower than indicated by the regression
derived equations due to aquatic organisms ability to metabolize phthalate esters.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful to contaminated terrestrial plants and
animals.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may have significant, adverse effects on aquatic plants and
animals if accidentally released to an aquatic environment.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State,
and local regulations or with regulations of Canada. This product, if unaltered by use, may be disposed of by treatment at
a permitted facility or as advised by your local waste regulatory authority. Empty containers, as defined by appropriate
sections of RCRA, are not RCRA hazardous wastes. Insure proper management of any residuals remaining in
containers.
EPA WASTE NUMBER: Wastes of this product should be tested to see if they meet the criteria of D001, Characteristic-
Ignitability
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Not Applicable.
HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable.
UN IDENTIFICATION NUMBER: Not Applicable.
DOT LABEL(S) REQUIRED: Not Applicable.
PACKAGING GROUP: Not Applicable.
NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): Not Applicable.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is NOT
considered as Dangerous Goods, per regulations of Transport Canada.
INTERNATIONAL AIR TRANSPORT ASSOCIATION DESIGNATION: This material is NOT considered as dangerous
goods, per rules of IATA.
SRP VELOCITYTM MSDS
PAGE 8 OF 11
INTERNATIONAL MARITIME ORGANIZATION (IMO): This product is considered as dangerous goods, per rules of the
IMO, as follows:
AUSTRALIAN FEDERAL OFFICE OF ROAD SAFETY CODE FOR THE TRANSPORTATION OF DANGEROUS
GOODS BY ROAD OR RAIL: This material is NOT considered as dangerous goods, per regulations of the Federal
Office of Road Safety.
15. REGULATORY INFORMATION
U.S. STATE AND FEDERAL REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements
of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Diphenyl Methane No No Yes
Diisocyanate
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this product.
The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per
40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Diphenyl Methane Diisocyanate = 5000 lb (2270 kg)
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Diisononyl Phthalate, as a phthalate ester is designated as a Toxic pollutant
designated pursuant to section 307(a)(1) of the Clean Water Act and is subject to effluent limitations.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of
this product is on the California Proposition 65 lists.
U.S. ANSI STANDARD LABELING (Z129.1): WARNING! COMBUSTIBLE LIQUID. MAY BE IGNITED IF SUBJECTED TO DIRECT
FLAME OR IF HIGHLY HEATED. HARMFUL IF INHALED OR INGESTED. CAN CAUSE ADVERSE EFFECTS ON THE CENTRAL
NERVOUS SYSTEM. CAUSES SKIN, RESPIRATORY SYSTEM AND EYE IRRITATION. CONTAINS KNOWN SKIN AND RESPIRATORY
SENSITIZER. ASPIRATION HAZARD ?INGESTION CAN CAUSE LIFE-THREATENING LUNG DAMAGE. Keep away from heat, spark or
flame. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing vapors o mist. Keep container closed. Use only with
r
adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, respiratory protection and eye protection, as appropriate.
FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. If inhaled, remove to fresh air. If
ingested, do not induce vomiting and get medical attention. Get medical attention if any adverse reaction occurs. IN CASE OF FIRE: Use
water fog (for cooling of containers), dry chemical, CO2, or "alcohol" foam. IN CASE OF SPILL: Absorb spill with inert material. Replace
residue in suitable container. Consult Material Safety Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL INVENTORY: The components of this product are listed on the DSL Inventory.
CANADIAN WHMIS IDL DISCLOSURE STATUS: The Diphenyl Methane Diisocyanate (listed as 4,4'Diphenylmethane
Diisocyanate) component has a disclosure requirement of 0.1%. The Carbon Black and Triphenyl ester components of
this product have a disclosure requirement level of 1%.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION AGENCY (CEPA) PRIORITY SUBSTANCES LISTS: The components
of this product are not on the Priority Substances Lists.
CANADIAN WHMIS SYMBOLS:
Class D2A: Poisonous and Infectious Material, Chronic
effects - Respiratory and Skin Sensitizer.
Class D2B: Poisonous and Infectious Material, Acute
effects - Central Nervous System Effects
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 3519, La Mesa, CA 91944-3519 (619) 670-0609
SHAT-R-PROOF, INC. CHEMISTRY DEPARTMENT
12800 Highway 13 South, Suite 500, Savage, MN 55378 (952) 944-8000
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Shat-R-Proof assumes no responsibility for injury to the vendee or third persons proximately caused
by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Shat-R-Proof assumes no responsibility for
injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore,
vendee assumes the risk in his use of the material.
SRP VELOCITYTM MSDS
PAGE 9 OF 11
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
identifies each constituent. RATINGS (continued):
EXPOSURE LIMITS IN AIR: FLAMMABILITY HAZARD:
CEILING LEVEL: The concentration that shall not be exceeded during any 0 (Minimal Hazard-Materials that will not burn in air when exposure to a
part of the working exposure. temperature of 815.5癈 [1500癋] for a period of 5 minutes.); 1 (Slight
LOQ: Limit of Quantitation. Hazard-Materials that must be pre-heated before ignition can occur.
MAK: Federal Republic of Germany Maximum Concentration Values in the Material require considerable pre-heating, under all ambient temperature
workplace. conditions before ignition and combustion can occur, Including: Materials
NE: Not Established. When no exposure guidelines are established, an that will burn in air when exposed to a temperature of 815.5癈 (1500癋) for a
entry of NE is made for reference. period of 5 minutes or less; Liquids, solids and semisolids having a flash
NIC: Notice of Intended Change. point at or above 93.3癈 [200癋] (e.g. OSHA Class IIIB, or; Most ordinary
NIOSH CEILING: The exposure that shall not be exceeded during any part combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-
of the workday. If instantaneous monitoring is not feasible, the ceiling shall Materials that must be moderately heated or exposed to relatively high
be assumed as a 15-minute TWA exposure (unless otherwise specified) ambient temperatures before ignition can occur. Materials in this degree
that shall not be exceeded at any time during a workday. would not, under normal conditions, form hazardous atmospheres in air, but
NIOSH RELs: NIOSH's Recommended Exposure Limits. under high ambient temperatures or moderate heating may release vapor in
PEL-Permissible Exposure Limit: OSHA's Permissible Exposure Limits. sufficient quantities to produce hazardous atmospheres in air, Including:
This exposure value means exactly the same as a TLV, except that it is Liquids having a flash-point at or above 37.8癈 [100癋]; Solid materials in
enforceable by OSHA. The OSHA Permissible Exposure Limits are based the form of course dusts that may burn rapidly but that generally do not form
in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal explosive atmospheres; Solid materials in a fibrous or shredded form that
Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the may burn rapidly and create flash fire hazards (e.g. cotton, sisal, hemp;
vacated PELs are indicated. The phrase, "Vacated 1989 PEL," is placed Solids and semisolids that readily give off flammable vapors.); 3 (Serious
next to the PEL that was vacated by Court Order. Hazard- Liquids and solids that can be ignited under almost all ambient
SKIN: Used when a there is a danger of cutaneous absorption. temperature conditions. Materials in this degree produce hazardous
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a atmospheres with air under almost all ambient temperatures, or, unaffected
15-minute time-weighted average (TWA) exposure that should not be by ambient temperature, are readily ignited under almost all conditions,
exceeded at any time during a workday, even if the 8-hr TWA is within the including: Liquids having a flash point below 22.8癈 [73癋] and having a
TLV-TWA, PEL-TWA or REL-TWA. boiling point at or above 38癈 [100癋] and below 37.8癈 [100癋] [e.g. OSHA
TLV-Threshold Limit Value: An airborne concentration of a substance that Class IB and IC]; Materials that on account of their physical form or
represents conditions under which it is generally believed that nearly all environmental conditions can form explosive mixtures with air and are
workers may be repeatedly exposed without adverse effect. The duration readily dispersed in air [e.g., dusts of combustible solids, mists or droplets
must be considered, including the 8-hour. of flammable liquids]; Materials that burn extremely rapidly, usually by
TWA-Time Weighted Average: Time Weighted Average exposure reason of self-contained oxygen [e.g. dry nitrocellulose and many organic
concentration for a conventional 8 (TLV, PEL) or up to a 10-hr (REL)
-hr peroxides]);)4 (Severe Hazard-Materials that will rapidly or completely
workday and a 40-hr workweek. vaporize at atmospheric pressure and normal ambient temperature or that
IDLH-Immediately Dangerous to Life and Health: This level represents a are readily dispersed in air, and which will burn readily, including:
concentration from which one can escape within 30-minutes without Flammable gases; Flammable cryogenic materials; Any liquid or gaseous
suffering escape-preventing or permanent injury. material that is liquid while under pressure and has a flash point below
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD 22.8癈 [73癋] and a boiling point below 37.8癈 [100癋] [e.g. OSHA Class IA;
RATINGS: This rating system was developed by the National Paint and Material that ignite spontaneously when exposed to air at a temperature of
Coating Association and has been adopted by industry to identify the degree 54.4癈 [130癋] or below [e.g. pyrophoric]).
of chemical hazards. PHYSICAL HAZARD:
HEALTH HAZARD: 0 (Water Reactivity: Materials that do not react with water. Organic
0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not Peroxides: Materials that are normally stable, even under fire conditions and
anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = "0". will not react with water. Explosives: Substances that are Non-Explosive.
Eye Irritation: Essentially non-irritating, or minimal effects which clear in < Unstable Compressed Gases: No Rating. Pyrophorics: No Rating.
24 hours [e.g. mechanical irritation]. Draize = "0". Oral Toxicity LD 50 Rat: < Oxidizers: No "0" rating allowed. Unstable Reactives: Substances that will
5000 mg/kg. Dermal Toxicity LD 50Rat or Rabbit: < 2000 mg/kg. Inhalation not polymerize, decompose, condense or self-react.); 1 (Water Reactivity:
Toxicity 4-hrs LC 50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Materials that change or decompose upon exposure to moisture. Organic
Injury may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly Peroxides: Materials that are normally stable, but can become unstable at
irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LD 50 Rat: > high temperatures and pressures. These materials may react with water,
500-5000 mg/kg. Dermal Toxicity LD 50Rat or Rabbit: > 1000-2000 mg/kg. but will not release energy. Explosives: Division 1.5 & 1.6 substances that
Inhalation Toxicity LC 50 4-hrs Rat: > 2-20 mg/L) ; (Moderate Hazard:
2 are very insensitive explosives or that do not have a mass explosion hazard.
Temporary or transitory injury may occur. Skin Irritation: Moderately Compressed Gases: Pressure below OSHA definition. Pyrophorics: No
irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation: Rating. Oxidizers: Packaging Group III; Solids: any material that in either
Moderately to severely irritating and/or corrosive; reversible corneal opacity; concentration tested, exhibits a mean burning time less than or equal to the
corneal involvement or irritation clearing in 8 -21 days. Draize > 0, < 25. mean burning time of a 3:7 potassium bromate/cellulose mixture and the
Oral Toxicity LD 50 Rat: > 50-500 mg/kg. Dermal Toxicity LD 50Rat or criteria for Packing Group I and II are not met. Liquids: any material that
Rabbit: > 200-1000 mg/kg. Inhalation Toxicity LC 50 4-hrs Rat: > 0.5-2 exhibits a mean pressure rise time less than or equal to the pressure rise
mg/L.);3 (Serious Hazard: Major injury likely unless prompt action is taken time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing
and medical treatment is given; high level of toxicity; corrosive. Skin Group I and II are not met. Unstable Reactives: Substances that may
Irritation: Severely irritating and/or corrosive; may destroy dermal tissue, decompose, condense or self-react, but only under conditions of high
cause skin burns, dermal necrosis. PII or Draize > 5-8 with destruction of temperature and/or pressure and have little or no potential to cause
tissue. Eye Irritation: Corrosive, irreversible destruction of ocular tissue; significant heat generation or explosive hazard. Substances that readily
corneal involvement or irritation persisting for more than 21 days. Draize > undergo hazardous polymerization in the absence of inhibitors.); 2 (Water
80 with effects irreversible in 21 days. Oral Toxicity LD 50 Rat: > 1-50 Reactivity: Materials that may react violently with water. Organic
mg/kg. Dermal Toxicity LD 50Rat or Rabbit: > 20-200 mg/kg. Inhalation Peroxides: Materials that, in themselves, are normally unstable and will
Toxicity LC 50 4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life- readily undergo violent chemical change, but will not detonate. These
threatening; major or permanent damage may result from single or repeated materials may also react violently with water. Explosives: Division 1.4 ?br>
exposure. Skin Irritation: Not appropriate. Do not rate as a "4", based on Explosive substances where the explosive effect are largely confined to the
skin irritation alone. Eye Irritation: Not appropriate. Do not rate as a "4", package and no projection of fragments of appreciable size or range are
based on eye irritation alone. Oral Toxicity LD 50 Rat: < 1 mg/kg. Dermal expected. An external fire must not cause virtually instantaneous explosion
Toxicity LD 50Rat or Rabbit: < 20 mg/kg. Inhalation Toxicity LC 50 4-hrs Rat: of almost the entire contents of the package.
< 0.05 mg/L).
SRP VELOCITYTM MSDS
PAGE 10 OF 11
DEFINITION OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
RATINGS (continued): RATINGS (continued):
PHYSICAL HAZARD (continued): INSTABILITY HAZARD: 0 Materials that in themselves are normally stable,
2 (continued): Compressed Gases: Pressurized and meet OSHA even under fire conditions. 1 Materials that in themselves are normally
stable, but that can become unstable at elevated temperatures and
definition but < 514.7 psi absolute at 21.1癈 (70癋) [500 psig]. Pyrophorics:
pressures. 2 Materials that readily undergo violent chemical change at
No Rating. Oxidizers: Packing Group II Solids: any material that, either in
elevated temperatures and pressures. 3 Materials that in themselves are
concentration tested, exhibits a mean burning time of less than or equal to
the mean burning time of a 2:3 potassium bromate/cellulose mixture and the capable of detonation or explosive decomposition or explosive reaction, but
criteria for Packing Group I are not met. Liquids: any material that exhibits a that require a strong initiating source or that must be heated under
mean pressure rise time less than or equal to the pressure rise of a 1:1 confinement before initiation. 4 Materials that in themselves are readily
aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria capable of detonation or explosive decomposition or explosive reaction at
for Packing Group I are not met. Unstable Reactives: Substances that may normal temperatures and pressures.
polymerize, decompose, condense, or self-react at ambient temperature FLAMMABILITY LIMITS IN AIR:
and/or pressure, but have a low potential for significant heat generation or Much of the information related to fire and explosion is derived from the
explosion. Substances that readily form peroxides upon exposure to air or National Fire Protection Association (NFPA). Flash Point - Minimum
oxygen at room temperature); 3 (Water Reactivity: Materials that may form temperature at which a liquid gives off sufficient vapors to form an ignitable
explosive reactions with water. Organic Peroxides: Materials that are mixture with air. Autoignition Temperature: The minimum temperature
capable of detonation or explosive reaction, but require a strong initiating required to initiate combustion in air with no other source of ignition. LEL -
source, or must be heated under confinement before initiation; or materials the lowest percent of vapor in air, by volume, that will explode or ignite in the
that react explosively with water. Explosives: Division 1.2 ?Explosive presence of an ignition source. UEL - the highest percent of vapor in air, by
substances that have a fire hazard and either a minor blast hazard or a volume, that will explode or ignite in the presence of an ignition source.
minor projection hazard or both, but do not have a mass explosion hazard. TOXICOLOGICAL INFORMATION:
Compressed Gases: Pressure > 514.7 psi absolute at 21.1癈 (70癋) [500 Human and Animal Toxicology: Possible health hazards as derived from
psig]. Pyrophorics: No Rating. Oxidizers: Packing Group I Solids: any human data, animal studies, or from the results of studies with similar
material that, in either concentration tested, exhibits a mean burning time compounds are presented. Definitions of some terms used in this section
less than the mean burning time of a 3.:2 potassium bromate/cellulose are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed
mixture. Liquids: Any material that spontaneously ignites when mixed with animals; LC50 - Lethal Concentration (gases) which kills 50% of the
cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less
exposed animals; ppm concentration expressed in parts of material per
than the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture.
million parts of air or water; mg/m3 concentration expressed in weight of
Unstable Reactives: Substances that may polymerize, decompose,
substance per volume of air; mg/kg quantity of material, by weight,
condense or self-react at ambient temperature and/or pressure and have a
administered to a test subject, based on their body weight in kg. Other
moderate potential to cause significant heat generation or explosion.); 4
measures of toxicity include TDLo, the lowest dose to cause a symptom
(Water Reactivity: Materials that react explosively with water without
and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and
requiring heat or confinement. Organic Peroxides: Materials that are readily
LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to
capable of detonation or explosive decomposition at normal temperature
cause lethal or toxic effects. Cancer Information: The sources are: IARC
and pressures. Explosives: Division 1.1 & 1.2-explosive substances that
- the International Agency for Research on Cancer; NTP - the National
have a mass explosion hazard or have a projection hazard. A mass
Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical
explosion is one that affects almost the entire load instantaneously.
Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a
Compressed Gases: No Rating. Pyrophorics: Add to the definition of
Flammability "4". Oxidizers: No "4" rating. Unstable Reactives: scale of decreasing potential to cause human cancer with rankings from 1
Substances that may polymerize, decompose, condense or self-react at to 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI -
ambient temperature and/or pressure and have a high potential to cause ACGIH Biological Exposure Indices, represent the levels of determinants
significant heat generation or explosion.). which are most likely to be observed in specimens collected from a healthy
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD worker who has been exposed to chemicals to the same extent as a worker
with inhalation exposure to the TLV.
RATINGS:
ECOLOGICAL INFORMATION:
HEALTH HAZARD: 0 (material that on exposure under fire conditions would
EC is the effect concentration in water. BCF = Bioconcentration Factor,
offer no hazard beyond that of ordinary combustible materials); 1 (materials
which is used to determine if a substance will concentrate in lifeforms which
that on exposure under fire conditions could cause irritation or minor
consume contaminated plant or animal matter. TLm = median threshold
residual injury); 2 (materials that on intense or continued exposure under
limit; Coefficient of Oil/Water Distribution is represented by log Kow or log
fire conditions could cause temporary incapacitation or possible residual
Koc and is used to assess a substance's behavior in the environment.
injury); 3 (materials that can on short exposure could cause serious
REGULATORY INFORMATION:
temporary or residual injury); 4 (materials that under very short exposure
could cause death or major residual injury). U.S. and CANADA:
FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire This section explains the impact of various laws and regulations on the
conditions, including intrinsically noncombustible materials such as material. EPA is the U.S. Environmental Protection Agency. ACGIH:
concrete, stone, and sand. 1 Materials that must be preheated before American Conference of Governmental Industrial Hygienists, a professional
ignition can occur. Materials in this degree require considerable preheating, association which establishes exposure limits. NIOSH is the National
under all ambient temperature conditions, before ignition and combustion Institute of Occupational Safety and Health, which is the research arm of the
can occur 2 Materials that must be moderately heated or exposed to U.S. Occupational Safety and Health Administration (OSHA). WHMIS is the
relatively high ambient temperatures before ignition can occur. Materials in Canadian Workplace Hazardous Materials I formation System. DOT and
n
this degree would not under normal conditions form hazardous TC are the U.S. Department of Transportation and the Transport Canada,
atmospheres with air, but under high ambient temperatures or under respectively. Superfund Amendments and Reauthorization Act (SARA); the
moderate heating could release vapor in sufficient quantities to produce Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S.
hazardous atmospheres with air. 3 Liquids and solids that can be ignited Toxic Substance Control Act (TSCA) ; Marine Pollutant status according to
under almost all ambient temperature conditions. Materials in this degree the DOT; the Comprehensive Environmental Response, Compensation,
produce hazardous atmospheres with air under almost all ambient and Liability Act (CERCLA or Superfund); and various state regulations.
temperatures or, though unaffected by ambient temperatures, are readily This section also includes information on the precautionary warnings which
ignited under almost all conditions. 4 Materials that will rapidly or completely appear on the material's package label. OSHA - U.S. Occupational Safety
vaporize at atmospheric pressure and normal ambient temperature or that and Health Administration.
are readily dispersed in air and will burn readily.
SRP VELOCITYTM MSDS
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