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MSDS Material Safety Data Sheet
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14567-64-7 25791-96-2 9016-87-9 101-68-8 1332-58-7 120962-03-0 26447-40-5

File Name: 14567-64-7_25791-96-2_9016-87-9_101-68-8_1332-58-7_120962-03.asp

                                   Material Safety Data Sheet
Product: Florikote Controlled Release Magnesium Sulfate

MSDS Date: 5/18/09
Product Name: Florikote Controlled Release Magnesium Sulfate
Manufacturer: Florikan ESA Corp./Agrikan Innovative Agriculture

1. Product and Company Description

Florikan ESA Corp./ Agrikan Innovative Agriculture
1579 Barber Road
Sarasota, FL 34240

For Product Information/Emergency:
800-322-8666

Chemical Synonym/Formula:
N/A

2. Hazards Identification

Emergency Overview
Appearance/Odor: Granular solid with some odor.

Potential Health Effects:
Acute Eye:
May cause irritation.

Acute Skin:
May cause irritation.

Acute Inhalation:
May be irritating to respiratory tract.

Acute ingestion:
Not considered a route of exposure under anticipated use conditions. May cause severe irritation
to the digestive tract if ingested.

Chronic Exposure:
Not determined

Aggravation of Pre-existing Conditions:
Not determined




Page 1 of 7
Material Safety Data Sheet
Product: Florikote Controlled Release Magnesium Sulfate


3. Chemical Composition

Component CAS# %Composition
Kieserite 14567-64-7 87-96
Poly(oxypropylene) triol 25791-96-2 2.1-5.6
Polymethylene polyphenylene isocyanate 9016-87-9 < 3.685
Methylene bisphenol isocyanate (MDI) 101-68-8 0.99-2.55
Kaolin 1332-58-7 0-2
Canola oil 120962-03-0 0-1
1,1'-Methylenebis (isocyanato-) benzene 26447-40-5 < .67

4. First Aid Measures

First Aid Measures for Accidental:
Eye Exposure:
Immediately flush eyes with copious amounts of water for at least 15 minutes. If irritation
develops, SEEK MEDICAL ATTENTION.

Skin Exposure:
Flood affected area with water for extended period then wash with vinegar. If irritation develops,
seek medical attention.

Inhalation:
Remove to fresh air. Seek medical attention if breathing becomes difficult.

Ingestion:
Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or
give anything by mouth if the victim is unconscious or having convulsions. Seek medical
attention.

5. Fire Fighting Measures

Fire Hazard Data:
Autoignition: N/A

Flash Point: N/A

Flammability Limits (vol/vol%): Lower: Upper:
N/A N/A


Page 2 of 7
Material Safety Data Sheet
Product: Florikote Controlled Release Magnesium Sulfate

Extinguishing Media:
Use extinguishing media suitable for surrounding fire

Special Fire Fighting Procedures:
None

Unusual Fire and Explosion Hazards:
None

6. Accidental Release Measures

Cleanup and Disposal of Spill:
Vacuum or sweep up material and place in a suitable container for reclamation or disposal. Do not
discharge into drains or sewers. Discard any product, residue, disposable container or liner in full
compliance with federal, state, and local regulations.

7. Handling and Storage

Handling/Storage:
Avoid contact with skin and eyes. Keep in a tightly closed container, stored in a cool, dry, well ventilated
area.

8. Exposure Controls / Personal Protection

Exposure Guidelines:

Component ACGIH NIOSH OSHA-PELs
Kieserite ND ND ND
Poly(oxypropylene) triol ND ND ND
Polymethylene
ND ND ND
polyphenylene isocyanate
0.005 ppm TWA; 0.05
mg/m3 TWA
Methylene bisphenol 0.02 ppm Ceiling;
0.005 ppm TWA 0.020 ppm Ceiling (10
0.2 mg/m3 Ceiling
isocyanate (MDI) min); 0.2 mg/m3 Ceiling
(10 min)
10 mg/m3 TWA
2 mg/m3 TWA (respirable fraction, 10 mg/m3 TWA (total
(total dust); 5
Kaolin particulate matter containing no dust); 5 mg/m3 TWA
mg/m3 TWA
asbestos and <1% crystalline silica) (respirable dust)
(respirable fraction)
Canola oil ND ND ND
1,1'-Methylenebis
ND ND ND
(isocyanato-) benzene




Page 3 of 7
Material Safety Data Sheet
Product: Florikote Controlled Release Magnesium Sulfate

Engineering Controls:
General mechanical ventilation is adequate for normal use. Local exhaust is recommended for confined
areas.

Respiratory Protection:
None

Eye / Face Protection:
None required under anticipated product use conditions.

Skin Protection:
Use gloves to protect hands.

9. Physical and Chemical Properties

Physical Appearance: Granular solid
Odor: Slight
pH: ND
Specific Gravity: >1
Water Solubility: Soluble
Melting Point: NA
Freezing Point NA
Boiling Point: ND
Vapor Pressure: ND
Density: NA
Percent Volatiles by Volume: NA
Evaporation Rate: ND
Viscosity: ND
Density: ND

10. Stability and Reactivity

Chemical Stability:
Stable

Conditions to Avoid:
None

Materials / Chemicals to Be Avoided:
None

Hazardous Decomposition Products:
None

Hazardous Polymerization:
Will not occur.



Page 4 of 7
Material Safety Data Sheet
Product: Florikote Controlled Release Magnesium Sulfate


11. Toxicological Information

Acute Effects
Poly(oxypropylene) triol (25791-96-2)
Oral LD50 Rat: >64 mL/kg; Dermal LD50 Rabbit:>20 mL/kg

Polymethylene polyphenylene isocyanate (9016-87-9)
Inhalation LC50 Rat: 490 mg/m3/4H; Oral LD50 Rat:49 g/kg; Dermal LD50 Rabbit:>9400 mg/kg

Methylene bisphenol isocyanate (MDI) (101-68-8)
Oral LD50 Rat: 9200 mg/kg

1,1'-Methylenebis (isocyanato-) benzene (26447-40-5)
Inhalation LC50 Rat: 0.369 mg/L/4H; Oral LD50 Rat:>7400 mg/kg; Dermal LD50 Rabbit:>6200
mg/kg

Chronic Effects
Carcinogenicity: Polymethylene polyphenylene isocyanate (9016-87-9)
IARC: Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))

Methylene bisphenol isocyanate (MDI) (101-68-8)
IARC: Monograph 71 [1999]; Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))

Kaolin (1332-58-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen

1,1'-Methylenebis (isocyanato-) benzene (26447-40-5)
IARC: Monograph 71 [1999]; Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))

Mutagenicity: No data
Reproductive Effects: No Data
Developmental Effects: No Data

12. Ecological Information

Environmental Fate:
No information found.

Environmental Toxicity:
1,1'-Methylenebis (isocyanato-) benzene (26447-40-5)
Test & Species Conditions
96 Hr EC50 Skeletonema costatum 3230 mg/L




Page 5 of 7
Material Safety Data Sheet
Product: Florikote Controlled Release Magnesium Sulfate

13. Disposal Considerations

Waste Disposal Method:
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved
waste disposal facility. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transportation Information

US Department of Transportation Shipping Name:

US Department Proper Shipping
Not Regulated
of Name
Transportation Not Regulated
Hazard Class
Not Regulated
ID Number
Not Regulated
Packaging Group

15. Regulatory Information

Federal Regulations:

SARA Title III Hazard Classes:
Fire Hazard: No
Reactive Hazard: No
Release of Pressure: No
Acute Health Hazard: No
Chronic Health Hazard: No

TSCA
All components of this product are on the TSCA inventory or are exempt from TSCA Inventory
requirements

Other Regulations:
None

16. Other Information

National Paint & Coating Hazardous Materials Identification System ?HMIS(R):

Health Hazard: 1
Flammability: 0
Reactivity: 0


Page 6 of 7
Material Safety Data Sheet
Product: Florikote Controlled Release Magnesium Sulfate
TLV ?Threshold Limit Value
Key Legend Information:
PEL ?Permissible Exposure Limit
NA ?Not Applicable
TWA ?Time Weighted Average
ND ?Not Determined
STEL ?Short Term Exposure Limit
ACGIH ?American Conference of Governmental
NTP ?National Toxicology Program
Industrial Hygienists
IARC ?International Agency for Research on Cancer
OSHA ?Occupational Safety and Health
Administration




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