3M General Offices
3M Center
St. Paul, MN 55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
7/11/2009 7:34:20 AM
Material Safety Data Sheet
Purchase Order #: 398106
Customer Number: MFR6696
ACCTS PAYABLE DEPT
KELLOGG MARINE INC
5 ENTERPRISE DR
OLD LYME, CT 06371-1568
United States of America
Dear ACCTS PAYABLE DEPT
Enclosed is the Material Safety Data Sheet (MSDS) for the product that your company recently purchased from 3M
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
Material Safety Data Sheet
Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534,
06535
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 07/07/09
Supercedes Date: 08/08/07
Document Group: 16-5850-9
Product Use:
Specific Use: Adhesive Sealant for fiberglass and wood.
Intended Use: Sealant
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
Urethane Polymer 51447-37-1 40 - 70
Titanium Dioxide 13463-67-7 10 - 30
Fumed Silica 7631-86-9 1 - 10
Zinc Oxide 1314-13-2 1- 5
p,p'-Methylenebis(Phenyl Isocyanate) 101-68-8 < 2.5
Diethylene Glycol Monoethyl Ether Acetate 112-15-2 < 2.5
Alumina Trihydrate 21645-51-2 < 2.5
Alkyl Isocyanate Silane 85702-90-5 <2
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
Odor, Color, Grade: White thixotropic paste, slight odor
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause allergic
respiratory reaction.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or
hazy vision.
Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Target Organ Effects:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Ventilate the area with fresh air. Avoid contact with water. Pour isocyanate decontaminant solution (90%
water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react
for more than 30 minutes. Cover with absorbent material. Place in a container approved for transportation by appropriate authorities,
but do not seal the container for 48 hours to avoid pressure build-up. Collect as much of the spilled material as possible. Collect the
resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
7.1 HANDLING
Avoid eye contact. Avoid skin contact. Avoid breathing of vapors. Do not eat, drink or smoke when using this product. Wash
exposed areas thoroughly with soap and water. Do not ingest. Avoid breathing of dust created by cutting, sanding, grinding or
machining. Keep out of the reach of children.
7.2 STORAGE
Store in a cool place. Store away from heat. Store out of direct sunlight. Keep container tightly closed.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not
use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to
control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is
not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Nitrile Rubber, Polyvinyl Alcohol (PVA).
8.2.3 Respiratory Protection
Avoid breathing of vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with formaldehyde cartridges and N95 particulate prefilters.
Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
FREE ISOCYANATES 3M TWA 0.005 ppm
FREE ISOCYANATES 3M STEL 0.02 ppm
p,p'-Methylenebis(Phenyl Isocyanate) ACGIH TWA 0.005 ppm
p,p'-Methylenebis(Phenyl Isocyanate) OSHA CEIL 0.02 ppm Table Z-1
Fumed Silica CMRG TWA, as respirable 3 mg/m3
dust
Titanium Dioxide ACGIH TWA 10 mg/m3 Table A4
Titanium Dioxide CMRG TWA, as respirable 5 mg/m3
dust
Titanium Dioxide OSHA TWA, Vacated, as 10 mg/m3
dust
Titanium Dioxide OSHA TWA, as total dust 15 mg/m3 Table Z-1
Zinc Oxide ACGIH TWA, respirable 2 mg/m3
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
Zinc Oxide ACGIH STEL 10 mg/m3
Zinc Oxide OSHA TWA, as fume 5 mg/m3 Table Z-1
Zinc Oxide OSHA TWA, respirable 5 mg/m3 Table Z-1
Zinc Oxide OSHA STEL, Vacated, as 10 mg/m3
fume
Zinc Oxide OSHA TWA, Vacated, as 10 mg/m3
dust
Zinc Oxide OSHA TWA, as total dust 15 mg/m3 Table Z-1
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
White thixotropic paste, slight odor
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
Boiling point
No Data Available
Vapor Density
No Data Available
Vapor Pressure
1.3 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
Not Applicable
Melting point
Nil
Solubility in Water
No Data Available
Evaporation rate
0.024 lb HAPS/lb solids
Hazardous Air Pollutants
40 g/l [Test Method: tested per EPA method 24]
Volatile Organic Compounds
2.94 % weight
Percent volatile
40 g/l [Test Method: tested per EPA method 24]
VOC Less H2O & Exempt Solvents
100000 - 500000 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Amines; Alcohols; Water
Hazardous Polymerization: Hazardous polymerization will not occur.
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
Hazardous Decomposition or By-Products
Substance Condition
Isocyanates During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Cyanide During Combustion
Oxides of Nitrogen During Combustion
Toxic Vapor, Gas, Particulate During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Cure (harden, set, or react) the product according to product instructions.
Dispose of waste product in a sanitary landfill. Dispose of completely cured (or polymerized) wastes in a sanitary landfill.
Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, incinerate in
an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, incinerate uncured product in
an industrial or commercial incinerator. As a disposal alternative, incinerate uncured product in an industrial or commercial
incinerator in the presence of a combustible material.
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9800-4557-3, 60-9800-4558-1, 60-9800-4562-3, 60-9801-0557-5, 62-5239-0330-0, 62-5239-0334-2, FS-9100-3615-1, FS-9100-
3648-2, LB-T000-0007-0
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
p,p'-Methylenebis(Phenyl Isocyanate) 101-68-8 < 2.5
(Diisocyanates (EPCRA 313))
Zinc Oxide (ZINC COMPOUNDS) 1314-13-2 1- 5
Diethylene Glycol Monoethyl Ether Acetate 112-15-2 < 2.5
(GLYCOL ETHERS)
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product name was modified.
Section 16: NFPA hazard classification for flammability was modified.
Section 1: Division name was modified.
Copyright was modified.
Section 3: Potential effects from skin contact information was modified.
Section 3: Potential effects from inhalation information was modified.
Section 5: Unusual fire and explosion hazard information was modified.
Section 7: Handling information was modified.
Section 7: Storage information was modified.
Section 8: Eye/face protection phrase was modified.
Section 8: Skin protection phrase was modified.
Section 8: Respiratory protection information was modified.
Section 8: Prevention of swallowing information was modified.
Section 8: Skin protection - recommended gloves information was modified.
Page Heading: Product name was modified.
Section 15: 311/312 Reactivity Hazard score was modified.
Section 15: 311/312 Delayed Hazard score was modified.
Section 15: Inventories information was modified.
Section 8: Respiratory protection - recommended respirators information was added.
Section 8: Respiratory protection - recommended respirators was added.
Section 8: Respiratory protection - recommended respirators guide was added.
Section 8: Respiratory protection - recommended respirators punctuation was added.
Section 14: ID Number Heading Template 1 was added.
Section 14: ID Number(s) Template 1 was added.
Section 2: Ingredient table was added.
Section 15: EPCRA 313 information was added.
Section 15: EPCRA 313 text was added.
Section 8: Exposure guidelines ingredient information was added.
Section 8: Exposure guidelines legend was added.
Section 8: Exposure guidelines data source legend was added.
Section 15: WHMIS regulations heading was deleted.
Section 15: WHMIS regulations information was deleted.
Section 3: Carcinogenicity phrase was deleted.
Section 3: Immediate other hazard(s) was deleted.
Section 15: California proposition 65 reproductive harm warning was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
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MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200, White; PN 06520 , 05220, 06534, 06535
07/07/09
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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