Material Safety Data Sheet
EUCOLASTIC/NEO SEAL PRIMER
Version 2. Print Date 06/10/2009
REVISION DATE: 06/08/2009
SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION
Product Information
Trade name : EUCOLASTIC/NEO SEAL PRIMER
Product code : 073R 94
Supplier : Euclid Canada
2835 Grande-All閑
St-Hubert, QC J4T 2R4
Telephone : 1-800-667-0920
Emergency Phone: : (613) 996-6666
Product use : Primer
Preparation Information
Prepared by: : Sewnauth Raghunandan
Date: : 06/08/2009
Telephone : (416) 421-3300
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
Clear. Liquid. May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and throat. May
cause moderate irritation to the respiratory system. May cause allergic respiratory sensitization. Move to fresh air.
If required, artificial respiration or administration of oxygen can be performed by trained personnel. Leave area to
breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause drowsiness, weakness, and fatigue. Vapor and/or mist may irritate nose and
:
throat. May cause moderate irritation to the respiratory system. May cause allergic
respiratory sensitization.
Eyes Vapor and/or mist may cause eye irritation.
:
Ingestion May cause irritation to the mouth, throat and stomach. May cause gastrointestinal irritation,
:
nausea, and vomiting.
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Pre-existing eye, skin, liver, kidney, and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.
Repeated overexposure to vapors and/or material may injure the liver, kidneys and respiratory system unless
suitable engineering controls and/or personal protective equipment are used. Prolonged or repeated exposure to
xylene may cause defatting, drying, and irritation of the skin, dermatitis, central nervous system (CNS) effects,
heart muscle sensitization and arrhythmia, hearing loss, and brain, liver, kidney damage. Xylene overexposure
may affect fetal development. Prolonged or repeated contact/exposure to aromatic petroleum distillates may
cause defatting, drying, and irritation of the skin, dermatitis, and central nervous system (CNS) effects. The
1/6 073R 94
Material Safety Data Sheet
EUCOLASTIC/NEO SEAL PRIMER
Version 2. Print Date 06/10/2009
REVISION DATE: 06/08/2009
International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and classified it as a possible
human carcinogen (Group 2B) based on sufficient evidence for carcinogenicity in experimental animals, but
inadequate evidence for cancer in exposed humans. A long-term NTP study showed that oral exposure to toluene
diisocyanate (TDI) caused cancer in rats and mice. A lifetime inhalation study sponsored by the International
Isocyanate Institute did not show carcinogenic activity in rats. May cause allergic skin and respiratory
sensitization. Fillers are encapsulated and not expected to be released from product under normal conditions of
use.
Target Organs: Eye, Lung, Liver, Kidney, Skin, Nerve
SECTION 3 : HAZARDOUS INGREDIENTS
Chemical Name CAS-No. Weight % Range
Aromatic petroleum distillates 64742-95-6 15.0 - 40.0
1,2,4-Trimethylbenzene 95-63-6 15.0 - 40.0
Xylene 1330-20-7 7.0 - 13.0
1,3,5-Trimethylbenzene 108-67-8 3.0 - 7.0
Ethylbenzene 100-41-4 1.0 - 5.0
Diethylbenzene, Mixed Isomers 25340-17-4 1.0 - 5.0
2,4-Toluene diisocyanate 584-84-9 0.1 - 1.0
4,4'-Methylene bis(phenylisocyanate) 101-68-8 0.1 - 1.0
The ingredients listed above are hazardous as defined in the controlled products regulation. (CPR).
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Move to fresh air. If required, artificial respiration or administration of oxygen can be
performed by trained personnel.Leave area to breathe fresh air. Avoid further
overexposure. If symptoms persist, get medical attention.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5: FIRE / EXPLOSION HAZARDS
Flash point : 94 ?34 ?br>
F, C
Method : Setaflash Closed Cup
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
2/6 073R 94
Material Safety Data Sheet
EUCOLASTIC/NEO SEAL PRIMER
Version 2. Print Date 06/10/2009
REVISION DATE: 06/08/2009
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Smoke,
products fumes.Hydrocyanic acid and nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
Fire and explosion conditions : Product may ignite if heated in excess of its flash point.Closed container,
may burst when exposed to extreme heat.Empty containers may contain
ignitable vapors.Vapors may travel to sources of ignition and flashback.
SECTION 6 - SPILLS / LEAKS / ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Remove sources of ignition immediately.
Stop flow of material if safe to do so. Contain spill and keep out of water courses. Ventilate area.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion, and contact with skin eyes and clothing. Keep container closed when not
in use. Precautions also apply to emptied containers. Change soiled work clothes frequently. Clean hands
thoroughly after handling. Do not smoke, weld, generate sparks, or use flame near container. To prevent
generation of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignition
sources including pilot lights, non-explosion proof motors and electrical equipment until vapors dissipate. Store
under dry warehouse conditions away from heat and all ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved respirator when
airborne contaminant level(s) are expected to exceed exposure limits indicated
on the MSDS. Select positive pressure supplied air respirator (TC19C or
equivalent) for isocyanates.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
shield to prevent eye contact. Do not wear contact lenses. Do not touch eyes
with contaminated body parts or materials. Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use only in well ventilated areas. Provide maximum ventilation in enclosed
areas.Use local exhaust when the general ventilation is inadequate.
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
1,2,4-Trimethylbenzene 95-63-6 Ontario TWAEV: 123 mg/m3
ACGIH TWA: 25 ppm
3/6 073R 94
Material Safety Data Sheet
EUCOLASTIC/NEO SEAL PRIMER
Version 2. Print Date 06/10/2009
REVISION DATE: 06/08/2009
Chemical Name CAS Number Regulation Limit Form
Xylene 1330-20-7 Ontario TWAEV: 435 mg/m3
Ontario STEV: 650 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 150 ppm
1,3,5-Trimethylbenzene 108-67-8 Ontario TWAEV: 123 mg/m3
ACGIH TWA: 25 ppm
Ethylbenzene 100-41-4 Ontario TWAEV: 435 mg/m3
Ontario STEV: 540 mg/m3
ACGIH TWA: 100 ppm
ACGIH STEL: 125 ppm
2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm
Ontario TWAEV: 0.005 ppm
4,4'-Methylene 101-68-8 Ontario TWAEV: 0.005 ppm
bis(phenylisocyanate) ACGIH TWA: 0.005 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State : Liquid
Form : Liquid
Color : Clear
Odor : Solvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : > 250 ?> 121 ?br>
F, C
Water solubility : Negligible
Evaporation Rate: : Not available.
Specific Gravity : 0.96
% Volatile Weight : 58 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Strong acids.Strong bases.Amines.Water or moisture.Alcohols.
Stability : Material is stable under normal storage, handling, and use.
4/6 073R 94
Material Safety Data Sheet
EUCOLASTIC/NEO SEAL PRIMER
Version 2. Print Date 06/10/2009
REVISION DATE: 06/08/2009
Hazardous polymerization : Will not occur under normal conditions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Xylene, CAS-No.: 1330-20-7
Acute oral toxicity (LD-50 oral) 4,300 mg/kg ( Rat ) 1,590 mg/kg ( Mouse ) 6,670 mg/kg ( Rat
) 3,523 - 8,600 mg/kg ( Rat ) 5,627 mg/kg ( Mouse )
Acute inhalation toxicity (LC-50) 6,350 mg/l for 4 h ( Rat ) 3,907 mg/l for 6 h ( Mouse ) 8,000
mg/l for 4 h ( Rat )
Ethylbenzene, CAS-No.: 100-41-4
Acute oral toxicity (LD-50 oral) 5,460 mg/kg ( Rat ) 3,500 mg/kg ( Rat )
Acute dermal toxicity (LD-50 dermal) 17,800 mg/kg ( Rabbit )
2,4-Toluene diisocyanate, CAS-No.: 584-84-9
Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 14 mg/l for 4 h ( Rat ) 10 mg/l for 4 h ( Mouse ) 13 mg/l for 4 h
( Guinea pig ) 11 mg/l for 4 h ( Rabbit )
4,4'-Methylene bis(phenylisocyanate), CAS-No.: 101-68-8
Acute inhalation toxicity (LC-50) 0.369 mg/l for 4 h ( Rat ) 0.38 mg/l for 4 h ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Disposal Method : Dispose as hazardous waste according to all local, state, federal and provincial
regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
ADHESIVES, 3, UN1133, PG III
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
One or more components are listed on the NDSL.
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Material Safety Data Sheet
EUCOLASTIC/NEO SEAL PRIMER
Version 2. Print Date 06/10/2009
REVISION DATE: 06/08/2009
Canadian Regulations:
WHMIS Classification : B2, D2A, D2B
This is a "controlled product" under the Canadian Workplace Hazardous Materials Information System (WHMIS).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Other Regulations:
Regulatory VOC (less water and : 559 g/l
exempt solvent)
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 3
2 = Moderate
Reactivity 2
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Sewnauth Raghunandan
Legend
ACGIH - American Conference of Governmental Hygienists OSHA - Occupational Safety and Health Administration
DOT - Department of Transportation PEL - Permissible Exposure Limit
DSL - Domestic Substance List RCRA - Resource Conservation and Recovery Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
NTP - National Toxicology Program WHMIS - Workplace Hazardous Materials Information System
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