MATERIAL SAFETY DATA SHEET
EPOXY REPAIR MATERIALS, EPOXY ADHESIVES, RIGID URETHANE FOAM & Job Size MINI TWIN SYSTEM
10/20/05
PRODUCTS COVERED
EPOXY REPAIR MATERIALS & ADHESIVES: CE-CB, CE-PB, CE-RL, CE-SS, CE-SU, CZTEC, RE-A, TE-R1&2, TP-E1&2
RIGID URETHANE FOAM: CF-R, Job Size MINI TWIN SYSTEM: CX-B, CX-F, CX-P, CX-Q, CX-R
SECTION I MANUFACTURER
Crest Industries, Inc., 1337 King Road, Trenton, MI 48183 Phone: (734) 479-4141 FAX: (734) 479-4040
24 HOUR EMERGENCY TELEPHONE (CHEMTEL): (800) 255-3924 INTERNATIONAL CALLS: (813) 248-0585
SECTION II PRODUCTS
Numbers of HMIS
Stock Ingredients RATING
Number Product Name on Label in Products H F R Appearance and Odor
Epoxy Repair Materials & Adhesives
CE-CB CODE BLUE 1,8,11,22,26,38 3* 1 0 Blue viscous liquid, floral odor
CE-PB PANEL BONDER 3500 1,2,7,12,13,14 3 1 0 Black liquid, mercaptan odor
CE-RL RED LINE 1,8,11,22,26,38 3* 1 0 Red viscous liquid, floral odor
CE-SS EPOXY SEAM SEALER 1,9,10,29,32 3 1 0 Yellow liquid, mercaptan odor
CE-SU ULTRA-VIS II 1,10,11,28,29,32 3 1 0 Yellow liquid, mercaptan odor
CZTEC QUICK SET 5,20 3 1 0 Very light yellow liquid, mercaptan odor
RE-A AUTOMOTIVE QUICKSTEEL 1,24 1 0 0 Dark Gray putty stick, no odor
TE-R1 RIGID RED Resin 8,11,22,26,30,38 3* 1 0 Gray-White, very viscous liquid, bland odor
TE-R2 RIGID RED Hardener 1,11,22,25,26,35 3* 1 0 Red, very viscous liquid, floral odor
TP-E1 TWO PART EPOXY Resin 8,11,22,26,30,38 3* 1 0 White, very viscous liquid, bland odor
TP-E2 TWO PART EPOXY Hardener 1,11,22,25,26,35 3* 1 0 Blue, very viscous liquid, floral odor
Rigid Urethane Foam:
CF-R RIGI-FOAM 15,24,27,31 3 1 0 Brown liquid, bland odor
Job Size Mini Twin System
CX-B BlaxTer 1,4,10,11,28,29,33 3* 1 0 Black liquid, mercaptan odor
CX-F FlexiFoam 6,17,18,27,34,37 3 1 0 Black liquid, bland odor
CX-P PlasTer 1,3,10,11,16,19,23,
29,33,38,39 3* 1 0 Gray liquid, mercaptan odor
CX-Q QwixTer 19,33,36 3 1 0 Clear liquid, mercaptan odor
CX-R RigiFoam 15,24,27,31 3 1 0 Light brown liquid, bland odor
*Chronic health effects are possible. See SECTION VI HEALTH HAZARD DATA.
VOC CONTENT
Stock Number Pounds per Gallon Grams per Liter Pounds per Package
CE-SS, CE-SU 0.04 4.8 0.0031
All Others 0 0 0
SECTION III HAZARDOUS INGREDIENTS
Exposure Limits in
Abbreviations
Ingredients CAS Number ppm (parts per million)
A means ACGIH Threshold
1. 2,4,6-Tri(Dimethylaminomethyl) Phenol 90-72-2 Not Established
Limit Value (TLV),
2. 3,3 -(Oxybis(2,1-Ethanediyloxy))BIS-
O means OSHA Permissible
1-Propanamine 4246-51-9 Not Established
Exposure Limit (PEL),
3. 3-Triethoxysilyl 1-Propanamine 919-30-2 Not Established
4. Amine/Mercaptan Blend Mixture Not Established > means greater than,
5. Amine/Mercaptan Hardener 122-60-1 Not Established R means Respirable fraction,
6. Amine Salts Mixture Not Established Skin means exposure to the
3
7. Amorphous Silica** 60676-86-0 0.1 mg/m A Dust skin must be considered.
8. Bisphenol A Epoxy Resin 25085-99-8 Not Established **These materials only contrib-
9. Bisphenol A Epoxy Resin Mixture Mixture Not Established ute to the hazard if the cured
10. Bisphenol A Polyglycidyl Ether 25068-38-6 Not Established
material is sanded and dust is
3
11. Calcium Carbonate** 1317-65-3 10 mg/m A Dust
inhaled.
3
12. Carbon Black** 1333-86-4 3.5 mg/m A,0
13. Colloidal Silica** 97762-90-7 Not Established
NOTE: All listed ingredients are present
3
14. Crystalline Silica (Cristobalite)** 14464-46-1 0.05 mg/m A,0 R
in the products at unknown percentages
15. Dibromoneopentylene Glycol Unknown Not Established
greater than 1.
3
16. Dibutyl Phthalate 84-74-2 5 mg/m
3
17. Dibutyltin Dilaurate (As Tin) 77-58-7 0.1 mg/m (Skin) DISCLAIMER: The information contained
18. Dipropylene Glycol 25265-71-8 Not Established in this MSDS is believed to be accurate
19. Epoxy NOVOLAC Resin 28064-14-4 Not Established and reliable as of the date indicated.
20. Epoxy Resin 2238-07-5 Not Established Crest Industries, Inc. assumes no legal
21. Epoxy Resin (Diglycidyl Ether of Bisphenol A) 25068-38-6 Not Established responsibility and makes no representa-
3
22. Fumed Silica** 7631-86-9 10 mg/m A Dust tion, warranty or guarantee, expressed or
23. Glycidoxypropyl-Trimethoxy Silane 2530-83-8 Unknown implied, as to the completeness or accu-
24. Isocyanate Prepolymer Mixture Not Established racy of the information. It is offered solely
25. Liquid Polymercaptan CAS Unknown Not Established for your consideration, investigation and
3
26. Magnesium Silicate** 14807-96-6 2 mg/m A Dust verification. The user is ultimately respon-
27. Methylene bisphenyl isocyanate 101-68-8 0.005 ppm A sible for the safe use of the material in
28. Modified Bisphenol Resin Mixture Not Established accordance with applicable federal, state,
provincial and local laws and regulations.
29. Modified Diglycidyl Ether 68909-14-8 Not Established
30. Nonyl Phenol 25154-52-3 Not Established
31. Polyether Polyol Mixture Not Established
EPOXY REPAIR MATERIALS, EPOXY ADHESIVES, RIGID URETHANE FOAM & Job Size MINI TWIN SYSTEM MSDS 10/20/05 page 2
SECTION III HAZARDOUS INGREDIENTS (CONTINUED FROM Page 1)
Exposure Limits in
Ingredients CAS Number ppm (parts per million)
32. Polymercaptan Resin Trade Secret Not Established
33. Polymercaptan Resin Proprietary Not Established
34. Polymethylene Polyphenyl Isocyanate 9016-87-9 Not Established
10 mg/m3 A Dust
35. Sodium Borosilicate Glass** Mixture
36. Tertiary Amine Proprietary Not Established
37. Tertiary Amine Mixture Not Established
10 mg/m3 A Dust
38. Titanium Dioxide** 13463-67-7
39. Triethylenediamine 280-57-9 Not Established
SECTION VIII EMPLOYEE PROTECTION
SECTION IV PHYSICAL DATA
RECOMMENDATIONS
Product Density (water = 1): >1. Solubility in Water: <1%
EYE PROTECTION: Wear safety glasses.
Vapor Density: Not Applicable
SKIN PROTECTION: Wear chemical resistant gloves
SECTION V FIRE AND EXPLOSION DATA
D.O.T. Flammability Class: Non Flammable Flash Point (Pensky- (polyethylene or rubber). Cover as much of the skin as possible
Martin Closed Cup Method) All Stock Numbers: >200癋 (>93癈). with appropriate clothing.
Vapor Pressure (mm Hg at 20癈): Not Applicable Evaporation Rate VENTILATION AND RESPIRATORY PROTECTION: Due to the low
(n-Butyl Acetate=1): Not Applicable Boiling Point: Not Applicable volatility of these products respiratory protection is not normally nec-
Flammable Limits in %: Not Applicable Autoignition Point: Not Ap- essary unless proper ventilation is impossible. NOTE: Always wear a
plicable Extinguishing Media: Water, foam, carbon dioxide, dry dust mask when sanding any of the products on this MSDS. Observe
chemical. Special Fire Fighting Procedures: Full protective equip- OSHA regulations (29 CFR 1910.134) for dust mask use.
ment, including self-contained breathing apparatus is recommended. OTHER PROTECTIVE MEASURES: Eyewash stations should be
During a fire highly toxic gasses may be generated by combustion or available. Educate and train employees in safe use of products. Fol-
thermal decomposition low all label instructions. Persons with recurrent skin eczema or sensi-
Unusual Fire and Explosion Hazards: None tization should be excluded from working with these materials unless
SECTION VI HEALTH HAZARD DATA protective gloves are worn.
PRIMARY ROUTES OF EXPOSURE: Skin and eye contact. SECTION IX REACTIVITY DATA
SIGNS AND SYMPTOMS OF EXPOSURE: STABILITY: Stable under normal room conditions.
SKIN CONTACT: HAZARDOUS POLYMERIZATION: Not Applicable
Acute Exposure: Skin irritation resulting in reddening, swelling, INCOMPATIBILITY (Materials to Avoid): Resins: strong amines,
rash, scaling or blistering. Some persons may develop skin sensitiza- acids, bases and oxidizing agents. Hardeners: Strong oxidizing
tion. Cured material is difficult to remove. Chronic Exposure: Pro- agents. CONDITIONS TO AVOID: Excessive heat buildup will result
longed contact can cause reddening, swelling, rash, scaling or blister- from mixing more than one pound (total weight) of resin and hardener.
ing. In sensitized persons these symptoms may occur as a result of HAZARDOUS DECOMPOSITION PRODUCTS: By high heat and fire:
carbon dioxide, carbon monoxide, oxides of nitrogen, hydrocarbon
contact with very small amounts of product.
fumes, sulfur oxides, soot and smoke.
EYE CONTACT:
SECTION X SPILL OR LEAK PROCEDURES
Acute Exposure: Product is irritating and can cause tearing, red-
dening and swelling accompanied by pain. Chronic Exposure: As in STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR
SPILLED: Prevent further spillage. Scrape or wipe up material.
acute exposure but to a lesser degree.
WASTE DISPOSAL METHOD: Follow all federal, state and local
INHALATION:
environmental control regulations. Incineration of the materials is the
Acute Exposure: Unlikely due to low volatility of the products.
preferred method. Cured material may be put in household trash.
Chronic Exposure: Unlikely.
RCRA STATUS: Since these products are toxic they are hazardous
INGESTION:
Acute Exposure: Irritation and possible corrosive action in the when discarded.
SECTION XI SPECIAL PRECAUTIONS &
mouth and, if swallowed, esophagus, stomach and intestinal tract.
STORAGE DATA
Chronic Exposure: Unknown.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin al- STORAGE TEMPERATURE:
MINIMUM / MAXIMUM: 50癋 (10癈) / 120癋 (49癈)
lergies, eczema and eye diseases may be aggravated by overexpo-
RECOMMENDED SHELF LIFE: One year
sure to these products.
CARCINOGENICITY: Ingredients not listed by NTP or OSHA. NOTE: PRECAUTIONS TO BE TAKEN IN HANDLING, STORAGE AND
IARC has determined that Crystalline Silica (Quartz and Cristobalite) USE: Do not store in temperatures above 120癋 (49癈) or in direct
are carcinogenic. 11. Calcium Carbonate and 26. Magnesium Sili- sunlight. Avoid contact with skin and eyes. Wash hands after use and
cate contain small but detectable amounts of Crystalline Silica. Quartz before eating, drinking, smoking or using the toilet. Employee educa-
and Cristobalite, if inhaled, can cause Lung fibrosis and Silicosis that tion and training in the safe use and handling of these products is re-
may result in cancer of the lungs. Under normal use conditions the quired under the OSHA Hazard Communication Standard (29CFR
1910.1200).
Quartz and Cristobalite are not free to be inhaled as dust.
SECTION XII CALIFORNIA PROPOSITION 65
WARNING: If the cured CE-CB, CE-PB, CE-RL, CE-SU, TE-R, TP-E,
WARNINGS
CX-B and CX-P are sanded, inhalation of the sanding dust must be
According to the California Safe Drinking Water and Toxic Enforce-
avoided. WEAR A DUST MASK.
ment Act (PROPOSITION 65) "No person in the course of doing busi-
SECTION VII EMERGENCY AND FIRST
ness shall knowingly and intentionally expose any individual to a
AID PROCEDURES
SKIN CONTACT: Remove contaminated clothing immediately. Wash chemical known to the State of California to cause cancer, birth de-
affected areas thoroughly with soap and water. Wash contaminated fects or reproductive toxicity without first giving clear and reasonable
clothing thoroughly before reuse. Seek medical attention if irritation warning to such individuals of such an exposure". WARNING: CE-CB,
CE-PB, CE-RL, CE-SU, TE-R, TP-E, CX-B and CX-P contain a chemi-
develops or persists.
EYE CONTACT: Flush with clean, lukewarm water (low pressure) for cal known to the State of California to cause cancer.
SECTION XIII VOLATILE ORGANIC COMPOUND
at least 15 minutes while lifting eyelids. Refer person to physician for
(V.O.C.) CONTENT ACCORDING TO
immediate attention.
THE FEDERAL EPA
INGESTION: Give two glasses of water and consult physician, hospi-
See SECTION II.
tal emergency room or poison control center immediately. Have list of
SECTION XIV OZONE DEPLETION IN THE
ingredients available. Do not induce vomiting!
UPPER ATMOSPHERE
INHALATION: Not Applicable
No upper atmosphere ozone depleting substances are contained in
these products.
KEEP OUT OF THE REACH OF CHILDREN!
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