Page 1/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
* 1 Identification of substance:
?Product details:
?Trade name: PYTHON WRAP 30207
?Article number: 30207
?Application of the substance / the preparation
Sealant
Resin
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation:
@
?
G Xn Harmful
?Information pertaining to particular dangers for man and environment
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42/43 May cause sensitisation by inhalation and skin contact.
Contains isocyanates. See information supplied by the manufacturer
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
~
Danger
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
~
Warning
H335+H336 - May cause respiratory irritation. May cause drowsiness or dizziness.
Warning
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H317 - May cause an allergic skin reaction.
Contains isocyanates. May produce an allergic reaction.
?Prevention:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P285 In case of inadequate ventilation wear respiratory protection.
GB
(Contd. on page 2)
Page 2/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: PYTHON WRAP 30207
(Contd. of page 1)
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Resin mixture with colouring agents.
?Dangerous components:
CAS: 9016-87-9 diphenylmethanediisocyanate,isomeres and homologues 5-10%
@
? Xn, ? Xi; R 20-36/37/38-40-42/43-48/20
G G
@
Danger: ~ 3.4.R/1
Warning: ~ 3.1.I/4, 3.8/3; 3.2/2, 3.3/2, 3.4.S/1
CAS: 101-68-8 diphenylmethane-4,4'-di-isocyanante 1-5%
EINECS: 202-966-0 ? Xn, ? Xi; R 20-36/37/38-40-42/43-48/20
@
G G
@
Danger: ~ 3.4.R/1
Warning: ~ 3.1.I/4, 3.8/3; 3.2/2, 3.3/2, 3.4.S/1
* 4 First aid measures
?General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Instantly remove any clothing soiled by the product.
?After inhalation
Take affected persons into the open air and position comfortably
Seek medical treatment.
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing
Do not induce vomiting; instantly call for medical help.
Rinse out mouth and then drink plenty of water.
* 5 Fire fighting measures
?Suitable extinguishing agents
Carbon dioxide
Foam
Fire-extinguishing powder
Water haze
?Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
Hydrogen cyanide (HCN)
?Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
?Additional information
Cool endangered containers with water spray jet.
Collect contaminated fire fighting water separately. It must not enter drains.
* 6 Accidental release measures
?Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
?Measures for environmental protection:
No special measures required.
Do not allow to enter drainage system, surface or ground water.
?Measures for cleaning/collecting:
Collect mechanically.
(Contd. on page 3)
GB
Page 3/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: PYTHON WRAP 30207
(Contd. of page 2)
Send for recovery or disposal in suitable containers.
Dispose of contaminated material as waste according to item 13.
* 7 Handling and storage
?Handling
?Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
?Information about protection against explosions and fires: No special measures required.
?Storage
?Requirements to be met by storerooms and containers: Store in cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Protect from humidity and keep away from water.
Store in cool, dry conditions in well sealed containers.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
diphenylmethanediisocyanate,isomeres and homologues
WEL Short-term value: 0.07 mg/m?br>
Long-term value: 0.02 mg/m?br>
Sen; as -NCO
diphenylmethane-4,4'-di-isocyanante
WEL Short-term value: 0.07 mg/m?br>
Long-term value: 0.02 mg/m?br>
Sen; as -NCO
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Take off immediately all contaminated clothing
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
?Breathing equipment: Use breathing protection in case of insufficient ventilation.
?Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
Butyl rubber, BR
Nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer.
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Safety glasses
?Body protection: Protective work clothing.
* 9 Physical and chemical properties:
?General Information
Form: Solid.
(Contd. on page 4)
GB
Page 4/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: PYTHON WRAP 30207
(Contd. of page 3)
Colour: Whitish
Odour: Odourless
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
?Flash point: Not applicable
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive.
?Density at 20癈 1.220 g/cm3
?Solubility in / Miscibility with
Water: Unsoluble
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: Stable at ambient temperature
?Dangerous reactions
Reacts with alcohols
Reacts with amines
Reacts with water
Reacts with alkali (lyes)
?Dangerous products of decomposition: No dangerous decomposition products known
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
diphenylmethanediisocyanate,isomeres and homologues
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >5000 mg/kg (rabbit)
Inhalative LC50/4 h 0.49mg/l mg/l (rat)
diphenylmethane-4,4'-di-isocyanante
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >5000 mg/kg (rabbit)
Inhalative LC50/4 h 0.49 mg/l (rat)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritant effect.
?Sensitization:
Sensitization possible by skin contact.
Sensitization possible by inhalation.
?Additional toxicological information:
Harmful
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
?Sensitisation May cause sensitisation by inhalation and skin contact.
* 12 Ecological information:
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
GB
(Contd. on page 5)
Page 5/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: PYTHON WRAP 30207
(Contd. of page 4)
* 13 Disposal considerations
?Product:
?Recommendation
Can be deposited with household garbage after consulting with the operator of the waste disposal facility and the pertinent
authorities and under adherence to the necessary technical regulations.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: n/a
?Maritime transport IMDG:
?IMDG Class: n/a
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: n/a
?UN "Model Regulation": n/a
* 15 Regulatory information
?Designation according to EC guidelines: Observe the normal safety regulations when handling chemicals
?Code letter and hazard designation of product:
@
?
G Xn Harmful
?Hazard-determining components of labelling:
diphenylmethanediisocyanate,isomeres and homologues
diphenylmethane-4,4'-di-isocyanante
?Risk phrases:
36/37/38 Irritating to eyes, respiratory system and skin.
42/43 May cause sensitisation by inhalation and skin contact.
?Safety phrases:
23 Do not breathe fumes.
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37 Wear suitable gloves.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
60 This material and its container must be disposed of as hazardous waste.
?Special designation of certain preparations:
Contains isocyanates. See information supplied by the manufacturer
?National regulations
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
20 Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
(Contd. on page 6)
GB
Page 6/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 09.11.2009 Revision: 28.09.2009
Trade name: PYTHON WRAP 30207
(Contd. of page 5)
40 Limited evidence of a carcinogenic effect.
42/43 May cause sensitisation by inhalation and skin contact.
48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
?Department issuing data specification sheet: Environment protection department.
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
?Data compared to the previous version altered. sections: all
GB
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