M A T E R I A L __ S A F E T Y __ D A T A __ S H E E T
Page: 1
PRODUCT NAME: DriTac 7600 HMIS CODES: H F R
221
================== SECTION I - MANUFACTURER IDENTIFICATION =================
MANUFACTURED FOR : BASIC ADHESIVES, INC. ADDRESS : 25 KNICKERBOCKER AVE BROOKLYN,
NY 11237
EMERGENCY PHONE : (800)-424-9300 EFFECTIVE DATE : 05/14/04
INFORMATION PHONE : (800) 394-9310
========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP PERCENT
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* POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 <0.00001 77 F 0 - 10%
CONTAINED IN THIS POLYMERIC MDI PRODUCT IS 4,4'-DIPHENYLMETHANE
DIISOCYANATE, CAS# 101-68-8, UPPER BOUND 20%.
OSHA PEL: 0.02 PPM CEILING 0.02 MG/M3 CEILING
ACGIH TLV: 0.005 PPM TWA 0.051 MG/M3 TWA
MINERAL SPIRITS 8052-41-3 2 68 F 0 - 10%
ACGIH TLV 100 PPM TWA
* Indicates toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.
INFORMATION CONCERNING ITEMS LISTED AS PROPRIETARY WILL BE DISPENSED TO HEALTH AND SAFETY PROFESSIONALS AS REQUIRED BY
29CFR 1910.1200 (OSHA HAZARD COMMUNICATIONS STANDARD).
TSCA INVENTORY STATUS: ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============
BOILING RANGE: NOT DETERMINED. SPECIFIC GRAVITY (H2O=1): 1.5667
VAPOR DENSITY: NOT DETERMINED. EVAPORATION RATE: NOT DETERMINED.
COATING V.O.C.: 0.7351 lb/gl MATERIAL V.O.C.: 0.7351 lb/gl
SOLUBILITY IN WATER: NOT DETERMINED.
APPEARANCE AND ODOR: REFER TO PRODUCT BULLETIN.
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============
FLASH POINT: 105 F METHOD USED: TCC
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1.0 UPPER: 7.0
EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY FOR LARGE
FIRES.
SPECIAL FIREFIGHTING PROCEDURES
FULL EMERGENCY EQUIPMENT WITH SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE CLOTHING SHOULD BE WORN BY FIRE FIGHTERS. DURING A FIRE ISOCYANATE
MONOMER VAPORS AND OTHER IRRITATING, HIGHLY TOXIC GASES MAY BE GENERATED BY
THERMAL DECOMPOSITION.
M A T E R I A L __ S A F E T Y __ D A T A __ S H E E T
PRODUCT NAME: DriTac 7600 Page: 3
UNUSUAL FIRE AND EXPLOSION HAZARDS
AT TEMPERATURES GREATER THAN 400F ISOCYANATES CAN POLYMERIZE AND DECOMPOSE WHICH
CAN CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS. EXPLOSIVE RUPTURE IS POSSIBLE.
THEREFORE, USE COLD WATER TO COOL FIRE EXPSOSED CONTAINERS.
======================== SECTION V - REACTIVITY DATA =======================
STABILITY: STABLE
CONDITIONS TO AVOID
EXCESSIVE HEAT.
INCOMPATIBILITY (MATERIALS TO AVOID) WATER,
AMINES, STRONG BASES, AND ALCOHOLS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE,
ISOCYANATE MONOMER VAPORS.
HAZARDOUS POLYMERIZATION: [X] MAY OCCUR [ ] WILL NOT OCCUR THROUGH
CONTACT WITH MOISTURE, OTHER MATERIALS WHICH REACT WITH ISOCYANATES, OR
TEMPERATURES ABOVE 400F MAY CAUSE POLYMERIZATION.
==================== SECTION VI - HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
CONCENTRATIONS OF ISOCYANATE VAPORS ABOVE THE TLV CAN IRRITATE THE MUCOUS
MEMBRANES IN THE RESPIRATORY TRACT CAUSING RUNNY NOSE, SORE THROAT, COUGHING,
CHEST DISCOMFORT, REDUCED LUNG FUNCTION, AND PULMONARY EDEMA. REPEATED
OVEREXPOSURE OR A SINGLE LARGE DOSE CAN RESULT IN ISOCYANATE SENSITIZATION.
THESE SYMPTOMS CAN BE DELAYED UP TO SEVERAL HOURS AFTER EXPOSURE.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
ISOCYANATES REACT WITH SKIN PROTEIN AND MOISTURE AND CAN CAUSE IRRITATION.
PROLONGED CONTACT CAN RESULT IN SKIN SENSITIZATION. VAPORS CAN CAUSE BURNING IN
EYES AND IF LEFT UNTREATED, CAN CAUSE CORNEAL DAMAGE.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
SKIN ABSORPTION MAY BE HARMFUL. MAY CAUSE SKIN SENSITIZATION OR OTHER ALLERGIC
RESPONSES. MAY CAUSE PAIN, ITCHING, DISCOMFORT OR DERMITITIS.
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
INGESTION CAN RESULT IN IRRITATION AND CORROSIVE ACTION IN THE MOUTH, STOMACH
TISSUE AND DIGESTIVE TRACT. SYMPTOMS CAN INCLUDE SORE THROAT, ABDOMINAL PAIN,
NAUSEA, VOMITING AND DIARRHEA.
HEALTH HAZARDS (ACUTE AND CHRONIC)
MAY BE IRRITATING TO EYES, SKIN AND MUCOUS MEMBRANES. MAY CAUSE REDNESS,
SWELLING OR DERMITITIS. PROLONGED CONTACT OR VAPOR OVEREXPOSURE MAY CAUSE
ALLERGIC REACTIONS, SENSITIZATION, COUGHING OR SORE THROAT.
M A T E R I A L __ S A F E T Y __ D A T A __ S H E E T
PRODUCT NAME: DriTac 7600 Page: 4
CARCINOGENICITY: NTP CARCINOGEN: IARC MONOGRAPHS: OSHA REGULATED:
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
ASTHMA, OTHER RESPIRATORY DISORDERS (BRONCHITIS, EMPHYSEMA, BRONCHIAL HYPER
ACTIVITY), SKIN ALLERGIES, ECZEMA.
EMERGENCY AND FIRST AID PROCEDURES
FOR EYES, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK
MEDICAL ATTENTION. FOR SKIN, REMOVE CONTAMINATED CLOTHING AND WASH THOROUGHLY
WITH SOAP AND WATER. FOR INHALATION, MOVE VICTIM TO FRESH AIR, ADMINISTER OXYGEN
OR ARTIFICIAL RESPIRATION AS NEEDED. SEEK MEDICAL ATTENTION. FOR INGESTION, DO
NOT INDUCE VOMITING. GIVE 1 TO 2 CUPS OF MILK OR WATER TO DRINK. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CONSULT PHYSICIAN.
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER SYSTEM.
WEAR FULL PROTECTIVE EQUIPMENT. ABSORB WITH INERT MATERIAL. SPILL CAN BE
NEUTRALIZED WITH THE FOLLOWING SOLUTION (90% WATER,8% AMMONIA, 2% DETERGENT). ADD
ABOUT 10 PARTS OF NEUTRALIZER PER PART OF ISOCYANATE. SCOOP INTO DISPOSAL
CONTAINERS. DO NOT SEAL WASTE CONTAINERS AS CO2 EVOLUTION CAN CAUSE PRESSURE
BUILDUP AND CONTAINER RUPTURE.
WASTE DISPOSAL METHOD
INCINERATE OR BURY IN LANDFILL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. INCINERATION IS THE PREFERRED METHOD OF DISPOSAL.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
STORE IN TIGHTLY CLOSED CONTAINERS TO PREVENT MOISTURE CONTAMINATION. CARE SHOULD
BE TAKEN TO AVOID CONTACT WITH SKIN AND EYES. DO NOT BREATHE AEROSOLS OR VAPORS.
KEEP AWAY FROM FOOD AND DRINK.
OTHER PRECAUTIONS
DISPOSE OF ALL CONTAMINATED LEATHER ITEMS. LEATHER CANNOT BE DECONTAMINATED.
===================== SECTION VIII - CONTROL MEASURES ======================
DriTac Adhesive Group GIVES ALL INFORMATION HEREIN CONTAINED IN GOOD FAITH. DUE
TO DIFFERENT APPLICATIONS, THE END USER SHOULD MAKE THE FINAL DETERMINATION AS TO
THE PROPER EQUIPMENT AND CONTROLS TO BE USED WITH THIS PRODUCT.
RESPIRATORY PROTECTION
SELF-CONTAINED OR AIR SUPPLIED RESPIRATOR WITH FULL FACE PIECE WHERE TLV IS
EXCEEDED. CARTRIDGE RESPIRATORS ARE NOT RECOMMENDED DUE TO THE POOR WARNING
PROPERTIES OF ISOCYANATES. EXPOSED PERSONS WILL NOT BE ABLE TO SMELL THE
MATERIAL UNTIL THE TLV HAS BEEN EXCEEDED.
M A T E R I A L __ S A F E T Y __ D A T A __ S H E E T
PRODUCT NAME: DriTac 7600 Page: 5
VENTILATION
LOCAL EXHAUST.
PROTECTIVE GLOVES
PERMEATION RESISTANT GLOVES (BUTYL RUBBER, NITRILE RUBBER, PVC OR POLYVINYL
ALCOHOL) .
EYE PROTECTION
GLASSES WITH SIDE SHIELDS, CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
EYE WASH STATION AND SAFETY SHOWER. IMPERVIOUS CLOTHING.
WORK/HYGIENIC PRACTICES
WASH AT THE END OF EACH WORKSHIFT AND BEFORE EATING, DRINKING, SMOKING OR USING
THE RESTROOM. PROMPTLY REMOVE CLOTHING THAT BECOMES CONTAMINATED. EXAMINE
PROTECTIVE GLOVES BEFORE USING. LAUNDER OR PROPERLY DISPOSE CONTAMINATED
CLOTHING ARTICLES.
====================== SECTION IX - OTHER INFORMATION ====================
THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY EXPRESSED OR IMPLIED IS MADE. DriTac URGES USERS OF THIS
PRODUCT TO EVALUATE ITS SUITABILITY AND COMPLIANCE WITH LOCAL REGULATIONS AS DriTac CANNOT FORESEE THE FINAL USE OF THE
PRODUCT, NOR THE FINAL LOCATION OF USAGE.
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