DEVCON?Dev-Thane 2TM light grey
MSDS Name:
[1:1]
Manufacturer Name: ITW Devcon
Stock No.: 14501
Components:
DEV-THANE II CURING AGENT
DEV-THANE II RESIN
ITW Performance Polymers (Finished Goods) Product Code : 14501
View Section :
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: DEV-THANE II CURING AGENT
HMIS
Manufacturer Name: ITW Devcon
Address: 30 Endicott Street
Danvers, MA 01923
Health Hazard 1
MSDS Revision Date: 10/10/2006
Fire Hazard 1
Emergency telephone number (800) 424-9300
REACTIVITY 0
Personal
x
Protection
* Chronic Health
Effects:
In the US, call CHEMTREC: (800) 424-9300
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SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS#
Trade secret. N/A 60 - 100 by Weight
Titanium dioxide 13463-67-7 1 - 5 by Weight
Inert material N/A 1 - 5 by Weight
Diisodecyl phthalate 26761-40-0 1 - 5 by Weight
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SECTION 3: HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Irritant.
Primary Routes of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye Contact: Can cause severe eye irritation and burns. Eye contact may cause permanent
damage or blindness.
Skin Contact: Causes severe skin irritation. May cause permanent skin damage.
Inhalation: Vapor or mist may cause severe respiratory system irritation.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal
tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening,
swelling, and possible tissue destruction
Signs/Symptoms: Overexposure may cause eye watering or discomfort, redness and swelling.
Target Organs: Eyes. Skin. Respiratory system. Digestive system.
Aggravation of Pre-Existing May aggravate pre-existing respiratory disorders, allergy, eczema, or skin
Conditions: conditions.
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SECTION 4: FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure
adequate flushing of the eyes by separating the eyelids with fingers. Get
immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while
removing contaminated clothing and shoes. Get medical attention if irritation
develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.
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SECTION 5: FIRE FIGHTING MEASURES
Auto Ignition Temp : Not determined.
Flash Point: >325癋 (162.7癈)
Flash Point Method: Pensky-Martens Closed Cup
Lower Explosive Limit (LEL) Not determined.
Upper Explosive Limit (UEL) Not determined.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire space
without full protective gear. If possible, contain fire run-off water.
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SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering
the spill area.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical
waste container. Provide ventilation. Clean up spills immediately observing
precautions in the protective equipment section. After removal, flush spill area
with soap and water to remove trace residue.
Avoid personal contact and breathing vapors or mists. Ventilate area. Use proper
personal protective equipment as listed in section 8.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Other Precautions: Pump or shovel to storage/salvage vessels.
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SECTION 7: HANDLING AND STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist.
Storage: Store in a cool, dry, well ventilated area away from sources of heat and
incompatible materials. Keep container tightly closed when not in use. Do not
store in reactive metal containers. Keep away from acids, oxidizers.
Hygiene Practices: Wash thoroughly after handling.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to protect
against dust during sanding/grinding of cured product.
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SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA or
other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin
contact. Consult manufacturer's data for permeability data.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash
and a deluge shower safety station.
Titanium dioxide:
Guideline ACGIH : ACGIH TLV-TWA 10 mg/m3
Notes : Only established PEL and TLV values for the ingredients are listed below.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State/Appearance: Liquid.
Color: gray.
Odor: mild.
Boiling Point: Not determined.
Melting / Freezing Point : Not determined.
Solubility: negligible
Specific Gravity: 1.4
pH: Not determined.
Vapor Density: > 1 (air = 1)
Vapor Pressure: Not determined.
Molecular Formula: Mixture
Molecular Weight: Mixture
Percent Volatile: Not determined.
VOC Data : Not determined.
Percent Solids by Weight Not determined.
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SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions.
Incompatibilities with Other Oxidizers, acids, and chlorinated organic compounds. Reactive metals (e.g.
Materials: sodium, calcium, zinc). Sodium/calcium hypochlorite. Nitrous acid/ oxide,
nitrites. Peroxides. Materials reactive with hydroxyl compounds.
Hazardous Polymerization: Not reported.
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SECTION 11: TOXICOLOGICAL INFORMATION
Titanium dioxide:
Skin Effects: Skin - Human Standard Draize Test : 300 ug/3D-I - [mild](RTECS)
Inhalation Effects: Inhalation - Rat TCLo - Lowest published toxic concentration: 1 mg/kg - [Lungs,
Thorax, or Respiration - other changes Biochemical - Metabolism (Intermediary)
- effect on inflammation or mediation of inflammation ] (RTECS)
Ingestion Effects: Oral - Rat TDLo - Lowest published toxic dose: 60 gm/kg - [Gastrointestinal -
hypermotility, diarrhea Gastrointestinal - other changes ] (RTECS)
Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans
Diisodecyl phthalate:
Skin Effects: Skin - Rat LD50: >3160 mg/kg - [Details of toxic effects not reported other than
lethal dose value](RTECS)
Inhalation Effects: Inhalation - Guinea pig LC: >130 mg/m3/6H - [Details of toxic effects not
reported other than lethal dose value] (RTECS)
Ingestion Effects: Oral - Rat LD50: 64 gm/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
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SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
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SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number : None
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SECTION 14: TRANSPORT INFORMATION
DOT UN Number: N/A
DOT Hazard Class: Not applicable.
DOT Packing Group: Not applicable.
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SECTION 15: REGULATORY INFORMATION
Titanium dioxide:
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
Canadian Regulations. WHMIS Hazard Class(es): None
All components of this product are on the Canadian Domestic Substances List.
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SECTION 16: ADDITIONAL INFORMATION
HMIS Health Hazard: 1
HMIS Fire Hazard: 1
HMIS Reactivity: 0
HMIS Personal Protection: x
MSDS Revision Date: 10/10/2006
Disclaimer: "This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. The information given in the
Data Sheet is designed only as a guidance for safe handling, storage and the use
of the substance. It is not a specification nor does it guarantee any specific
properties. All chemicals should be handled only by competent personnel, within
a controlled environment."
Copyright?1996-2007 Actio Software Corporation. All Rights Reserved.
View Section :
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: DEV-THANE II RESIN
Manufacturer Name: ITW Devcon
HMIS
Address: 30 Endicott Street
Danvers, MA 01923
MSDS Revision Date: 10/10/2006
Health Hazard 3*
Fire Hazard 1
Emergency telephone number (800) 424-9300
REACTIVITY 2
Personal
x
Protection
* Chronic Health
Effects:
In the US, call CHEMTREC: (800) 424-9300
To Top of page
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS#
Higher oligimers of methane diisocyanate (MDI) 9016-87-9 60 - 100 by Weight
4,4'-Diphenylmethane diisocyanate 101-68-8 5 - 10 by Weight
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SECTION 3: HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Irritant. Potential Sensitizer.
Primary Routes of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye Contact: Can cause moderate irritation, burning sensation, tearing, redness, and swelling.
Overexposure may cause lacrimation, conjunctivitis, corneal damage and
permanent injury..
Skin Contact: Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling.
Allergic reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on
reexposure to this material.
Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache, and
anesthetic effects. May cause respiratory sensitization with asthma-like
symptoms in susceptible individuals.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal
tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening,
swelling, and possible tissue destruction
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
Isocyanate exposure levels must be monitored. Medical supervision of all
employees who handle or come in contact with isocyanates is recommended (i.e.
FEV, FVC). This should include pre-employment and periodic medical
examinations.
Persons with asthmatic-type conditions, chronic bronchitis, other chronic
respiratory diseases, recurrent skin eczema or sensitization should be excluded
from working with this product. Once sensitized no further exposure can be
permitted.
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SECTION 4: FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure
adequate flushing of the eyes by separating the eyelids with fingers. Get
immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while
removing contaminated clothing and shoes. Get medical attention if irritation
develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.
Note to Physicians: Asthmatic type symptoms may develop, which may be immediate or delayed for
several hours.
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SECTION 5: FIRE FIGHTING MEASURES
Flammable Properties : Combustible Class III B
Auto Ignition Temp : Not determined.
Flash Point: >450癋 (232.2癈)
Flash Point Method: Pensky-Martens Closed Cup
Lower Explosive Limit (LEL) Not determined.
Upper Explosive Limit (UEL) Not determined.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire space
without full protective gear. If possible, contain fire run-off water.
To Top of page
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering
the spill area.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical
waste container. Provide ventilation. Clean up spills immediately observing
precautions in the protective equipment section. Neutralize residue with
appropriate neutralizer. Do not attempt to neutralize large quantities of material
unless measures to control reactivity and heat generation have been taken.
Absorb spill with inert material (e.g.., dry sand or earth), then place in a
chemical waste container. Provide ventilation. After removal, flush spill area with
soap and water to remove trace residue.
Avoid personal contact and breathing vapors or mists. Ventilate area. Use proper
personal protective equipment as listed in section 8.
A blanket of protein foam may be placed over spill for temporary control of
isocyanate vapor.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Other Precautions: Pump large quantities into closed but not sealed metal containers. Isocyanates
will react with water and generate carbon dioxide, this could result in the rupture
of any closed containers.
Neutralize using 10 parts neutralizer to 1 part isocyanate solution. Mix and allow
to stand for 48 hrs in containers, letting evolved carbon dioxide to vent.
Neutralizer consist of 90% water, 3-8% concentrated ammonia (or sodium
carbonate), 2% detergent.
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SECTION 7: HANDLING AND STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist.
Storage: Store in a cool, dry, well ventilated area away from sources of heat and
incompatible materials. Keep container tightly closed when not in use. Do not
reseal container If moisture or water contamination is suspected. Water
contaminated material in a sealed container may rupture due to pressure
buildup.
Hygiene Practices: Wash thoroughly after handling.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to protect
against dust during sanding/grinding of cured product.
To Top of page
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA or
other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin
contact. Consult manufacturer's data for permeability data.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash
and a deluge shower safety station.
4,4'-Diphenylmethane diisocyanate:
Guideline ACGIH : ACGIH TLV-TWA 0.005 ppm
Guideline OSHA : OSHA PEL-STEL 0.02 ppm Ceiling/Peak
Notes : Only established PEL and TLV values for the ingredients are listed below.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State/Appearance: Liquid.
Color: Beige.
Odor: mild.
Boiling Point: 406癋 (207.7癈) @ 5 mmHg
Melting / Freezing Point : Not determined.
Solubility: Reacts.
Specific Gravity: 1.41
pH: Not determined.
Vapor Density: >1 (air = 1)
Vapor Pressure: Not determined.
Molecular Formula: Mixture
Molecular Weight: Mixture
Percent Volatile: 0
VOC Data : 0 g/L
Percent Solids by Weight Not determined.
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SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions. Moisture and extended exposure over 85 F.
Incompatibilities with Other Alcohols, amines, strong bases (alkali, ammonia), acids, metal compounds,
Materials: moisture or water. Resin reacts with water to give off carbon dioxide.
Hazardous Polymerization: Polymerization may occur under certain conditions.
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SECTION 11: TOXICOLOGICAL INFORMATION
Higher oligimers of methane diisocyanate (MDI):
Eye Effect: Eye - Rabbit Standard Draize Test: 100 mg - [mild](RTECS)
Skin Effects: Skin - Rat LD50: >9400 mg/kg - [Details of toxic effects not reported other than
lethal dose value](RTECS)
Inhalation Effects: Inhalation - rat LC50: 490 mg/m3/4H - [Sense Organs and Special Senses (Eye)
- effect, not otherwise specified Lungs, Thorax, or Respiration - respiratory
depression Blood - hemorrhage] (RTECS)
Ingestion Effects: Oral - Rat LD50: 49 gm/kg - [oral - somnolence (general depressed activity)
Gastrointestinal - hypermotility, diarrhea Nutritional and Gross Metabolic - body
rat decrease] (RTECS)
4,4'-Diphenylmethane diisocyanate:
Eye Effect: Eye - Rabbit Standard Draize Test : 100 mg - [Moderate ](RTECS)
Skin Effects: Skin - Rat Standard Draize Test : 500 mg/24H(RTECS)
Inhalation Effects: Inhalation - Rat LC50: 178 mg/m3 - [Details of toxic effects not reported other
than lethal dose value] (RTECS)
Ingestion Effects: Oral - Rat LD50: 9200 mg/kg - [oral - somnolence (general depressed activity)
oral - ataxia Nutritional and Gross Metabolic - body rat decrease ] (RTECS)
Oral - Mouse LD50: 2200 mg/kg - [Details of toxic effects not reported other
than lethal dose value ] (RTECS)
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SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
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SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number : None
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SECTION 14: TRANSPORT INFORMATION
DOT Shipping Name: Non regulated.
DOT UN Number: N/A
DOT Hazard Class: Not applicable.
DOT Packing Group: Not applicable.
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SECTION 15: REGULATORY INFORMATION
Higher oligimers of methane diisocyanate (MDI):
TSCA Inventory Status Listed
State: Listed in the New Jersey State Right to Know List.
EC Num : 615-005-01-6
4,4'-Diphenylmethane diisocyanate:
TSCA Inventory Status Listed
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 615-005-00-9
Canadian Regulations. WHMIS Hazard Class(es): D2A; D2B
All components of this product are on the Canadian Domestic Substances List.
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SECTION 16: ADDITIONAL INFORMATION
HMIS Health Hazard: 3*
HMIS Fire Hazard: 1
HMIS Reactivity: 2
HMIS Personal Protection: x
MSDS Revision Date: 10/10/2006
Disclaimer: "This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. The information given in the
Data Sheet is designed only as a guidance for safe handling, storage and the use
of the substance. It is not a specification nor does it guarantee any specific
properties. All chemicals should be handled only by competent personnel, within
a controlled environment."
Copyright?1996-2007 Actio Software Corporation. All Rights Reserved.
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