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Material Safety Data Sheet (Component A)
Industrial Polymers, Inc. Chemtrec emergency phone 1-800-424-9300
3250 South Sam Houston Parkway East Product data information (713) 943-8451
Houston, Texas 77047 Fax (713) 943-1525
Date: January 1, 2006
Product Identification
Chemical family: Synthetic Urethane Polymer
Product name: Primer 450 & 460
Composition Information / Ingredients
Ingredient Name / CAS Number Exposure Limits Concentration
4? Diphenylmethane Diisocyanate (MDI) ACGIH TLV 0.05 mg/M_ (8 hour, 40 hours/week) 10%
CAS number 101-68-8 OSHA PEL Ceiling 0.20 mg/M_ by weight
NIOSH PEL/TWA 0.05 mg/M_ (10 hour, 40 hours/week)
NIOSH PEL Ceiling 0.20 mg/M_ (10 minute)
Higher Oligomers of MDI OSHA: not established 11.09%
CAS number 9016-87-9 ACGIH: not established by weight
2,4 Diphenylmethane Diisocyanate (MDI) OSHA: not established 0.6525%
CAS number 5873-54-1 ACGIH: not established by weight
Toluene OSHA PEL 200 ppm ?TWA 51%
CAS number 108-88-3 OSHA PEL 300 ppm ?Ceiling by weight
OSHA VPEL 100 ppm ?TWA
OSHA VPEL 150 ppm ?STEL
ACGIH TLV 50 ppm ?TWA (skin)
ACGIH TLV 150 ppm ?STEL (skin)
Urethane Prepolymer
CAS 64771-77-3 Not Established 27%
Toluene diisocyanate
CAS 584-84-9
CAS 91-08-7 Less than 0.05%
Hazardous Material Identification
Primary route(s) of entry: skin absorption, inhalation and ingestion.
Eyes: eye irritant, possible eye burn.
Skin: skin irritant and possible skin sensitizer. Direct skin contact is likely route or entry into the body. Once sensitized an individual may react to airborne levels below the TLV with the
following symptoms, itching and tingling of the earlobe and neck, rash and hives, swelling of the arms and legs or other symptoms common to allergic dermatitis. Any individual having
a sensitization reaction to this material should be removed from exposure to any isocyanate.
Inhalation: inhalation of vapors or spray mist may also cause irritation to the respiratory tract (dry throat, cough, shortness of breath or chest tightness). In addition, sinusitis, bronchitis
or respiratory sensitization (asthma-like symptoms) may occur. Exposure to Toluene may cause nausea, headaches, dizziness or any other central nervous system effects.
Emergency and first aid procedure
Eyes: flush with large amounts of water for at least 15 minutes. Seek medical attention immediately.
Skin: wash exposed area thoroughly with soap and water. Be sure to wash contaminated clothing before reusing. Seek medical attention.
Inhalation: move person into fresh air. Oxygen may be administered if available and needed. Seek medical attention immediately.
Ingestion: do not induce vomiting. Give glass of water or milk to drink. Do not give anything by mouth to unconscious person. Seek medical attention immediately.
Fire and explosion hazard data
Flash point: 44?F (TCC, ASST. D45-70).
Flammable limits (% by volume in air): upper ?1.7, lower ?1.
Extinguishing media: water spray (fog), foam, dry chemical or carbon dioxide.
Full protective equipment with self-contained breathing apparatus should be worn.
Material contains flammable solvent. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to
extreme heat. Water spray may be used to cool closed containers and prevent pressure build-up. Empty containers may contain liquid or vapor, which is flammable or explosive. Do
not weld, burn or cut empty containers.
Accidental release measures
Shut off and eliminate all ignition sources. Ventilate confined spaces. Workers should avoid direct skin or eye contact, or inhalation of vapors. Absorb on dry inert material. Package for
disposal.
Special precautions and storage data
Storage temperature: 100?F (38?C) maximum
Shelf life: minimum 1 year at 75?F (23?C)
Keep containers closed when not in use. Keep away from heat, sparks and open flame. Store in tightly sealed containers and away from moisture and direct sunlight. Wear personal
protective equipment when working on equipment that may be contaminated with material.
Personal protection
Respiratory protection: if working in conditions where TLV is exceeded, use a chemical cartridge mask or air supply hood as required and/or approved by ANSI and OSHA.
Eye protection: splash goggles or face shield required. A full-face shield is recommended for most situations as it affords eye as well as face protection.
Skin protection: chemical resistant gloves, apron or coveralls, and face shield are required. If protective creams are used, minimize the area protected only by the cream.
Ventilation requirements: use with adequate forced air mechanical ventilation in accordance with OSHA regulations. Ventilation must be sufficient to prevent vapors from exceeding
exposure limit(s) or build-up of explosive concentrations of vapor in air.
Component A Page 2 of 4
Physical properties
Appearance: viscous liquid
Odor: aromatic
Color: clear
Boiling point: 230?F
Specific gravity: 1.00
Percent volatile by volume: 50
Evaporation rate (ether = 1): slower
Vapor density (air = 1): greater
Solubility in water (%): negligible/reacts slowly with water
Stability and reactivity
Stability: stable under normal conditions.
Avoid contact with moisture and other materials that react with isocyanates and temperatures above maximum storage temperature.
Incompatibility: contact with water, alcohols, amines and strong bases.
Hazardous decomposition products: by high heat and fire, carbon monoxide, carbon dioxide, oxides of nitrogen, traces of HEN, isocyanate and solvent vapors.
Hazardous polymerization will not occur under normal conditions.
Toxicological information
No data
Ecological information
No data
Disposal considerations
Dispose of in accordance with local, state and federal regulations.
Shipping information
DOT shipping name: Paint Related Material
DOT hazard classification: 3
UN/NA number: UN1263
Packaging group: II
DOT labels required: red label, Flammable Liquid
DOT placards required: Flammable Liquid
Freight class: 55
Packaging, airfreight:
Passenger aircraft only: Packaging Inst. (see IATA): Y305 Limited Qty: 1 liter
Passenger/Cargo aircraft only: Packaging Inst. (see IATA): 305 Limited Qty: 5 liters
Cargo aircraft only: Packaging Inst. (see IATA): 307 Limited Qty: 60 liters
Volatile organic content
Formulation used to compute VOC/liter
Ws-Ww-Wec
Vm-Vw-Vec
Ws ?Weight of solvent in grams Vm ?Volume of material
Ww ?Weight of water Vw ?Volume of water
Wec ?Weight of exempt solvent Vec ?Volume of exempt solvent
Ws ?1934 grams 1934 grams = 511 grams VOC/liter or 4.26 lb./gallon
Ww ?0 3.784 liters
Wec ?0
Vm ?3.784 liters (1 gallon)
Vw ?0
Vec ?br>
Regulatory information
California Proposition 65:
Component A for this product contains the following chemicals that are known to cause reproductive toxicity, and are listed under California Proposition 65.
Ingredient / CAS Number Exposure Limits Concentration
Toluene OSHA PEL 200 ppm ?TWA
CAS number 108-88-3 OSHA PEL 300 ppm ?Ceiling 51 %
OSHA VPEL 100 ppm ?TWA
OSHA VPEL 150 ppm ?STEL
ACGIH TLV 50 ppm ?TWA (skin)
ACGIH TLV 150 ppm ?STEL (skin)
Material Safety Data Sheet (Component B)
Product Identification
Chemical family: Polyol Mixture
Product name: Primer 450 & 460
Component B Page 3 of 4
Composition Information / Ingredients
Ingredient Name / CAS Number Exposure Limits Concentration
Methyl Ethyl Ketone ACGIH ?TLV TWA 200 ppm (v) 300 ppm (v) 60%
CAS Number 78-93-3 OSHA ?PEL TWA 200 ppm (v) by weight
OSHA ?PEL Interim Standard TWA 200 ppm (v) STEL 300 ppm (v)
Note: This chemical is subject to reporting requirements of section 313 of SARA Title III.
Hazardous Material Identification
Primary route(s) of entry: skin absorption, inhalation and ingestion.
Eyes: eye irritant, possible eye burn.
Skin: skin irritant and possible skin sensitize. Direct skin contact is likely route of entry into the body.
Inhalation: inhalation of vapors or spray mist may also cause irritation to the respiratory tract (dry throat, cough, shortness of breath, chest tightness). In addition, sinusitis, bronchitis, or
respiratory sensitization (asthma like symptoms) may occur. Exposure to Toluene may cause nausea, headaches, dizziness or any other central nervous system effects.
Emergency and first aid procedure
Eyes: flush with large amounts of water for at least 15 minutes. Seek medical attention immediately.
Skin: wash exposed area thoroughly with soap and water. Be sure to wash contaminated clothing before reusing. Seek medical attention.
Inhalation: get person into fresh air. Oxygen may be administered if available and needed. Seek medical attention immediately.
Ingestion: do not induce vomiting. Give glass of water or milk to drink. Do not give anything by mouth to unconscious person. Seek medical attention immediately.
Fire and explosion hazard data
Flash point: 14?F, (T.C.C., ASTM. D45-70)
Flammable limits: (% by volume in air): upper ?11.0, lower - 2.2
Extinguishing media: water spray (fog), foam, dry chemical or carbon dioxide.
Special fire fighting procedures: full protective equipment with self-contained breathing apparatus should be worn.
Unusual fire and explosion hazards: material contains flammable solvent. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flames. Closed
containers may explode when exposed to extreme heat. Water spray may be used to cool closed containers and prevent pressure build up. Empty containers may contain liquid or
vapor, which is flammable or explosive. Do not weld, burn, or cut empty containers. Always ground container when pouring to avoid static discharge (sparking), which could ignite
solvents. Do not allow free fall of more than a few inches when pouring, as dangerous static charges could be generated.
Accidental release measures
Shut off and eliminate all ignition sources. Ventilate confined spaces. Workers should avoid direct skin or eye contact, or inhalation of vapors. Absorb on dry inert material. Package for
disposal.
Special precautions and storage data
Storage temperature: 100?F (38?C) maximum
Shelf life: minimum 1 year at 75?F (28?C)
Keep containers closed when not in use. Keep away from heat, sparks and open flame. Store on tightly sealed containers and away form moisture and direct sunlight. Wear personal
protective equipment when working on equipment that may be contaminated with material.
Personal protection
Respiratory protection: if working in conditions where TLV is exceeded, use a chemical cartridge mask or air supply hood as required and/or approved by ANSI and OSHA.
Ventilation requirements: use with adequate forced air mechanical ventilation in accordance with OSHA regulations. Ventilation must be sufficient to prevent vapors form exceeding
exposure limit(s) or build up of explosive concentrations of vapor in air.
Eye protection: splash goggles or face shield required. A full-face shield is recommended for most situations as it affords eye as well as face protection.
Other protective equipment: chemical resistant gloves, apron or coveralls, and face shield are required. If protective creams are used, minimize the area protected only by the cream.
Physical properties
Appearance: thin amber liquid
Odor: aromatic
Color: amber
Boiling point: 171?F
Specific gravity: .8672
Percent volatile by volume: 41
Evaporation rate (ether=1): slower
Vapor density (air=1): greater
Solubility in water (%): 7-8 (ethyl acetate)
Stability and reactivity
Stability: stable under normal conditions.
Conditions to avoid: contact with moisture. Temperatures above maximum storage temperature.
Incompatibility (materials to avoid): strong acids.
Hazardous decomposition products: by high heat and fire, carbon monoxide, carbon dioxide, and solvent vapors.
Hazardous polymerization: will not occur under normal conditions.
Toxicological information
No data
Ecological information
No data
Component B Page 4 of 4
Disposal considerations
Dispose of in accordance with local, state, and federal regulations.
Shipping information
DOT shipping name: Paint Related Materials
DOT hazardous classification: 3
UN number: UN1263
Packaging Group: II
DOT labels required: red label, Flammable Liquid
DOT placards required: Flammable Liquid
Freight class: 55
Packaging, Airfreight:
Passenger aircraft only: Packaging Inst. (see IATA): Y305 Limited Qty: 1 liter
Passenger/Cargo aircraft: Packaging Inst. (see IATA): 305 Limited Qty: 5 liters
Cargo aircraft only: Packaging Inst. (see IATA): 307 Limited Qty: 60 liters
Volatile organic content
Formulation used to compute VOC/liter
Ws-Ww-Wec
Vm-Vw-Vec
Ws ?Weight of solvent in grams Vm ?Volume of material
Ww ?Weight of water Vw ?Volume of water
Wec ?Weight of exempt solvent Vec ?Volume of exempt solvent
Ws ?1934 grams 1934 grams = 511 grams VOC/liter or 4.26 lb./gallon
Ww ?0 3.784 liters
Wec ?0
Vm ?3.784 liters (1 gallon)
Vw ?0
Vec ?br>
Regulatory information
California Proposition 65:
Component B for this product does not contain any chemicals that are listed under California Proposition 65.
Other information
The data in this material safety data sheet relates only to the material designated herein and does not relate to use in combination with any other material or in any process. The
information herein is furnished free of charge and is based on technical data that Industrial Polymers, Inc. believes to be reliable, and to the best of our knowledge, accurately reflects
the properties and effects of the hazardous components. This product is intended for use by persons having technical skills and at their own discretion and risks. Because conditions
of use of this material are outside our control we make no warranties, expressed or implied, and assume no liability in connection with any use of this material.
Prepared by: C. Boddie
Approval date: 01/06
Supercedes 05/02
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