EC Safety Data Sheet (according to 91/155/EEC)
Product name: IH 81 Component B Issue No. 0002
Issued on: 23/07/2003 Printing date: 14/11/2003 Page 1 of 4
1. Substance-/Preparation and company name
Details of the product IH 81 Component B;
(Product name and use): Polyurethane Injection resin for waterproofing of building
structures
Information about manufacturer/supplier
Germany Switzerland
Manufacturer/Supplier: Tricosal GmbH Tricosal BBZ AG
Address: Von-Helmholtz-Str. 1 Gewerbezentrum Rotfarb
D-89257 Illertissen 9213 Hauptwil (Schweiz)
Telephone: + 49 (0) 73 03 180 - 0 +41 (0) 71 424 6070
Telefax: + 49 (0) 73 03 180 280 +41 (0) 71 424 6077
Information Line: + 49 (0) 73 03 180 - 0 +41 (0) 71 424 6070
E-mail info@tricosal.de info@bbz-ag.ch
URL www.tricosal.de
2. Composition / Information on ingredients
Chemical composition: Preparation based on special diphenylmethandiisocyanate
Hazardous ingredients
CAS-No. Name of substance Content Symbol R--phrases
101-68-8 < 60 % Xn 20; 36/37/38; 42/43
Diphenylmethan-4,4'-diisocyanat; Isomeric and homologous
3. Possible Hazards
Identification of hazard: Xn harmful
Information concerning hazards for Harmful if breathing in; irritating to eyes, skin and muscous
man and environment: membranes are possible; sensibilization by breathing in and skin
contact is possible.
This classification system complies with the current EC-lists and company information.
4. First aid measures
General advice: Immediately remove contaminated and soaked clothing.
After inhalation: Provide for fresh air, at troubles seek medical advice
After skin contact: Wash off with plenty of water and soap.
After eye contact: Rinse with plenty of water for at least 15 min.; seek medical advice
immediately
After ingestion: Rinse mouth; seek medical advice immediately
5. Fire Fighting Measures
Foam, Extinguishing powder, CO2 (Carbon Dioxide),
Suitable extinguishing media:
water spray.
Non-suitable extinguishing agent (for safety reason): Water jet spray.
Particular hazards caused by the substance, Toxic and irritant burnt gases can form in case of fire.
combustion products or developing gases:
Special Protective equipment: Wear self-contained breathing apparatus in case of
fire; follow the standard safety measures for handling
chemicals in case of fire.
MSDS_IH81_ComponentB.doc
EC Safety Data Sheet (according to 91/155/EEC)
Product name: IH 81 Component B Issue No. 0002
Issued on: 23/07/2003 Printing date: 14/11/2003 Page 2 of 4
6. Accidental release measures
Personal precautions: Protect eyes and hands; wear personal protective
equipment; avoid inhalation of fumes.
Environmental precautions: Do not allow to enter drains, sewers, watercourses
and soil.
Measures for cleaning / collection: Soak up with inert liquid absorbent material (e.g.
universal binders); dispose in accordance with local
regulations.
7. Handling and storage
Handling:
Directions for safe handling: Wear personal protective equipment; provide for
good ventilation.
Directions to prevent fire and explosions: Protect from sources of ignition; protect from heat
Storage:
Requirements for warehouses and containers: keep containers tightly closed; protect from sunlight,
protect from heat; store under cool conditions, but
protect from frost; keep out of reach of children.
Further information for storage conditions: Not applicable
8. Exposure controls and personal protection
Engineering control measures: Provide for good ventilation (see paragraph 7)
Occupational exposure limits (Germany):
CAS-No. Name of substance Type Value Unit
101-68-8 Diphenylmethan-4,4'-diisocyanat MAK 0,05 mg/m?br>
Personal protective equipment
Breathing protection: Provide for good ventilation.
Hand protection: Chemical resistant protective gloves (e.g. nitrile rubber).
Eye Protection: Tight fitting safety goggles.
Body protection: Normal working clothes.
Hygiene at working place: Keep away from food and beverages, wash hands before breaks and
at the end of working day. Do not eat, drink or smoke during working.
9. Physical and chemical properties
Physical state: liquid Colour: clear, brown Odour: not applicable
Value / Unit
Change in condition: Not determined
Density (at 20癈): Approx. 1,1 g/ml
Vapour pressure (at 20癈): Not determined
Viscosity (at 20癈): Thin
Solubility in water (at 20癈): Insoluble, reacts
pH-value (at 20癈): Not applicable
Flash point: > 100癈
Explosion hazard: Not determined
MSDS_IH81_ComponentB.doc
EC Safety Data Sheet (according to 91/155/EEC)
Product name: IH 81 Component B Issue No. 0002
Issued on: 23/07/2003 Printing date: 14/11/2003 Page 3 of 4
10. Stability and reactivity
Conditions and substances to avoid: None if properly used and stored
Hazardous decomposition products: None if properly used and stored
Hazardous reactions: Exothermic reaction with amines and alcohols; with water (moisture):
CO2 is produced; pressure may build up inside closed containers
(danger of bursting)
11. Toxicological information
Primary irritant effect (skin, eyes): Irritating after contact with skin, eyes and respiratory system.
Sensitization: Possible by inhalation and skin contact.
Additional information: None
12. Ecological information
Degradability: Not determined
German water endangering class (WGK): 1 (own classification)
Further ecological information: Do not release product into environment.
Further ecological data: The product reacts with water releasing CO2, to form a solid,
insoluble polycarbamide with a high melting point, which, according
to present knowledge, is inert and not degradable.
13. Disposal considerations
Product:
Recommendation: If recycling is not possible, disposal in accordance with local and
official regulations.
Uncleaned packaging
Recommendation: Disposable in accordance with local and official regulations.
14. Transport information
Land transport: No hazardous good according to transport regulations
Sea transport: No hazardous good according to transport regulations
Air transport: No hazardous good according to transport regulations
15. Regulatory information
Identification according to EC directives
Code letter and hazard designation of the product:
Xn harmful
Relevant component for hazardous goods labelling: Contains: Diphenylmethanediisocyanate, isomers
and homologues
Special identification of certain preparations: Contains Isocyanate; observe manufacturer's
instructions
R-phrases: 20 Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin
42/43 May cause sensitisation by inhalation and skin contact
S-phrases: 23 Do not breathe vapour/spray
24 Avoid contact with skin
37/39 Wear suitable gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible)
National regulations
German water endangering class (WGK): 1 (own classification)
Swiss Federal Office of Public Health: BAG T-Nr. 614463, poisonous category 3
MSDS_IH81_ComponentB.doc
EC Safety Data Sheet (according to 91/155/EEC)
Product name: IH 81 Component B Issue No. 0002
Issued on: 23/07/2003 Printing date: 14/11/2003 Page 4 of 4
16. Other information
Relevant code letter and hazard designation of the product see section 2:
R 20 Harmful by inhalation.
R 36/37/38 Irritating to eyes, respiratory system and skin
R 42/43 May cause sensitisation by inhalation and skin contact
Changes in comparison with the previous version are marked at the margin with a line
The information of this MSDS is based on the present state of our knowledge. The users working conditions are
beyond our knowledge and control. The product is not to be used for other purposes than those specified under
section 1 without first obtaining written handling instruction.
It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the
local rules and legislation. The information in this MSDS is meant as a description of the safety requirements of
our product and is not to be considered as a guarantee of product properties.
MSDS_IH81_ComponentB.doc
|