Page: 1
Revision Date: 04/30/2008
SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751
P.O. Box 2219 Telephone 614-790-3333
Columbus, OH 43216 Emergency telephone 1-800-ASHLAND
(1-800-274-5263)
Product name ISOSET?UX100 ADHESIVE
Product code 33496
Product Use Description No data
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid, yellow, Yellow
WARNING! MAY BE HARMFUL IF INHALED. MAY CAUSE EYE
IRRITATION. MAY CAUSE SKIN AND RESPIRATORY TRACT
IRRITATION.PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND
CAUSE DERMATITIS AND BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
Potential Health Effects
Routes of exposure
Inhalation, Skin contact, Eye Contact, Ingestion
Eye contact
Can cause eye irritation. Symptoms include stinging, tearing, redness, and
swelling of eyes.
Skin contact
Can cause skin irritation. Prolonged or repeated contact may dry the skin.
Symptoms may include redness, burning, and drying and cracking of skin, burns and
other skin damage. Additional symptoms of skin contact may include: allergic skin
reaction (delayed skin rash which may be followed by blistering, scaling and other skin
effects)
Ingestion
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Revision Date: 04/30/2008
SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
Swallowing small amounts of this material during normal handling is not likely to
cause harmful effects. Swallowing large amounts may be harmful.
Inhalation
Breathing of vapor or mist is possible. Breathing aerosol and/or mist is possible
when material is sprayed. Aerosol and mist may present a greater risk of injury because
more material may be present in the air than from vapor alone. Breathing this material
may be harmful. This product is a two-part urethane system. While breathing
4,4'-diphenylmethane diisocyanate (MDI) can be harmful or fatal, breathing MDI is not
expected during normal use of this system.
Aggravated Medical Condition
Preexisting disorders of the following organs (or organ systems) may be
aggravated by exposure to this material:, respiratory tract, skin, lung (for example,
asthma-like conditions)
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing,
and/or passage of the material through the skin may include:, stomach or intestinal upset
(nausea, vomiting, diarrhea), irritation (nose, throat, airways), Cough, discomfort in the
chest, Headache, Shortness of breath, Exposure to this product (or a component) may
cause an allergic reaction (narrowing of the air passages of the lungs resulting in difficult
breathing, tightness in the chest, coughing and wheezing) in some sensitive individuals.
Other symptoms of an allergic reaction may include itchy and watery eyes, runny and
stuffy nose, sweating, flushing, hives, rapid heart rate, and lowered blood pressure.
Target Organs
Overexposure to this material (or its components) has been suggested as a cause
of the following effects in humans:, respiratory sensitization
Carcinogenicity
In a two-year inhalation study in rats, exposure to polymeric methylene
bisphenylisocyanate (MDI) aerosol caused a significant increase in benign
(noncarcinogenic) lung tumors, along with a single carcinogenic lung tumor, at the
highest dose only (6 mg/m3). The tumors occurred along with irritation of the respiratory
tract and the accumulation of a yellow material in the lungs. There was irritation only at
1.0 mg/m3 and no effect at 0.2 mg/m3. MDI is not listed as carcinogenic by the
International Agency for Research on Cancer (IARC), the National Toxicology Program
(NTP) or the Occupational Safety and Health Administration (OSHA).
Reproductive hazard
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Revision Date: 04/30/2008
SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
No data
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS-No. Concentration
POLY(METHYLENEPHENYLENE) 9016-87-9 >=30-<40%
POLYISOCYANATE
4,4'-DIPHENYLMETHANE 101-68-8 >=30-<40%
DIISOCYANATE
METHYLENE 26447-40-5 >=5-<10%
DIPHENYLISOCYANATE
4. FIRST AID MEASURES
Eyes
If symptoms develop, move individual away from exposure and into fresh air.
Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is
any visual difficulty, seek medical attention.
Skin
Remove contaminated clothing. Wash exposed area with soap and water. If
symptoms persist, seek medical attention. Launder clothing before reuse.
Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give
anything by mouth; place individual on the left side with the head down. Contact a
physician, medical facility, or poison control center for advice about whether to induce
vomiting. If possible, do not leave individual unattended.
Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If
symptoms persist, seek medical attention. If breathing is difficult, administer oxygen.
Keep person warm and quiet; seek immediate medical attention.
Notes to physician
Hazards: No information available.
Treatment: No information available.
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Revision Date: 04/30/2008
SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Alcohol-resistant foam, regular foam (such
as AFFF), Agents approved for class B hazards or water fog.
Hazardous combustion products
carbon dioxide and carbon monoxide, Hydrogen cyanide (hydrocyanic acid),
nitrogen compounds, various hydrocarbons
Precautions for fire-fighting
Never use welding or cutting torch on or near drum (even empty) because
product (even just residue) can ignite explosively.Wear full firefighting turn-out gear (full
Bunker gear), and respiratory protection (SCBA). DO NOT direct a solid stream of
water or foam into hot, burning pools of liquid since this may cause frothing and increase
fire intensity. Frothing can be violent and possibly endanger any firefighter standing too
close to the burning liquid. Use water spray to cool fire exposed containers and structures
until fire is out if it can be done with minimal risk. Avoid spreading burning liquid with
water used for cooling purposes.
Flammability Class for Flammable Liquids
Combustible Liquid Class IIIBCombustible Liquid Class IIIB
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
No data
Environmental precautions
Prevent run-off to sewers, streams or other bodies of water. If run-off occurs,
notify proper authorities as required, that a spill has occurred.
Methods for cleaning up
Persons not wearing protective equipment should be excluded from area of spill
until clean-up has been completed. Stop spill at source, dike area of spill to prevent
spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay,
earth, floor absorbent, or other absorbent material and shoveled into containers. Absorb
liquid on vermiculite, floor absorbent or other absorbent material.
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Revision Date: 04/30/2008
SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
7. HANDLING AND STORAGE
Handling
Containers of this material may be hazardous when emptied. Since emptied
containers retain product residues (vapor, liquid, and/or solid), all hazard precautions
given in the data sheet must be observed.
Storage
No data
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
4,4'-DIPHENYLMETHANE 101-68-8
DIISOCYANATE
ACGIH time weighted average 0.005 ppm
NIOSH Recommended exposure limit 0.005 ppm
(REL):
NIOSH Recommended exposure limit 0.05 mg/m3
(REL):
NIOSH Ceiling Limit Value and Time 0.020 ppm
Period (if specified):
NIOSH Ceiling Limit Value and Time 0.2 mg/m3
Period (if specified):
OSHA Z1 Ceiling Limit Value: 0.02 ppm
OSHA Z1 Ceiling Limit Value: 0.2 mg/m3
OSHA Z1A Ceiling Limit Value: 0.02 ppm
OSHA Z1A Ceiling Limit Value: 0.2 mg/m3
US CA OEL Time Weighted Average (TWA) 0.005 ppm
Permissible Exposure Limit (PEL):
US CA OEL Time Weighted Average (TWA) 0.051 mg/m3
Permissible Exposure Limit (PEL):
General advice
These recommendations provide general guidance for handling this product.
Personal protective equipment should be selected for individual applications and should
consider factors which affect exposure potential, such as handling practices, chemical
concentrations and ventilation. It is ultimately the responsibility of the employer to
follow regulatory guidelines established by local authorities.
Exposure controls
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SAFETY DATA SHEET
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MSDS Number: R0317585
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33496
Provide sufficient mechanical (general and/or local exhaust) ventilation to
maintain exposure below TLV(s).
Eye protection
Chemical splash goggles in compliance with OSHA regulations are advised;
however, OSHA regulations also permit other type safety glasses. Consult your safety
representative.
Skin and body protection
To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Wear resistant gloves such as:
butyl-rubber
Respiratory protection
If workplace exposure limit(s) of product or any component is exceeded (see
exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of
proper environmental control. OSHA regulations also permit other NIOSH respirators
(negative pressure type) under specified conditions (see your industrial hygienist).
Engineering or administrative controls should be implemented to reduce exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state liquid
Form No data
Colour yellowYellow
Odour No data
Boiling point/boiling range No data
pH No data
Flash point 459.9 癋 / 237.7 癈
Evaporation rate No data
Explosion limits No data
Vapour pressure 0.00 hPa
Vapour density No data
Density 1.160 g/cm3 @ 77.0 癋 / 25.0 癈
9.67 lb/gal @ 77.00 癋 / 25.00 癈
Solubility No data
Partition coefficient: n- No data
octanol/water
log Pow no data available
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Revision Date: 04/30/2008
SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
Autoignition temperature No data
10. STABILITY AND REACTIVITY
Stability
Stable.
Conditions to avoid
Avoid contact with:, excessive heat
Incompatible products
Avoid contact with strong alkalies, strong mineral acids, and water., Avoid
contact with:, strong alkalis, strong mineral acids, water
Hazardous decomposition products
carbon dioxide and carbon monoxide, Hydrogen cyanide (hydrocyanic acid),
nitrogen compounds, various hydrocarbons
Hazardous reactions
Product can undergo hazardous polymerization.
Thermal decomposition
No data
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity
POLY(METHYLENEPHENYLENE) LD 50 Rat: > 10,000 mg/kg
POLYISOCYANATE
4,4'-DIPHENYLMETHANE DIISOCYANATE LD 50 Rat: 9,200 mg/kg
METHYLENE DIPHENYLISOCYANATE LD 50 Rat: > 15,800 mg/kg
Acute inhalation toxicity
POLY(METHYLENEPHENYLENE) LC 50 Rat: 369 - 490 mg/m3 , 4 h
POLYISOCYANATE
4,4'-DIPHENYLMETHANE DIISOCYANATE LC 50 Rat: 0.369 mg/l , 4 h
METHYLENE DIPHENYLISOCYANATE LC 50 Rat: 490 mg/m3 , 4 h
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SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
Acute dermal toxicity
POLY(METHYLENEPHENYLENE) LD 50 Rabbit: > 10,000 mg/kg
POLYISOCYANATE
4,4'-DIPHENYLMETHANE DIISOCYANATE LD 50 Rabbit: > 7,900 mg/kg
METHYLENE DIPHENYLISOCYANATE LD 50 Rabbit: > 5,010 mg/kg
12. ECOLOGICAL INFORMATION
Aquatic toxicity
Acute and Prolonged Toxicity to Fish
No data
Acute Toxicity to Aquatic Invertebrates
No data
Environmental fate and pathways
No data
13. DISPOSAL CONSIDERATIONS
Waste disposal methods
Destroy by incineration in accordance with applicable regulations. Contaminated
absorbent, after a sufficient conditioning time of at least 48 hours for deactivation and
drying, may be deposited in a landfill in accordance with local, state and federal
regulations. For assistance with your waste management needs - including disposal,
recycling and waste stream reduction, contact Ashland Distribution's Environmental
Services Group at 800-637-7922.
14. TRANSPORT INFORMATION
Dangerous goods descriptions (if indicated above) may not reflect package size, quantity,
end-use or region-specific exceptions that can be applied. Consult shipping documents for
descriptions that are specific to the shipment.
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Revision Date: 04/30/2008
SAFETY DATA SHEET
Print Date: 6/19/2009
MSDS Number: R0317585
ISOSET?UX100 ADHESIVE Version: 1.3
33496
15. REGULATORY INFORMATION
California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer,
birth, or any other reproductive defects.
SARA Hazard Classification Acute Health Hazard
SARA 313 Component(s)
POLY(METHYLENEPHENYLENE 9016-87-9 31.6085%
) POLYISOCYANATE
4,4'-DIPHENYLMETHANE 101-68-8 30.9763%
DIISOCYANATE
Reportable quantity - Product
US. EPA CERCLA Hazardous Substances (40 CFR 302) 16141 lbs
Reportable quantity - Components
POLY(METHYLENEPHENYLENE) 9016-87-9 none
POLYISOCYANATE
4,4'-DIPHENYLMETHANE 101-68-8 5000 lbs
DIISOCYANATE
METHYLENE 26447-40-5 none
DIPHENYLISOCYANATE
Health Flammability Reactivity Other
HMIS 2* 1 1
NFPA 3 1 1
16. OTHER INFORMATION
The information accumulated herein is believed to be accurate but is not warranted to be
whether originating with the company or not. Recipients are advised to confirm in
advance of need that the information is current, applicable, and suitable to their
circumstances. This MSDS has been prepared by Ashland's Environmental Health and
Safety Department (1-800-325-3751).
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