MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: MARINE TRADES PROJECT
TRADE NAME:
3M Marine Adhesive Sealant Fast Cure 4200 - Black, P.N. 06564, 05261
ID NUMBER/U.P.C.:
60-9800-3030-2 00-51135-06564-8 60-9800-3297-7 00-51135-06564-8
60-9800-4295-0 00-51135-05261-7
ISSUED: December 13, 2001
SUPERSEDES: May 10, 2001
DOCUMENT: 07-7655-9
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1. INGREDIENT C.A.S. NO. PERCENT
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URETHANE POLYMER........................ 68130-40-5 30.0 - 40.0
POLY(VINYL CHLORIDE).................... 9002-86-2 20.0 - 30.0
PLASTICIZER (Europe & Australia CAS
91082-17-6)........................... 70775-94-9 20.0 - 30.0
XYLENE.................................. 1330-20-7 5.0 - 10.0
HYDROTREATED LIGHT PETROLEUM
DISTILLATES........................... 64742-47-8 1.0 - 5.0
IRON OXIDE (FE3O4)...................... 1317-61-9 1.0 - 5.0
DIPHENYLMETHANE-4 4'-DIISOCYANATE (MDI). 101-68-8 < 0.6
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
XYLENE
DIPHENYLMETHANE-4 4'-DIISOCYANATE (MDI)
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2. PHYSICAL DATA
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BOILING POINT:................. N/D
VAPOR PRESSURE:................ N/D
VAPOR DENSITY:................. 3.66 Air=1
(Xylene)
EVAPORATION RATE:.............. N/A
SOLUBILITY IN WATER:........... nil
SPECIFIC GRAVITY:.............. 1.17 g/cc
PERCENT VOLATILE:.............. 7.5 % by wt
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Marine Adhesive Sealant Fast Cure 4200 - Black, P.N. 06564, 05261
December 13, 2001 PAGE 2
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2. PHYSICAL DATA (continued)
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pH:............................ N/A
VISCOSITY:..................... N/D
MELTING POINT:................. N/A
APPEARANCE AND ODOR:
Black paste with solvent odor.
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... 110 F PMCC
ASTM D93
FLAMMABLE LIMITS - LEL:........ 1 %
FLAMMABLE LIMITS - UEL:........ 8 %
AUTOIGNITION TEMPERATURE:...... 851 F
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
None known.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 2 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Amines, Alcohols, Water. Reaction with water, alcohols and amines is
not hazardous if container can vent to the atmosphere to prevent
pressure buildup.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Isocyanates.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Marine Adhesive Sealant Fast Cure 4200 - Black, P.N. 06564, 05261
December 13, 2001 PAGE 3
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Evacuate unprotected personnel from hazard area.
Collect using non-sparking tools. Clean up residue with an
appropriate organic solvent. Read and follow safety precautions on
the solvent label and MSDS. Place in an approved metal container.
Seal the container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 0.73 lb/gal calculated per SCAQMD rule 443.1.
Volatile Organic Compounds: 88 gms/liter calculated per SCAQMD rule 443.1.
VOC Less H2O & Exempt Solvents: 88 gms/liter calculated per SCAQMD rule
443.1.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity. U.S. EPA Hazardous Waste Number = D001
(Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Immediately wash skin with soap and large amounts of water. Remove
contaminated clothing. If signs/symptoms occur, call a physician.
Wash contaminated clothing before reuse and dispose of contaminated
shoes.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Marine Adhesive Sealant Fast Cure 4200 - Black, P.N. 06564, 05261
December 13, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear safety glasses with side shields.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: nitrile rubber, polyethylene/ethylene vinyl alcohol,
polyvinyl alcohol.
RECOMMENDED VENTILATION:
Do not use in a confined area or areas with little or no air
movement. Use in a well-ventilated area. Provide sufficient
ventilation to maintain emissions below recommended exposure limits.
If exhaust ventilation is not adequate, use appropriate respiratory
protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors. Select one of the following NIOSH
approved respirators based on airborne concentration of contaminants
and in accordance with OSHA regulations: half-mask organic vapor
respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Wash hands after handling and
before eating. Do not ingest.
RECOMMENDED STORAGE:
Store in a cool place. Keep container dry. Keep container closed
when not in use. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Keep away from heat, sparks, open
flame, and other sources of ignition.
OTHER PRECAUTIONARY INFORMATION:
Wash contaminated clothing thoroughly before re-use. Discard
contaminated leather clothing.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Marine Adhesive Sealant Fast Cure 4200 - Black, P.N. 06564, 05261
December 13, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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URETHANE POLYMER..................... NONE NONE NONE NONE
POLY(VINYL CHLORIDE)................. NONE NONE NONE NONE
PLASTICIZER (Europe & Australia
CAS 91082-17-6).................... NONE NONE NONE NONE
XYLENE............................... 100 PPM TWA ACGIH
XYLENE............................... 150 PPM STEL ACGIH
XYLENE............................... 100 PPM TWA OSHA
XYLENE............................... 150 PPM STEL OSHA
HYDROTREATED LIGHT PETROLEUM
DISTILLATES........................ 300 PPM TWA CMRG
IRON OXIDE (FE3O4)................... NONE NONE NONE NONE
DIPHENYLMETHANE-4 4'-DIISOCYANATE
(MDI).............................. 0.02 PPM CEIL OSHA
DIPHENYLMETHANE-4 4'-DIISOCYANATE
(MDI).............................. 0.005 PPM TWA ACGIH
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.
SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction: signs/symptoms can include redness,
swelling, blistering, and itching.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Marine Adhesive Sealant Fast Cure 4200 - Black, P.N. 06564, 05261
December 13, 2001 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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INHALATION:
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Prolonged or repeated exposure may cause:
Allergic Respiratory Reaction: signs/symptoms can include
difficulty breathing, wheezing, tightness of chest, and
respiratory failure.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, muscular weakness,
incoordination, slowed reaction time, fatigue, blurred vision,
slurred speech, giddiness, tremors and convulsions.
OTHER HEALTH HAZARD INFORMATION:
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) (101-68-8): Persons previously
sensitized to an isocyanate, or persons with a preexisting,
non-specific bronchial hyperreactivity, can respond to concentrations
below the TLV. These symptoms, which can include chest tightness,
wheezing, cough, shortness of breath, or asthma attack, could be
immediate or delayed (up to several hours after exposure).
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SECTION CHANGE DATES
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SUGG. FIRST AID SECTION CHANGED SINCE May 10, 2001 ISSUE
PRECAUTIONARY INFO. SECTION CHANGED SINCE May 10, 2001 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M Marine Adhesive Sealant Fast Cure 4200 - Black, P.N. 06564, 05261
December 13, 2001 PAGE 7
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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