MATERIAL SAFETY DATA SHEET
FIRE
PRODUCT NAME: ULTIMATE LININGS BONDING AGENT
1
SECTION I - COMPANY IDENTIFICATION
2 1 REACTIVITY
HEALTH
COMPANY NAME: Ultimate Linings Ltd. H
ADDRESS: 6630 Roxburgh Drive, Suite 175, Houston, TX 77041
PERSONAL PROTECTION (SECTION VIII)
INFORMATION PHONE: 713-466-0302
HMIS HAZARD RATING
EMERGENCY CONTACT: (CHEMTREC): 800-424-9300 LEAST ----------- 0 SLIGHT ---- 1
MODERATE --- 2 HIGH ------- 3
EXTREME ---- 4
DATE REVISED: August 22, 2006
SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION
OCCUPATIONAL EXPOSURE LIMITS
VAPOR PRESSURE
HAZARDOUS COMPONENTS CAS NUMBER OSHA PEL ACGIH TLV MFG TLV
mm Hg @ TEMP
*4,4'-DIPHENYLMETHANE DIISOCYANATE 101-68-8 .02 ppm .005 ppm
<5.0 25癈 (77癋)
(CEILING)
*N-METHYL-2-PRROLIDINONE 872-50-4 N/E N/E
* Indicates toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.
Information concerning non-hazardous ingredients is considered a Trade Secret.
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING POINT: >138癈 (280癋) SPECIFIC GRAVITY: (H2O=1):1.82
COATING V.O.C.: 200 g/l (1.67 lb/gal) VAPOR DENSITY: N/A
EVAPORATION RATE: Slower than ether SOLUBILITY IN WATER: Reacts with
water
APPEARANCE AND ODOR: Clear liquid, aromatic odor
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: >93癈 (199癋) METHOD USED: TCC
FLAMMABLE LIMITS IN AIR BY VOLUME: (Based on N-MTHYL-2PRROLIDINONE) Lower: 1.3%
Upper: 9.5%
EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide. If water is used, use very large quantities of cold
water. The reaction between water and hot isocyanate may be vigorous.
SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved self-contained breathing apparatus in positive
pressure mode with full-face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required.
Excessive pressure or temperature may cause explosive rupture of containers.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Water contamination will produce carbon dioxide. Do not reseal
contaminated containers as pressure buildup may rupture them. Combustible.
SECTION V - REACTIVITY DATA
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible
materials in a closed system will cause liberation of carbon dioxide and buildup of pressure.
INCOMPATIBILITY (MATERIALS TO AVOID): This product will react with any material containing active hydrogens,
such as water, alcohol, ammonia, amines, alkalis and acids, the reaction with water is slow under 50癈, but is
accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal compounds. Some
reactions can be violent. Material can react violently with strong oxidizing agents.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Carbon dioxide, carbon monoxide, nitrogen oxides, trace
amounts of hydrogen cyanide and unidentified organic compounds may be formed during combustion.
HAZARDOUS POLYMERIZATION: May occur. High temperatures, above 207癈 (400癋) in the presence of moisture
alkalis, tertiary amines, and metal compounds will accelerate polymerization. Possible evolution of carbon dioxide gas
may rupture closed containers.
SECTION VI - HEALTH HAZARD DATA
SKIN CONTACT: Some components used in this material when spilled on the skin may cause irritation, redness,
swelling, or blistering. Repeated contact may cause irritation of the skin and an allergic skin reaction consisting of a
hive-like rash on locations not even directly contacted by the liquid. Individuals who have developed a skin
sensitization can develop these symptoms as a result of contact with very small amounts of liquid material or as a
result of exposure to vapor.
EYE CONTACT: Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and
swelling. The effects of liquid directly contacting the eye can lead to possible damage to the cornea and impairment
of vision. The effects of high vapor concentration may vary from slight irritation with tearing and burning sensation to
keratitis consisting of inflammation of the cornea and impairment of vision. Any level of contact should not be left
untreated.
SKIN ABSORPTION: Systemically toxic concentrations of this product will probably not be absorbed through human
skin.
INGESTION: Can result in irritating and corrosive action in the mouth, stomach tissue and digestive tract and
gastroenteritis. Symptoms can include sore throat, headache, abdominal pain, nausea, vomiting and diarrhea.
Pronounced gastroenteritis effects would probably occur on repeated ingestion.
INHALATION: Isocyanate vapors or mist at concentrations above the TLV can irritate (burning sensation) the
mucous membranes in the respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest
discomfort, shortness of breath and reduced lung function (breathing obstruction). High vapor concentrations may
cause central nervous system (CNS) depression as evidenced by giddiness, headache, dizziness, and nausea.
Persons with a preexisting, non-specific bronchial hyperactivity can respond to concentrations below the TLV with
similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm
and pulmonary edema (fluid in lungs). As a result of previous repeated overexposures or a single large dose, certain
individuals may develop isocyanate sensitization (chemical asthma) which will cause them to react to a later
exposure to isocyanate at levels well below the TLV. Similar to many non-specific asthmatic responses, there are
reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air or other
irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years. Chronic
overexposure to isocyanate has also been reported to cause lung damage (including decrease in lung function) which
may be permanent. Sensitization can either be temporary or permanent.
HEALTH HAZARDS: ACUTE: Exposure may cause mucous membrane and respiratory tract irritation, tightness of
chest, headache, shortness of breath, and a dry cough. At concentrations exceeding current occupational limits and
for sensitized individuals at levels less than or greater than current occupational limits, asthma-like symptoms may
occur. These symptoms may include coughing, wheezing, and shortness of breath. A hypersensitive pneumonitis
may also occur if the person is sensitized. This syndrome is characterized by fever, nonproductive cough, wheezing,
chills, and shortness of breath. Central nervous system (CNS) depression may also result. The effects of acute
exposure may be delayed in onset up to 12-24 hours. CHRONIC: Repeated exposure above current occupational
limits may cause an allergic sensitization of the respiratory tract. This is characterized by an asthma-like response
upon re-exposure to the chemical. The symptoms may include coughing, wheezing, shortness of breath and chest
tightness, and may be fatal. Central nervous system (CNS) impairment leading to unconsciousness and fatality may
occur in extreme cases.
CARCINOGENICITY: NTP: No IARC Monographs: NO OSHA Regulated: No
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Cardiovascular disease, asthma or
asthmatic bronchitis, emphysema, allergic disease, chronic respiratory disease, sinusitis, headache and dizziness.
EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: Immediately flush eyes with plenty of water,
preferably lukewarm. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Have eyes examined and treated by medical personnel. INHALATION: Remove victim to fresh air. If not breathing,
give artificial respiration, preferably mouth-to-mouth. If breathing is labored, give oxygen. Consult medical personnel.
SKIN CONTACT: Wash material off the skin thoroughly with plenty of soap and water. If redness, itching, or a
burning sensation develops, get medical attention. Wash contaminated clothing and decontaminate footwear before
reuse. INGESTION: Do not induce vomiting. Immediately drink large quantities of water and refer person to medical
personnel. Do not give anything by mouth to an unconscious person.
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear skin, eye, and respiratory
protection during cleanup. Soak up material with absorbent and shovel into a chemical waste container. Cover
container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent
and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the
ammonium hydroxide). Follow the precautions on the supplier's material safety data sheets. All operations should be
performed by trained personnel familiar with the hazards of the chemicals used. Treat the spill area with the
decontamination solution, using about 10 parts of solution for each part of the spill, and allow it to react for at least 15
minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated
as described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous
waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
WASTE DISPOSAL METHOD: Slowly stir the isocyanate waste into the decontamination solution described above.
Let stand for 48 hours, allowing the evolved carbon dioxide to vent away, residues may still be subject to RCRA
storage and disposal requirements. Dispose off in compliance with all relevant local, state, and federal laws and
regulations regarding treatment.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep in cool, dry, ventilated storage area, in closed
containers and out of direct sunlight. Keep liquid and vapors away from heat, sparks and flame, store in containers
above ground and surrounded by dikes to contain spills or leaks. Sufficient heat or pressure may ignite or detonate
even liquid product in the absence of sparks or open flame. Extinguish pilot lights, cigarettes and turn off other
sources of ignition before use and until all vapors are gone. Vapors may accumulate and travel to ignition sources
distant from the handling site; flash fire can result. Keep containers closed when not in use. Containers, even those
that have been emptied, may contain explosive vapors. Do not cut, drill, grind, weld or perform similar operations on
or near containers. Do not pressurize containers to empty them. Use explosion-proof lighting and equipment, non-
sparking tools, clothes and shoes. Ground all structures, transfer containers and equipment to conform to the national
electrical code. Use procedures which prevent static electrical sparks. Static electricity may accumulate and create a
fire hazard.
OTHER PRECAUTIONS: Prevent skin and eye contact, observe TLV limitations. Avoid breathing vapors. Workers
should shower and change to fresh clothing after each shift. A sensitized individual should not be exposed to the
product that caused the sensitization. Air circulation and exhaustion of product vapors must be maintained until the
coatings have fully cured to insure that no potential fire, explosion or health hazard remains. Warning properties
(irritation of the eyes, nose and throat or odor) are not adequate to prevent chronic overexposure from inhalation.
This product can produce asthmatic sensitization upon either single inhalation exposure to a relatively high
concentration or upon repeated inhalation exposure to lower concentrations. Exposure to vapors of heated products
can be extremely dangerous. Employee education and training in safe handling of this material is required under
OSHA hazard communication standard. Individuals with existing respiratory disease such as chronic bronchitis,
emphysema, or asthma should not be exposed to products. These individuals should be identified through baseline
and annual evaluation and removed from further exposure. Medical examination should include medical history, vital
capacity, and forced expiratory volume at one second.
SECTION VIII - CONTROL MEASURES
VENTILATION: The use of mechanical dilution ventilation is recommended whenever this product is used in a
confined space, is heated above ambient temperatures, or is agitated. Use explosion-proof ventilation equipment.
Use local exhaust ventilation to keep airborne concentrations below the TLV. Follow guidelines in the ACGIH
publication "Industrial Ventilation". Exhaust air may need to be cleaned by scrubbers of filters to reduce
environmental contamination.
RESPIRATORY PROTECTION: If airborne concentrations exceed or are expected to exceed the TLV, use
MSHA/NIOSH approved positive pressure supplied air respirator with a full face piece or an air supplied hood. For
emergencies, use a positive pressure self-contained breathing apparatus. Air purifying (cartridge type) respirators are
not approved for protection against isocyanates.
PROTECTIVE CLOTHING: Gloves determined to be impervious under the conditions of use should be worn always
when working with this product. Depending on conditions of use, additional protection may be required such as
apron, arm covers, or full body suit. Wash contaminated clothing before re-wearing. Protective clothing should be
selected and used in accordance with "Guidelines for the Selection of Chemical Protective Clothing" published by
ACGIH.
EYE PROTECTION: Chemical tight goggles and full-face shield.
OTHER PROTECTIVE EQUIPMENT AND MEASURES: Unhindered access to safety shower and eye wash stations.
As a general hygienic practice, wash hands and face after use. Showers and cleaning of clothes are recommended.
Follow all label instructions. Educate and train employees in safe use of product.
SECTION IX - REGULATORY INFORMATION
DOT PROPER SHIPPING NAME: - Not regulated.
IATA PROPER SHIPPING NAME: Not regulated.
IMO PROPER SHIPPING NAME: Not regulated.
STATE REGULATIONS: CALIFORNIA - As per requirements of the Safe Drinking Water & Toxic Enforcement Act of
CA, USA 1985 (Proposition 65), the public is warned that materials used in this product may create an exposure to
chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm. This warning
required by Section 25249.6 of the California Health and Safety Code.
TOXIC SUBSTANCE CONTROL ACT: All chemicals comprising this product are listed on the TSCA inventory.
USER'S RESPONSIBILITY: A bulletin such as this cannot be expected to cover all possible individual situations. As
the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined
to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and
safety information herein should be passed on to your customers or employees, as the case may be.
DISCLAIMER: The information contained herein is, to the best of our knowledge and belief, accurate and current as
of the date of this MSDS. However, since the conditions of handling and use are beyond our control, we make no
guarantee of results, and assume no liability for damages incurred by use of this material. All chemicals may present
unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole
responsibility of the user. No representations or warranties, either expressed or implied, of merchantability, fitness for
a particular purpose or any other nature are made hereunder with respect to the information contained herein or the
chemical to which the information refers. It is the responsibility of the user to comply with all applicable federal, state
and local laws and regulations.
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