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MSDS Material Safety Data Sheet
CAS

90-43-7 67-56-1 7632-00-0

File Name: 90-43-7_67-56-1_7632-00.asp

REVISION DATE: May 2007                                                                                                                                                     SDS No.:   10135




SAFETY DATA SHEET
SPS


1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING


PRODUCT NAME SPS

PRODUCT NO. 910100

SUPPLIER Dodge Company Ltd,
Units 11/15 Ardglen Industrial
Estate,
Whitchurch, Hampshire,
RG28 7BB, United Kingdom
44 (0)1256-893883
44 (0)1256-893868


2 COMPOSITION/INFORMATION ON INGREDIENTS

Name EC No. CAS-No. Content Classification


2-PHENYLPHENOL (ISO) 201-993-5 90-43-7 < 1% Xi;R36/37/38 N;R50


METHANOL 200-659-6 67-56-1 1-5% F;R11 T;R23/24/25,R39/23/24/25


SODIUM NITRITE 231-555-9 7632-00-0 < 1% O;R8 T;R25 N;R50



The Full Text for all R-Phrases are Displayed in Section 16


3 HAZARDS IDENTIFICATION


Not regarded as a health or environmental hazard under current legislation.


4 FIRST-AID MEASURES


INHALATION

Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by
administering oxygen. Keep the affected person warm and at rest. Get prompt medical attention.

INGESTION

Not relevant.

SKIN CONTACT

Wash the skin immediately with soap and water. Get medical attention if any discomfort continues.

EYE CONTACT

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES


EXTINGUISHING MEDIA

Use: Alcohol resistant foam. Foam. Powder. Dry chemicals, sand, dolomite etc.

SPECIAL FIRE FIGHTING PROCEDURES

Containers close to fire should be removed or cooled with water. Ventilate closed spaces before entering them. Use water to keep fire
exposed containers cool and disperse vapours.

UNUSUAL FIRE & EXPLOSION HAZARDS

Aerosol cans may explode in a fire. Vapours may ignite.

SPECIFIC HAZARDS

Fire creates: Toxic gases/vapours/fumes of Carbon monoxide (CO). Carbon dioxide (CO2).


6 ACCIDENTAL RELEASE MEASURES


SPILL CLEAN UP METHODS

Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.




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REVISION DATE: May 2007 SDS No.: 10135

SPS

7 HANDLING AND STORAGE


USAGE PRECAUTIONS

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. During application and drying, solvent vapours will
be emitted. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Static electricity
and formation of sparks must be prevented. Use explosion proof electric equipment.

STORAGE PRECAUTIONS

Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50癈. May attack some plastics, rubber and coatings.


8 EXPOSURE CONTROLS/PERSONAL PROTECTION



Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3

METHANOL WEL 266 mg/m3(Sk) 250 ppm(Sk) 333 mg/m3(Sk)
200 ppm(Sk)


INGREDIENT COMMENTS

WEL = Workplace Exposure Limits

PROTECTIVE EQUIPMENT




ENGINEERING MEASURES

Explosion-proof general and local exhaust ventilation.

RESPIRATORY EQUIPMENT

If ventilation is insufficient, suitable respiratory protection must be provided.

HAND PROTECTION

Use protective gloves made of: P.T.F.E (Teflon). or Polyethylene/Ethylene Vinyl Alcohol (PE/EVAL).

EYE PROTECTION

Wear approved safety goggles.

OTHER PROTECTION

Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.

HYGIENE MEASURES

DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove
any clothing that becomes contaminated. When using do not eat, drink or smoke.

9 PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE Aerosol

COLOUR Colourless

ODOUR Pleasant, agreeable.

SOLUBILITY Slightly soluble in water.

VAPOUR DENSITY (air=1) >1 VAPOUR PRESSURE 862.069 kPa 54

EVAPORATION RATE <1 BuAc=1 VOLATILE BY VOL. (%) 100

FLASH POINT (癈) >23 CC (Closed cup).


10 STABILITY AND REACTIVITY


STABILITY

Stable under normal temperature conditions.

CONDITIONS TO AVOID

Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents. Strong alkalis. Strong mineral acids.


11 TOXICOLOGICAL INFORMATION


INHALATION

Harmful by inhalation. Vapours may cause headache, fatigue, dizziness and nausea.

INGESTION

May cause discomfort if swallowed. May cause stomach pain or vomiting. Drowsiness, dizziness, disorientation, vertigo. Central
nervous system depression. Narcotic effect.


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REVISION DATE: May 2007 SDS No.: 10135

SPS
SKIN CONTACT

Harmful in contact with skin. Acts as a defatting agent on skin. May cause cracking of skin, and eczema.

EYE CONTACT

Spray and vapour in the eyes may cause irritation and smarting.

HEALTH WARNINGS

May cause irritation to the respiratory system. Prolonged inhalation of high concentrations may damage respiratory system.

ROUTE OF ENTRY

Inhalation. Skin and/or eye contact.



12 ECOLOGICAL INFORMATION


ECOTOXICITY

Not regarded as dangerous for the environment.



13 DISPOSAL CONSIDERATIONS


DISPOSAL METHODS

Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority
requirements.

14 TRANSPORT INFORMATION




UK ROAD CLASS 2.1

PROPER SHIPPING NAME AEROSOLS

UN NO. ROAD 1950 UK ROAD PACK GR. Not Applicable

ADR CLASS NO. 2 ADR CLASS Class 2: Gases

ADR PACK GROUP Not Applicable ADR LABEL NO. 2.1

CEFIC TEC(R) NO. 20G5F RID CLASS NO. 2

RID PACK GROUP Not Applicable UN NO. SEA 1950

IMDG CLASS 2.1 IMDG PAGE NO. 2.1

IMDG PACK GR. Not Applicable EMS F-D, S-U

MFAG See Guide MARINE POLLUTANT No.

UN NO. AIR 1950 AIR CLASS 2.1

AIR PACK GR. Not Applicable


15 REGULATORY INFORMATION


RISK PHRASES

NC Not classified.

SAFETY PHRASES

P13 Safety data sheet available for professional user on request.


16 OTHER INFORMATION


REVISION DATE May 2007

RISK PHRASES IN FULL

R11 Highly flammable.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R25 Toxic if swallowed.

R36/37/38 Irritating to eyes, respiratory system and skin.

R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

R50 Very toxic to aquatic organisms.

R8 Contact with combustible material may cause fire.



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REVISION DATE: May 2007 SDS No.: 10135

SPS




DISCLAIMER

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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