Safety Data Sheet
according to 91/155/EEC and ISO 11014-1
Date of printing: 08.09.2004 Page: 1/7
Revised: 10.12.2003 SDS No.: 082-00031651.0000
1. Identification of the substance/preparation and company
Product
Product name
Inertol-Poxitar?F Part A
Manufacturer/supplier information
Manufacturer/supplier: Sika Deutschland GmbH
Street/postbox: Kornwestheimer Str. 103-107
Town/City and Post Code: Stuttgart
Country: Germany
Phone: +4971180090
Telefax: +497118009321
General information: Product safety
Emergency information phone:
+49-(0)173-6774799
Only out of office hours
2. Composition/information on ingredients
Chemical characterization
Modified, filled anthracene oil and polyamine
Hazardous ingredients
Designation according to 67/548/EEC
CAS No. Concentration Danger symbols R phrases
EEC No.
?Solvent naphtha (petroleum), light arom.
64742-95-6 2.5 - 10 % N,Xn 51/53,10,65,37,66,67
265-199-0
?biphenyl-2-ol
90-43-7 2.5 - 10 % Xi,N 36/37/38,50
201-993-5
?(Z)-N-9-octadecenylpropane-1,3-diamine
7173-62-8 1 - 2.5 % C,N 22,34,50
230-528-9
?2,2'-dimethyl-4,4'methylenebis(cyclohexylamine)
6864-37-5 2.5 - 10 % T,C,N 23/24,35,22,51/53
229-962-1
3. Hazards identification
Hazards identification
C Corrosive
N Dangerous to the environment
Information on hazards to man and to the environment
20/21 Harmful by inhalation and in contact with skin.
34 Causes burns.
51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Product name: Inertol-Poxitar?F Part A
Date of printing: 08.09.2004 Page: 2/7
Revised: 10.12.2003 SDS No.: 082-00031651.0000
4. First-aid measures
General instructions
In any case show the physician the Safety Data Sheet
After inhalation
In the event of symptoms take medical treatment.
After skin contact
In case of contact with skin wash off immediately with soap and
water
Consult a doctor if skin irritation persists.
After eye contact
In case of contact with the eyes, rinse immediately for at least
15 minutes with plenty of water.
Summon a doctor immediately.
After ingestion
Do not induce vomiting.
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
compatible with all usual extinguishing media
Exposure hazard arising from the product, its combustion products or
resulting gases
In the event of fire the following can be released:
Carbon monoxide (CO)
Carbondioxide (CO2)
Nitrogen oxides (NOx)
Additional information
Fire residues and contaminated firefighting medium must be disposed
of in accordance with the local regulations.
Collect contaminated firefighting water separately, must not
be discharged into the drains.
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Use breathing apparatus if exposed to vapours/dust/aerosol.
Environmental precautions
Do not allow to enter drains or waterways
In case of entry into waterways, soil or drains,
inform the responsible authorities.
Product name: Inertol-Poxitar?F Part A
Date of printing: 08.09.2004 Page: 3/7
Revised: 10.12.2003 SDS No.: 082-00031651.0000
6. Accidental release measures (continued)
Procedures for cleaning up
Pick up with absorbent material (e.g. sand, sawdust, general-purpose
binder).
When picked up, treat material as prescribed under heading "Disposal".
7. Handling and storage
Handling
Instructions for safe handling
See chapter 8 / Personal protective equipment.
Instructions for fire and explosion protection
Not applicable.
Storage
Requirements for storage rooms and containers
Keep container tightly closed and dry in a cool, well-ventilated place
Combined storage instructions
Keep away from food, beverages and animal feedstocks.
Additional information regarding storage
Protect from frost.
Protect from heat and direct sunlight
Protect from atmospheric moisture and water
* 8. Exposure controls/personal protection
Personal protective equipment
General protective and hygiene measures
Take care for sufficient ventilation or exhaust on the workshop place.
Avoid contact with eyes and skin
Use barrier skin cream.
Remove soiled or soaked clothing immediately.
Do not eat, drink or smoke during work time.
Wash hands before breaks and after work.
Respiratory protection
In case of insufficient ventilation.
Multi-purpose filter ABEK
Class of vapour filter is depending on
pollutant concentration on the scene.
Hand protection
Butyl rubber/nitrile rubber gloves
Eye protection
Tightly fitting safety glasses
Product name: Inertol-Poxitar?F Part A
Date of printing: 08.09.2004 Page: 4/7
Revised: 10.12.2003 SDS No.: 082-00031651.0000
* 8. Exposure controls/personal protection (continued)
Face shield
Body protection
Working clothes
9. Physical and chemical properties
Appearance
Physical state: liquid
Colour: various
Odour: characteristic
Data relevant to safety Method
Flash point 66 癈
Density at 20癈 2.05 g/cm3
Solubility in water insoluble
Viscosity at 23癈 > 60 s 6mm/ISO 2431
(efflux time)
VOC (solvents) 3.4 %
VOC (CH) 3.4 %
10. Stability and reactivity
Materials to avoid/dangerous reactions
No hazardous reactions when stored and handled according to
prescribed instructions.
Thermal decomposition and hazardous decomposition products
No decomposition if used as prescribed.
11. Toxicological information
Experience on humans
When skin contact:
Causes burns.
When eyes contact:
Causes burns.
When inhalation:
Harmful effects.
When swallowed:
Causes burns.
Product name: Inertol-Poxitar?F Part A
Date of printing: 08.09.2004 Page: 5/7
Revised: 10.12.2003 SDS No.: 082-00031651.0000
12. Ecological information
Additional information
Do not allow to enter waste water drain, waterways or soil.
13. Disposal considerations
Product
Recommendations
Must be disposed of in a special waste disposal unit in accordance
with the corresponding regulations.
See chapter 15, national regulations.
Packaging
Recommendations
Completely emptied packagings can be given for recycling.
Packaging that cannot be cleaned should be disposed of as product
waste
14. Transport information
ADR/RID
UN 1760 Class: 8 Packing group: III Class.code: C9
Proper shipping name
Corrosive liquid, n.o.s.
contains: 2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine)
Label No.: 8
IMO/IMDG
UN 1760 Class: 8 Packing group: III
EmS: F-A, S-B
Marine pollutant: *
Proper shipping name
Corrosive liquid, n.o.s.
contains: 2,2'-Dimethyl-4,4'-methylenbis(cyclohexylamin)
Label No.: 8
IATA/ICAO
UN 1760 Class: 8 Packing group: III
Proper shipping name
Corrosive liquid, n.o.s.
contains: 2,2'-Dimethyl-4,4'-methylenbis(cyclohexylamin)
Label No.: 8
15. Regulatory information
Labelling according to EEC Directive
The product is classified and labelled in accordance with
EC directives/the relevant national laws.
Product name: Inertol-Poxitar?F Part A
Date of printing: 08.09.2004 Page: 6/7
Revised: 10.12.2003 SDS No.: 082-00031651.0000
15. Regulatory information (continued)
Relevant hazardous ingredients for labelling
Contains: 2,2'-dimethyl-4,4'methylenebis(cyclohexylamine)
Danger symbols
C Corrosive
N Dangerous to the environment
R phrases
20/21 Harmful by inhalation and in contact with skin.
34 Causes burns.
51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S phrases
23 Do not breathe gas/fumes/vapour/spray
26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.
38 In case of insufficient ventilation, wear suitable
respiratory equipment.
45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
National regulations
UK Legislation
Health and Safety at Work etc Act, 1974, and relevant Statutory
Provisions.
SI 2002/1689: Chemicals (Hazard Information and Packaging)
Regulations, 2002.
SI 1988/1657: The Control of Substances Hazardous to Health
Regulations.
SI No 2839 1991 Environmental Protection (Duty of Care) Regulations.
SI No. 972/1996: The Special Waste Regulations 1996
UK Guidance Publications
Approved Code of Practice - Management of Health and Safety
at Work, HSE.
General Approved Code of Practice to COSHH Regulations, HSE.
HS(G) 53, Respiratory Protective Equipment - a Practical Guide for
Users, HSE.
HS (G) 37, An Introduction to Local Exhaust Ventilation, HSE
Product name: Inertol-Poxitar?F Part A
Date of printing: 08.09.2004 Page: 7/7
Revised: 10.12.2003 SDS No.: 082-00031651.0000
* 16. Other information
asterisk (*) on left margin marks modification of previous version
R-phrases of the ingredients listed in chapter 2
10 Flammable.
22 Harmful if swallowed.
23/24 Toxic by inhalation and in contact with skin.
34 Causes burns.
35 Causes severe burns.
36/37/38 Irritating to eyes, respiratory system and skin.
37 Irritating to respiratory system.
50 Very toxic to aquatic organisms.
51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed
66 Repeated exposure may cause skin dryness or cracking
67 Vapours may cause drowsiness and dizziness
The information contained in this Safety Data Sheet corresponds to our
level of knowledge at the time of publication. All warranties are ex-
cluded. Our most current General Sales Conditions shall apply. Please
consult the Technical Data Sheet prior to any use and processing.
Safety Data Sheet
according to 91/155/EEC and ISO 11014-1
Date of printing: 08.09.2004 Page: 1/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
1. Identification of the substance/preparation and company
Product
Product name
Inertol-Poxitar?F Part B
Manufacturer/supplier information
Manufacturer/supplier: Sika Deutschland GmbH
Street/postbox: Kornwestheimer Str. 103-107
Town/City and Post Code: Stuttgart
Country: Germany
Phone: +4971180090
Telefax: +497118009321
General information: Product safety
Emergency information phone:
+49-(0)173-6774799
Only out of office hours
2. Composition/information on ingredients
Chemical characterization
Modified epoxi resin, containing solvent
Hazardous ingredients
Designation according to 67/548/EEC
CAS No. Concentration Danger symbols R phrases
EEC No.
?reaction product: bisphenol A-(epichlorhydrin)
epoxy resin (number average molecular weight <= 700)
25068-38-6 50 - 100 % Xi,N 36/38,43,51/53
500-033-5
?reaction product: bisphenol F-(epichlorhydrin) epoxy resin
(number average molecular weight <= 700)
9003-36-5 25 - 50 % Xi,N 36/38,43,51/53
500-006-8
?xylene
1330-20-7 2.5 - 10 % Xn 10,20/21,38
215-535-7
?Ethylbenzene
100-41-4 2.5 - 10 % F,Xn 11,20
202-849-4
3. Hazards identification
Hazards identification
Xi Irritant
N Dangerous to the environment
Information on hazards to man and to the environment
10 Flammable.
36/38 Irritating to eyes and skin.
Product name: Inertol-Poxitar?F Part B
Date of printing: 08.09.2004 Page: 2/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
3. Hazards identification (continued)
43 May cause sensitization by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
4. First-aid measures
General instructions
In any case show the physician the Safety Data Sheet
After inhalation
In the event of symptoms take medical treatment.
After skin contact
In case of contact with skin wash off immediately with soap and
water
Consult a doctor if skin irritation persists.
After eye contact
In case of contact with the eyes, rinse immediately for at least
15 minutes with plenty of water.
Summon a doctor immediately.
After ingestion
Do not induce vomiting.
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
alcohol-resistant foam
dry powder
carbon dioxide
Unsuitable extinguishing media for safety reasons
Full water jet
Exposure hazard arising from the product, its combustion products or
resulting gases
In the event of fire the following can be released:
Carbon monoxide (CO)
Carbondioxide (CO2)
Nitrogen oxides (NOx)
Special protective equipment for fire-fighting
Use breathing apparatus.
Additional information
Fire residues and contaminated firefighting medium must be disposed
of in accordance with the local regulations.
Product name: Inertol-Poxitar?F Part B
Date of printing: 08.09.2004 Page: 3/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
5. Fire-fighting measures (continued)
Collect contaminated firefighting water separately, must not
be discharged into the drains.
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Use breathing apparatus if exposed to vapours/dust/aerosol.
Environmental precautions
Do not allow to enter drains or waterways
In case of entry into waterways, soil or drains,
inform the responsible authorities.
Procedures for cleaning up
Avoid sparking.
Pick up with absorbent material (e.g. sand, sawdust, general-purpose
binder).
When picked up, treat material as prescribed under heading "Disposal".
7. Handling and storage
Handling
Instructions for safe handling
See chapter 8 / Personal protective equipment.
Instructions for fire and explosion protection
Keep away from sources of ignition - no smoking.
Vapours may form explosive mixtures with air
Take precautionary measures against electrostatic loading.
Storage
Requirements for storage rooms and containers
Keep container tightly closed and dry in a cool, well-ventilated place
Combined storage instructions
Keep away from food, beverages and animal feedstocks.
Additional information regarding storage
Protect from frost.
Protect from heat and direct sunlight
Protect from atmospheric moisture and water
Product name: Inertol-Poxitar?F Part B
Date of printing: 08.09.2004 Page: 4/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
* 8. Exposure controls/personal protection
Substances having workplace related exposure values/limits which may
require monitoring for assessment purposes
Designation of substance
CAS No. Type Ref./Country/Year
?xylene
1330-20-7 OES 441 mg/m3 HSE/EH40/UK
1330-20-7 OES 100 ml/m3 HSE/EH40/UK
?Ethylbenzene
100-41-4 OES 441 mg/m3 HSE/EH40/UK
100-41-4 OES 100 ml/m3 HSE/EH40/UK
Personal protective equipment
General protective and hygiene measures
Take care for sufficient ventilation or exhaust on the workshop place.
Avoid contact with eyes and skin
Use barrier skin cream.
Remove soiled or soaked clothing immediately.
Do not eat, drink or smoke during work time.
Wash hands before breaks and after work.
Respiratory protection
In case of insufficient ventilation.
Ori-nasal mask suitable for organic vapours.
Class of vapour filter is depending on
pollutant concentration on the scene.
Hand protection
Butyl rubber/nitrile rubber gloves
Eye protection
Safety glasses
Body protection
Working clothes
9. Physical and chemical properties
Appearance
Physical state: liquid
Colour: yellowish
Odour: of xylene
Data relevant to safety Method
Flash point 23 癈
Vapour pressure at 20癈 8 mbar
Density at 20癈 approx. 1.1 g/cm3
Product name: Inertol-Poxitar?F Part B
Date of printing: 08.09.2004 Page: 5/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
9. Physical and chemical properties (continued)
Solubility in water immiscible
Viscosity at 20癈 > 75 s 4mm/DIN 53211
VOC (solvents) 12.56 %
VOC (CH) 12.56 %
10. Stability and reactivity
Conditions to avoid
Formation of explosive gas/air mixtures.
Materials to avoid/dangerous reactions
No hazardous reactions when stored and handled according to
prescribed instructions.
Thermal decomposition and hazardous decomposition products
No decomposition if used as prescribed.
11. Toxicological information
Sensitization
Sensitization/allergic reaction possible.
Allergic reaction may be observed in sensitive persons, even
on very low concentrations.
Experience on humans
When skin contact:
Repeated exposure may cause skin dryness or cracking
Irritation.
When eyes contact:
Irritation.
When inhalation:
Vapours have a narcotic effect.Reaction-time and sense of coordi-
nation may be affected.
Irritation.
When swallowed:
Small amount may cause considerable health disorders.
12. Ecological information
Additional information
Do not allow to enter waste water drain, waterways or soil.
Product name: Inertol-Poxitar?F Part B
Date of printing: 08.09.2004 Page: 6/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
13. Disposal considerations
Product
Recommendations
Must be disposed of in a special waste disposal unit in accordance
with the corresponding regulations.
See chapter 15, national regulations.
Packaging
Recommendations
Completely emptied packagings can be given for recycling.
Packaging that cannot be cleaned should be disposed of as product
waste
14. Transport information
ADR/RID
UN 1263 Class: 3 Packing group: III Class.code: F1
Proper shipping name
Paint
Label No.: 3
Further information
Special provision 640E
Transport according to chapter 2.2.3.1.5 ADR
IMO/IMDG
UN 1263 Class: 3 Packing group: III
EmS: F-E, S-E
Marine pollutant: *
Proper shipping name
Paint
Label No.: 3
IATA/ICAO
UN 1263 Class: 3 Packing group: III
Proper shipping name
Paint
Label No.: 3
15. Regulatory information
Labelling according to EEC Directive
The product is classified and labelled in accordance with
EC directives/the relevant national laws.
Relevant hazardous ingredients for labelling
Contains: reaction product: bisphenol A-(epichlorhydrin)
epoxy resin (number average molecular weight <= 700)
reaction product: bisphenol F-(epichlorhydrin) epoxy resin
(number average molecular weight <= 700)
Danger symbols
Xi Irritant
N Dangerous to the environment
Product name: Inertol-Poxitar?F Part B
Date of printing: 08.09.2004 Page: 7/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
15. Regulatory information (continued)
R phrases
10 Flammable.
36/38 Irritating to eyes and skin.
43 May cause sensitization by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S phrases
24 Avoid contact with skin.
37 Wear suitable gloves.
51 Use only in well-ventilated areas.
Special labelling for certain preparations
Contains epoxy-containing compounds.
Observe manufacturer's instructions.
National regulations
UK Legislation
Health and Safety at Work etc Act, 1974, and relevant Statutory
Provisions.
SI 2002/1689: Chemicals (Hazard Information and Packaging)
Regulations, 2002.
SI 1988/1657: The Control of Substances Hazardous to Health
Regulations.
SI No 2839 1991 Environmental Protection (Duty of Care) Regulations.
SI No. 972/1996: The Special Waste Regulations 1996
UK Guidance Publications
Approved Code of Practice - Management of Health and Safety
at Work, HSE.
General Approved Code of Practice to COSHH Regulations, HSE.
EH40, Occupational Exposure Limits, HSE. Revised Annually.
HS(G) 53, Respiratory Protective Equipment - a Practical Guide for
Users, HSE.
HS (G) 37, An Introduction to Local Exhaust Ventilation, HSE
* 16. Other information
asterisk (*) on left margin marks modification of previous version
R-phrases of the ingredients listed in chapter 2
10 Flammable.
11 Highly flammable.
20 Harmful by inhalation.
20/21 Harmful by inhalation and in contact with skin.
36/38 Irritating to eyes and skin.
38 Irritating to skin.
43 May cause sensitization by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Product name: Inertol-Poxitar?F Part B
Date of printing: 08.09.2004 Page: 8/8
Revised: 10.12.2003 SDS No.: 082-00010406.0000
The information contained in this Safety Data Sheet corresponds to our
level of knowledge at the time of publication. All warranties are ex-
cluded. Our most current General Sales Conditions shall apply. Please
consult the Technical Data Sheet prior to any use and processing.
|