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CAS

68477-31-6 112-57-2 90-72-2 106-89-8

File Name: 68477-31-6_112-57-2_90-72-2_106-89-8.asp

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MATERIAL SAFETY DATA SHEET
1. Product and Company Identification


Trade Name: MASCOBOND HI MOD, COMPONENT B
Revised: April08
Chemical Family: AMINEMIXTURE
Product Code: MS2GHM

Company: MasonsSupplyCompany(MASCO)
2637SE12thAvenue
Portland,OR97202


2. COMPOSITION INFORMATION

ThisdocumentispreparedpursuanttotheOSHAHazardCommunicationStandard(29CFR1910.1200).

INGREDIENT CAS NO. TLV STEL PEL CONTENT

MODIFIEDAMINE * N/E N/E N/E >50%

PETROLEUMDISTILLATE 68477-31-6 N/E N/E N/E <15%

ALPHATICAMINE 112-57-2 N/E N/E N/E <8%

AMINOPHENOL 90-72-2 N/E N/E N/E <3%


3. HAZARDS IDENTIFICATION

HMIS Hazard Rating No. 3 (HIGH)
PRIMARY ROUTE OF ENTRY: INHALATION,DERMAL,EYES
EFFECTSOFOVEREXPOSURE:
INHALATION: Vapors/mistmaybecorrosivetoupperrespiratorytract.Repeatedorprolongedexposurecanresultinlungdamage.
Lungdamagemaybeevidencedbyshortnessofbreathandmaybeaccompaniedbychroniccough.
EYES: Productmaycauseirritationtotheeyes.Corrosivetotheeyesandmaycauseseveredamageincludingblindness.
SKIN CONTACT: Corrosivetotheskin.Maycauseskinsensitization.
SKIN ABORPTION: Noknowninformationavailable.
INGESTION: Notexpectedtoarelevantrouteofexposure.However,maycausepermanentdamgetomouth,throatand
stomach.
CHRONIC: Repeatedexposuremaycauseskinsensitization,orsensitizationtotherespiratorytractanddevelopmentofan
asthmaticreactiontofutureexposure.Preexistingeye,skin,andrespiratorydisordersmaybeaggrevatedbyexposure
ofthisproduct.

4. FIRST AID MEASURES

INHALATION: Remove vitcim from exposure. If difficulty with breathing, administer oxygen. If breathing has stopped, administer
artificial respiration. Seek medical attention.


EYES: Flusheyeswithwaterfor15minutes,liftingupperandlowerlidsoccasionally.Seekmedicalattention.


SKIN: Immediatelyremovecontaminatedclothing.Washthoroughlywithsoapandwaterforatleast15minutes.Ifirritaion
occurs,getmedicalattention.Donotre-useclothinguntilthoroughlycleaned.


INGESTION: Donotinducevomiting.Ifvomitingoccursspontaneously,keepheabelowhipstopreventaspirationofliquidintothe
lungs.Giveoneglassofwaterunlessvictimisdrowsy,convulsingorunconscious.Seekmedicalattention.

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MASCOBOND HI MOD, COMPONENT B | msds



5. FIRE FIGHTING METHODS
HMIS HAZARD RATING NO. 1 (Slight)
Flash Point: >200o F METHOD: SETAFLASH
AUTO-IGNITION TEMP.:Notavailable
LIMITS OF FLAMMABILITY:LEL:NotavailableUEL:NotAvailable
EXTINGUISHING MEDIA:Usewaterfog,drychemicalorCO2.
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS: Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats,
gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing apparatus. Cool fire exposed containers with water.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Containers exposed to intense heat from fires should be cooled with water to prevent vapor pressure buildup,
whichcouldresultincontainerrupture.Delayedlungdamagecanbeexperiencedafterexposuretocombustionproduct.Nitrogenoxidesandnitrogen
containingorganiccompoundsmaybereleaseduponcombustion.

6. ACCIDENTAL RELEASE MEASURES
ACTION TO TAKE FOR SPILLS / LEAKS: Cleanuppersonnelmustbeequippedwithself-containedbreathingapparatus,rubberglovesandprotectiveclothing.
Dikeandcontainspill.Soakupresiduewithanabsorbentsuchasclay,sandorothersuitablematerial.Disposeoftheabsorbentmaterialinaccordance
withfederal,stateandlocalregulations.Residualresinmayberemovedwithhotsoapywater.
WASTE DISPOSAL METHOD:Disposeincompliancewithfederal,stateandlocalregulations.

7. HANDLING AND STORAGE
HANDLING: Keep away from open flames and high temperatures. STORAGE:Storeinawellventilatedarea.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION: Avoidprolongedorrepeatedbreathingofvapors.UseaNIOSHapprovedrespiratortopreventoverexposure.Inaccordwith29
CFR1910.134,useafullface,airsupplyingrespiratororanair-purifyingrespiratorfororganicvapors.
PROTECTIVE CLOTHING:Donotgetonskinorclothing.Wearchemicalresistantprotectiveclothing,gloves,andboots.Wearchemicalgogglestoprevent
contactwitheyes.
ADDITIONAL PROTECTIVE MEASURES:Useexplosionproofventilationtocontrolvaporsormistconcentrations.Eyewashfountainsandsafetyshowersshould
beavailableforemergencyuse.


9. PHYSICAL AND CHEMICAL PROPERTIES
Water/Oil Distribution Coefficient: Odor:
N/AV Slight
Boiling Point (0C): Solubility in Water:
N/AV Negligible
Percent Volatile: Specific Gravity:
0.1% 1.13
Freezing Point (0C): pH:
N/AV N/AV
Vapor Pressure mmHg @ 200C: Evaporation Rate:
<10 N/AV
Vapor Density: >Air
Odor Threshold: N/AV
Appearance: GrayLiquid


N/AV = NotAvailable ca. = Approximate

10. STABILITY AND REACTIVITY
HMIS Hazard Rating No. 0
STABILITY: Stable Hazardouspolymerizationwillnotoccur.
CONDITIONS AND MATERIALS TO AVOID: Avoid heat, flame and contact with strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides, carbon monoxide and unidentified organic compounds may be formed during combustion.




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MASCOBOND HI MOD, COMPONENT B | msds



11. TOXICITY INFORMATION

HMIS Hazard Rating No. 3 (High)


PRIMARY ROUTE OF ENTERY:Inhalation,Dermal,Eyes


EFFECTS OF OVEREXPOSURE


INHALATION: Vaporsmaybecorrosivetoupperrespiratorytract.


LC(50) INHAL. N/AV
EYES: Maycauseseveredamageincludingblindness.
SKIN CONTACT: Corrosivetotheskin.Insomeindividualsitmaycausesensitization.
SKIN ABSORPTION: Noinformationavailable.
INGESTION: Notexpectedtoberouteofentry.Maycausepermanentdamagetomouth,throatandstomach.
LD(50) ORAL: CAS.NO.
90-72-2>2169mg/kg(rat)
112-57-23.99g/kg(rat)
68477-31-62,622mg/kg(rat)
CHRONIC: ProductdoesnotcontainchemicalsconsideredtobecarcinogenicbyNTP,IARC,orOSHA.


Thisproductcontainsresidual(<5ppm)quantitiesofepichlorohydrin(ECH)(CASNO.106-89-8).Itisveryunlikelythatnormalworkpracticeswiththis
productcouldresultinmeasurableECHconcentrationsintheworkplaceatmosphere.Nevertheless,youshouldbeawarethatECHhasbeenreported
to produce cancer in laboratory animals and to product mutagenic changes in bacteria and cultured human cells. It has been classified by IARC as a


12. ECOLOGICAL INFORMATION

Marine Pollutant:NL
(NL=NotListed;P=Moderate;PP=SEvere;ND=NotDetermined)


13. DISPOSAL CONSIDERATIONS

Disposeinamannerwhichcomplieswithlocal,state,andfederalregulations.


14. TRANSPORT INFORMATION

DOT/UN SHIPPING NAME: POLYAMINES,LIQUID,CORROSIVE,N.O.S.,(ALKALINEAMINE)
DOT HAZARD CLASS: CLASS8(CORROSIVELIQUID),PGIII
DOT PLACARD: CORROSIVE
OTHER REQUIREMENTS: UN1760,CLASS60


15. REGULATORY INFORMATION
Components are listed on EPA/TSCA inventory of chemical substances.
TITLE III SECTION 302: Noreportablematerials.
TITLE III SECTION 311/312: Healthhazard:Immediate.
Physicalhazard:Fire.
TITLE III SECTION 313: Noreportablematerials.


15. REGULATORY INFORMATION
Information contained in this MSDS refers only to the specific material designated and does not relate to any process or to use with any
other materials. This information is based on data believed to be reliable as of the date hereof. It is furnished without warranty of any kind
express or implied. Since actual use is beyond our control, no guarantee, express or implied, and no liability is assumed by MASONS SUPPLY
COMPANY in conjunction with the use of this information. Nothing herein is to be construed as a recommendation to infringe any patents.




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